Relations between Acceptance-Rejection and Fear of Intimacy in Spanish Adults

This study tried to analyze whether the experience of remembrance perceived parental acceptance- rejection during childhood is retrospectively associated to Fear of Intimacy in adulthood, and to explore the effects of social anxiety and gender on the relations between these two variables. Five instruments were used: adult Parental Acceptance-Rejection Questionnaire for mothers and fathers (short forms), Interpersonal Relationship Anxiety Questionnaire, adult Psychological Adjustment Questionnaire (short form), and Fear of Intimacy Scale. Participants (N=273) ranged from 18 to 75 years (M = 30.11; SD = 12.53), and 65% were females. Correlational and regression analyses were conducted. Correlational analyses indicated that, only for males, paternal rejection remembrance (no maternal) was associated to higher levels of fear of intimacy. Regression analysis showed, only in men, that perceived paternal warmth was a significant predictor of lower levels of fear of intimacy. Results suggest that interpersonal anxiety could moderate the association between fear of intimacy and remembrances of paternal (especially paternal) rejection. Regarding women’s fear of intimacy, no significant results were found.2017-1

N=2 Supersymmetric Kinks and real algebraic curves

The kinks of the (1+1)-dimensional Wess-Zumino model with polynomic superpotential are investigated and shown to be related to real algebraic curves.Comment: 8 pages, LaTeX, epsfig, 4 figures include

Changing shapes: adiabatic dynamics of composite solitary waves

We discuss the solitary wave solutions of a particular two-component scalar field model in two-dimensional Minkowski space. These solitary waves involve one, two or four lumps of energy. The adiabatic motion of these composite non-linear non-dispersive waves points to variations in shape.Comment: 21 pages, 15 figures. To appear in Physica D: Nonlinear Phenomen

The moderating effect of perceived acceptance-rejection predicting children psychological adjustment from a multi-informant approach

The purpose of this study was to explore the moderating effect of children ́s perceived rejection on the relations between parental acceptance and children ́s psychological adjustment reported by mothers, fathers and children. The prediction values and incremental validity of the different informants were also explored. The sample was composed by 681 participants (227 children, 227 fathers, and 227 mothers), children’s (60% girls) ages ranged from 9 to 17 years (M = 12.52, SD = 1.81). Instruments used were the Parental Acceptance Rejection Questionnaire (PARQ; Ronher & Khaleque, 2008) and the Achenbach System of Empirically Based Assessment (ASEBA; Achenbach and Rescorla, 2007) filled both by mothers, fathers, and children in a round-robin design. Hierarchical regression analyses were applied. The moderating effect of children ́s perceived rejection showed that different prediction values and percentages of incremental validity from mothers, fathers and children were found depending of the level of rejection that children perceived. The findings of the present study have important practical implications: the need of considering the role of perceived carelessness as moderator when predicting children psychological adjustment and the necessity of using a multi-informant perspective rather than a single one to increase the predictive value and the incremental validity when we try to predict children’s psychological adjustment.2017-1

Convective Heat Transfer Coefficient in a Bubbling Fluidized Bed with PCM

Proceedings of: 14th International Conference on Fluidization: From Fundamentals to Products. Noordwijkerhout, Netherlands, 26-31 may 2013.This work presents an experimental study to determine the capacity of a Phase Change Material (PCM) in granular form to be used in a bubbling fluidized bed for thermal energy storage. The experimental measurements are focused on the determination of the heat transfer coefficient between a heated surface and the granular PCM in fluidized state. The results obtained indicates that the heat transfer coefficient notably increases (up to values three times higher) when the granular PCM is in solid form because it changes its phase when touches the heated surfaceThis work was partially founded by the Spanish Government (Project ENE2010-15403), the regional Government of Castilla-La Mancha (Project PPIC10-0055-4054) and Castilla-La Mancha University (Project GE20101662).publicad

Developing biodata for public manager selection purposes: A comparison between fuzzy logic and traditional methods

Biodata have been widely used in personnel selection for a long time, mainly due to their predictive validity in different contexts, low faking, and positive applicant reactions. At the same time, some disadvantages need to be highlighted, with discriminatory content representing a major concern. In order to shed light on these issues, the objectives of the present research are twofold: firstly, we aim to develop biodata items for personnel selection for the provision of managerial positions in Public Administration and, secondly, we aim to test the fuzzy logic method as a valid approach for the development of biodata scales, with a view to choosing the best biodata items in terms of job performance, fairness, and privacy, according with manager and applicant perspectives. Participants assessed 26 items according to traditional and fuzzy rules, resulting in 8 highly effective items. Then, both approaches were compared: fuzzy logic turned out to have similar results as the traditional approach. Finnally, future developments in research an practical implications in the field are suggested. Los datos biográficos (biodata) se han utilizado en la selección de personal durante mucho tiempo debido, principalmente, a su buena validez predictiva en diferentes contextos, a su bajo falseamiento y a las reacciones positivas de los solicitantes de empleo. No obstante, podemos destacar el posible contenido discriminatorio como su principal desventaja. Por tanto, los objetivos de la presente investigación son, en primer lugar, desarrollar empíricamente ítems válidos y justos para la selección de puestos directivos en la Administración Pública y, en segundo lugar, comprobar la utilidad de la lógica difusa en el desarrollo de escalas con biodata para elegir los mejores ítems en términos de desempeño laboral, equidad y privacidad, de acuerdo con las perspectivas de directivos y de solicitantes de empleo. Los participantes en el estudio evaluaron 26 ítems según reglas tradicionales y difusas, y se obtuvieron 8 ítems altamente efectivos. Posteriormente se compararon ambos enfoques: aunque la lógica difusa demostró cierta eficacia, logró resultados similares a los del enfoque tradicional. Finalmente, se proponen futuros desarrollos de investigación e implicaciones prácticas en esta materia

Supersymmetry versus Integrability in two-dimensional Classical Mechanics

Supersymmetric extensions of Hamilton-Jacobi separable Liouville mechanical systems with two degrees of freedom are defined. It is shown that supersymmetry can be implemented in this type of systems in two independent ways. The structure of the constants of motion is unveiled and the entanglement between integrability and supersymmetry is explored.Comment: 28 pages, Added reference

Generalized Zeta Functions and One-loop Corrections to Quantum Kink Masses

A method for describing the quantum kink states in the semi-classical limit of several (1+1)-dimensional field theoretical models is developed. We use the generalized zeta function regularization method to compute the one-loop quantum correction to the masses of the kink in the sine-Gordon and cubic sinh-Gordon models and another two ${\rm P}(\phi)_2$ systems with polynomial self-interactions.Comment: 29 pages, 4 figures; version to appear in Nucl. Phys.

Preparation and degradation of rhodium and iridium diolefin catalysts for the acceptorless and base-free dehydrogenation of secondary alcohols

Rhodium and iridium diolefin catalysts for the acceptorless and base-free dehydrogenation of secondary alcohols have been prepared, and their degradation has been investigated, during the study of the reactivity of the dimers [M(µ-Cl)(I4-C8H12)]2 (M = Rh (1), Ir (2)) and [M(µ-OH)(I4-C8H12)]2 (M = Rh (3), Ir (4)) with 1, 3-bis(6'-methyl-2'-pyridylimino)isoindoline (HBMePHI). Complex 1 reacts with HBMePHI, in dichloromethane, to afford equilibrium mixtures of 1, the mononuclear derivative RhCl(I4-C8H12){¿1-Npy-(HBMePHI)} (5), and the binuclear species [RhCl(I4-C8H12)]2{µ-Npy, Npy-(HBMePHI)} (6). Under the same conditions, complex 2 affords the iridium counterparts IrCl(I4-C8H12){¿1-Npy-(HBMePHI)} (7) and [IrCl(I4-C8H12)]2{µ-Npy, Npy-(HBMePHI)} (8). In contrast to chloride, one of the hydroxide groups of 3 and 4 promotes the deprotonation of HBMePHI to give [M(I4-C8H12)]2(µ-OH){µ-Npy, Niso-(BMePHI)} (M = Rh (9), Ir (10)), which are efficient precatalysts for the acceptorless and base-free dehydrogenation of secondary alcohols. In the presence of KOtBu, the [BMePHI]- ligand undergoes three different degradations: Alcoholysis of an exocyclic isoindoline-N double bond, alcoholysis of a pyridyl-N bond, and opening of the five-membered ring of the isoindoline core.

Rhodium complexes in p-C bond formation: Key role of a hydrido ligand

Olefin hydrophosphanation is an attractive route for the atom-economical synthesis of functionalized phosphanes. This reaction involves the formation of P-C and H-C bonds. Thus, complexes that contain both hydrido and phosphanido functionalities are of great interest for the development of effective and fast catalysts. Herein, we showcase the excellent activity of one of them, [Rh(Tp)H(PMe3)(PPh2)] (1), in the hydrophosphanation of a wide range of olefins. In addition to the required nucleophilicity of the phosphanido moiety to accomplish the P-C bond formation, the key role of the hydride ligand in 1 has been disclosed by both experimental results and DFT calculations. An additional Rh-H··· C stabilization in some intermediates or transition states favors the hydrogen transfer reaction from rhodium to carbon to form the H-C bond. Further support for our proposal arises from the poor activity exhibited by the related chloride complex [Rh(Tp)Cl(PMe3)(PPh2)] as well as from stoichiometric and kinetic studies