Concentration, temperature, and density in a hydrogen-air flame by excimer-induced Raman scattering

Single-pulse, vibrational Raman scattering (VRS) is an attractive laser diagnostic for the study of supersonic hydrogen-air combustion. The VRS technique gives a complete thermodynamic description of the gas mixture at a point in the reacting flow. Single-pulse, vibrational Raman scattering can simultaneously provide independent measurements of density, temperature, and concentration of each major species (H2, H2O, O2 and N2) in a hydrogen/air turbulent combustor. Also the pressure can be calculated using the ideal gas law. However, single-pulse VRS systems in current use for measurement of turbulent combustion have a number of shortcomings when applied to supersonic flows: (1) slow repetition rate (1 to 5 Hz), (2) poor spatial resolution (0.5x0.3x0.3 cu mm), and (3) marginal time resolution. Most of these shortcomings are due to the use of visible wavelength flash-lamp pumped dye lasers. The advent of UV excimer laser allows the possibility of dramatic improvements in the single-pulse, vibrational Raman scattering. The excimer based VRS probe will greatly improve repetition rate (100 to 500 Hz), spatial resolution (0.1x0.1x0.1 cu mm) and time resolution (30ns). These improvements result from the lower divergence of the UV excimer, higher repetition rate, and the increased Raman cross-sections (15 to 20 times higher) at ultra-violet (UV) wavelengths. With this increased capability, single-pulse vibrational Raman scattering promises to be an ideal non-intrusive probe for the study of hypersonic propulsion flows

Advanced smoke meter development survey and analysis

Ideal smoke meter characteristics are determined to provide a basis for evaluation of candidate systems. Five promising techniques are analyzed in detail to evaluate compilance with the practical smoke meter requirements. Four of the smoke measurement concepts are optical methods: Modulated Transmission (MODTRAN), Cross Beam Absorption Counter (CBAC), Laser Induced Incandescence (LIN), and Photoacoustic Spectroscopy (PAS). A rapid response filter instrument called a Taper Element Oscillating Microbalance (TEOM) is also evaluated. For each technique, the theoretical principles are described, the expected performance is determined, and the advantages and disadvantages are discussed The expected performance is evaluated against each of the smoke meter specifications, and the key questions for further study are given. The most promising smoke meter technique analyzed was MODTRAN, which is a variation on a direct transmission measurement. The soot-laden gas is passed through a transmission cell, and the gas pressure is modulated by a speaker

Experiments and Simulations on Day-to-Day Route Choice-Behaviour

The paper reports laboratory experiments on a day-to-day route choice game with two routes. Subjects had to choose between a main road M and a side road S. The capacity was greater for the main road. 18 subjects participated in each session. In equilibrium the number of subjects is 12 on M and 6 on S. Two treatments with 6 sessions each were run at the Laboratory of Experimental Economics at Bonn University using RatImage. Feedback was given in treatment I only about own travel time and in treatment II on travel time for M and S. Money payoffs increase with decreasing time. The main results are as follows. 1. Mean numbers on M and S are very near to the equilibrium. 2. Fluctuations persist until the end of the sessions in both treatments. 3. Fluctuations are smaller under treatment II .The effect is small but significant. 4. The total number of changes is significantly greater in treatment I. 5. Subjects’ road changes and payoffs are negatively correlated in all sessions. 6. A direct response mode reacts with more changes for bad payoffs whereas a contrary response mode shows opposite reactions. Both response modes can be observed. 7. The simulation of an extended payoff sum learning model closely fits the main results of the statistical evaluation of the data.travel behaviour research, information in intelligent transportation systems, day-to-day route choice, laboratory experiments, payoff sum model

Chemical Kinetic Models for HCCI and Diesel Combustion

Predictive engine simulation models are needed to make rapid progress towards DOE's goals of increasing combustion engine efficiency and reducing pollutant emissions. These engine simulation models require chemical kinetic submodels to allow the prediction of the effect of fuel composition on engine performance and emissions. Chemical kinetic models for conventional and next-generation transportation fuels need to be developed so that engine simulation tools can predict fuel effects. The objectives are to: (1) Develop detailed chemical kinetic models for fuel components used in surrogate fuels for diesel and HCCI engines; (2) Develop surrogate fuel models to represent real fuels and model low temperature combustion strategies in HCCI and diesel engines that lead to low emissions and high efficiency; and (3) Characterize the role of fuel composition on low temperature combustion modes of advanced combustion engines

Experiments and Simulations on Day-to-Day Route Choice-Behaviour

The paper reports laboratory experiments on a day-to-day route choice game with two routes. Subjects had to choose between a main road M and a side road S. The capacity was greater for the main road. 18 subjects participated in each session. In equilibrium the number of subjects is 12 on M and 6 on S.Two treatments with 6 sessions each were run at the Laboratory of Experimental Economics at Bonn University using RatImage. Feedback was given in treatment I only about own travel time and in treatment II on travel time for M and S. Money payoffs increase with decreasing time. The main results are as follows. 1. Mean numbers on M and S are very near to the equilibrium. 2. Fluctuations persist until the end of the sessions in both treatments. 3. Fluctuations are smaller under treatment II .The effect is small but significant. 4. The total number of changes is significantly greater in treatment I. 5. Subjects' road changes and payoffs are negatively correlated in all sessions.6. A direct response mode reacts with more changes for bad payoffs whereas a contrary response mode shows opposite reactions. Both response modes can be observed. 7. The simulation of an extended payoff sum learning model closely fits the main results of the statistical evaluation of the data

Commuters route choice behaviour

The paper reports laboratory experiments with a two route choice scenario. In each session 18 subjects had to choose between a main road M and a side road S. The capacity of M was larger. Feedback was given in treatment I only on the subjects' own travel time and in treatment II on travel time for M and S. The main results are as follows: • Mean numbers on M and S are near to pure equilibrium. • Fluctuations persist until the end of the sessions. • The total number of changes is significantly greater in treatment I. • Subjects' road changes and payoffs are negatively correlated. • A direct response mode results in more changes for bad payoffs whereas a contrary response mode shows opposite reactions. • Simulations of an extended payoff sum learning model fits the main results of the statistical evaluation of the data

A flow cytometric assay to quantify \u3ci\u3ein vivo\u3c/i\u3e bacterial uptake by alveolar macrophages

Our laboratory has developed a flow cytometric assay to quantify alveolar macrophage (MФ) phagocytosis of bacteria within a live animal. MФs collected by bronchoalveolar lavage from rats infected transtracheally with Syto 9-labeled bacteria are fluorescently labeled for identification and analyzed by flow cytometry to quantify their bacterial uptake

Prevalence and Association of the Laboulbenialean Fungus \u3ci\u3eHesperomyces virescens\u3c/i\u3e (Laboulbeniales: Laboulbeniaceae) on Coccinellid Hosts (Coleoptera: Coccinellidae) in Kentucky, USA

The laboulbenialean fungi occur throughout the world and are closely associated with a range of arthropods, including many coleopteran hosts. Throughout the summer of 2004, coccinellids were collected from a Bluegrass savanna woodland ecosystem, dominated by blue ash Fraxinus quadrangulata and Chinkapin Oak Quercus muehlenbergii, and the adults were examined for the presence of Hesperomyces virescens using binocular and scanning electron microscopy. Over 80% of adult Harmonia axyridis, a species previously reported as having a persistent association with the fungus, were infected. No significant differences were observed in incidence on male and female hosts, however, the distribution of fungus differed between sexes. Female H. axyridis had a greater percentage of infection on their elytron compared to other parts of their body whilst male infection was concentrated around their elytra, legs and abdomen. Although infection rates were significantly lower, we report, for the first time, the presence of this fungus on the hosts Cycloneda munda, Brachiacantha quadripunctata and Psyllobora vigintimaculata. This is the first study documenting the incidence of this insect-associated fungus with these native coccinellids of North America. In the samples collected from the Bluegrass savanna, two species (Coleomegilla maculata and Hyperaspis signata) were not infected by this fungus

Orbital M1 versus E2 strength in deformed nuclei: A new energy weighted sum rule

Within the unified model of Bohr and Mottelson we derive the following linear energy weighted sum rule for low energy orbital 1$^+$ excitations in even-even deformed nuclei S_{\rm LE}^{\rm lew} (M_1^{\rm orb}) \cong (6/5) \epsilon (B(E2; 0^+_1 \rightarrow 2_1^+ K=0)/Z e^2^2) \mu^2_N with B(E2) the E2 strength for the transition from the ground state to the first excited state in the ground state rotational band, $$ the charge r.m.s. radius squared and $\epsilon$ the binding energy per nucleon in the nuclear ground state. It is shown that this energy weighted sum rule is in good agreement with available experimental data. The sum rule is derived using a simple ansatz for the intrinsic ground state wave function that predicts also high energy 1$^+$ strength at 2$\hbar \omega$ carrying 50\% of the total $m_1$ moment of the orbital M1 operator.Comment: REVTEX (3.0), 9 pages, RU924

Particle number size distributions in urban air before and after volatilisation

Aerosol particle number size distributions (size range 0.003–10 μm) in the urban atmosphere of Augsburg (Germany) were examined with respect to the governing anthropogenic sources and meteorological factors. The two-year average particle number concentration between November 2004 and November 2006 was 12 200 cm−3, i.e. similar to previous observations in other European cities. A seasonal analysis yielded twice the total particle number concentrations in winter as compared to summer as consequence of more frequent inversion situations and enhanced particulate emissions. The diurnal variations of particle number were shaped by a remarkable maximum in the morning during the peak traffic hours. After a mid-day decrease along with the onset of vertical mixing, an evening concentration maximum could frequently be observed, suggesting a re-stratification of the urban atmosphere. Overall, the mixed layer height turned out to be the most influential meteorological parameter on the particle size distribution. Its influence was even greater than that of the geographical origin of the prevailing synoptic-scale air mass. Size distributions below 0.8 μm were also measured downstream of a thermodenuder (temperature: 300 °C), allowing to retrieve the volume concentration of non-volatile compounds. The balance of particle number upstream and downstream of the thermodenuder suggests that practically all particles >12 nm contain a non-volatile core while additional nucleation of particles smaller than 6 nm could be observed after the thermodenuder as an interfering artifact of the method. The good correlation between the non-volatile volume concentration and an independent measurement of the aerosol absorption coefficient (R2=0.9) suggests a close correspondence of the refractory and light-absorbing particle fractions. Using the "summation method", an average diameter ratio of particles before and after volatilisation could be determined as a function of particle size. The results indicated that particles >60 nm contain a significantly higher fraction of non-volatile compounds, most likely black carbon, than particles <60 nm. The results are relevant for future health-related studies in that they explore the size distribution and time-dependent behaviour of the refractory component of the urban aerosol over an extended time period