523 research outputs found
Molecular random tilings as glasses
We have recently shown [Blunt et al., Science 322, 1077 (2008)] that
p-terphenyl-3,5,3',5'-tetracarboxylic acid adsorbed on graphite self-assembles
into a two-dimensional rhombus random tiling. This tiling is close to ideal,
displaying long range correlations punctuated by sparse localised tiling
defects. In this paper we explore the analogy between dynamic arrest in this
type of random tilings and that of structural glasses. We show that the
structural relaxation of these systems is via the propagation--reaction of
tiling defects, giving rise to dynamic heterogeneity. We study the scaling
properties of the dynamics, and discuss connections with kinetically
constrained models of glasses.Comment: 5 pages, 5 figure
Critical point network for drainage between rough surfaces
In this paper, we present a network method for computing two-phase flows between two rough surfaces with significant contact areas. Low-capillary number drainage is investigated here since one-phase flows have been previously investigated in other contributions. An invasion percolation algorithm is presented for modeling slow displacement of a wetting fluid by a non wetting one between two rough surfaces. Short-correlated Gaussian process is used to model random rough surfaces.The algorithm is based on a network description of the fracture aperture field. The network is constructed from the identification of critical points (saddles and maxima) of the aperture field. The invasion potential is determined from examining drainage process in a flat mini-channel. A direct comparison between numerical prediction and experimental visualizations on an identical geometry has been performed for one realization of an artificial fracture with a moderate fractional contact area of about 0.3. A good agreement is found between predictions and observations
Broken symmetry and the variation of critical properties in the phase behaviour of supramolecular rhombus tilings
The degree of randomness, or partial order, present in two-dimensional
supramolecular arrays of isophthalate tetracarboxylic acids is shown to vary
due to subtle chemical changes such as the choice of solvent or small
differences in molecular dimensions. This variation may be quantified using an
order parameter and reveals a novel phase behaviour including random tiling
with varying critical properties as well as ordered phases dominated by either
parallel or non-parallel alignment of neighbouring molecules, consistent with
long-standing theoretical studies. The balance between order and randomness is
driven by small differences in the intermolecular interaction energies, which
we show, using numerical simulations, can be related to the measured order
parameter. Significant variations occur even when the energy difference is much
less than the thermal energy highlighting the delicate balance between entropic
and energetic effects in complex self-assembly processes
Simulating temporal evolution of pressure in two-phase flow in porous media
We have simulated the temporal evolution of pressure due to capillary and
viscous forces in two-phase drainage in porous media. We analyze our result in
light of macroscopic flow equations for two-phase flow. We also investigate the
effect of the trapped clusters on the pressure evolution and on the effective
permeability of the system. We find that the capillary forces play an important
role during the displacements for both fast and slow injection rates and both
when the invading fluid is more or less viscous than the defending fluid. The
simulations are based on a network simulator modeling two-phase drainage
displacements on a two-dimensional lattice of tubes.Comment: 12 pages, LaTeX, 14 figures, Postscrip
Nonequilibrium dynamics of fully frustrated Ising models at T=0
We consider two fully frustrated Ising models: the antiferromagnetic
triangular model in a field of strength, , as well as the Villain
model on the square lattice. After a quench from a disordered initial state to
T=0 we study the nonequilibrium dynamics of both models by Monte Carlo
simulations. In a finite system of linear size, , we define and measure
sample dependent "first passage time", , which is the number of Monte
Carlo steps until the energy is relaxed to the ground-state value. The
distribution of , in particular its mean value, , is shown to
obey the scaling relation, , for both models.
Scaling of the autocorrelation function of the antiferromagnetic triangular
model is shown to involve logarithmic corrections, both at H=0 and at the
field-induced Kosterlitz-Thouless transition, however the autocorrelation
exponent is found to be dependent.Comment: 7 pages, 8 figure
Pipe network model for scaling of dynamic interfaces in porous media
We present a numerical study on the dynamics of imbibition fronts in porous
media using a pipe network model. This model quantitatively reproduces the
anomalous scaling behavior found in imbibition experiments [Phys. Rev. E {\bf
52}, 5166 (1995)]. Using simple scaling arguments, we derive a new identity
among the scaling exponents in agreement with the experimental results.Comment: 13 pages, 3 figures, REVTeX, to appear in Phys. Rev. Let
Viscous stabilization of 2D drainage displacements with trapping
We investigate the stabilization mechanisms due to viscous forces in the
invasion front during drainage displacement in two-dimensional porous media
using a network simulator. We find that in horizontal displacement the
capillary pressure difference between two different points along the front
varies almost linearly as function of height separation in the direction of the
displacement. The numerical result supports arguments taking into account the
loopless displacement pattern where nonwetting fluid flow in separate strands
(paths). As a consequence, we show that existing theories developed for viscous
stabilization, are not compatible with drainage when loopless strands dominate
the displacement process.Comment: The manuscript has been substantially revised. Accepted in Phys. Rev.
Let
Front instabilities in evaporatively dewetting nanofluids
Various experimental settings that involve drying solutions or suspensions of
nanoparticles -- often called nanofluids -- have recently been used to produce
structured nanoparticle layers. In addition to the formation of polygonal
networks and spinodal-like patterns, the occurrence of branched structures has
been reported. After reviewing the experimental results we use a modified
version of the Monte Carlo model first introduced by Rabani et al. [Nature 426,
271 (2003)] to study structure formation in evaporating films of nanoparticle
solutions for the case that all structuring is driven by the interplay of
evaporating solvent and diffusing nanoparticles.
After introducing the model and its general behavior we focus on receding
dewetting fronts which are initially straight but develop a transverse
fingering instability. We analyze the dependence of the characteristics of the
resulting branching patterns on the driving chemical potential, the mobility
and concentration of the nanoparticles, and the interaction strength between
liquid and nanoparticles. This allows us to understand the underlying
instability mechanism.Comment: 35 pages, 28 figure
Pore Scale Observations of Trapped CO2 in Mixed-Wet Carbonate Rock: Applications to Storage in Oil Fields
Geographically touring the eastern bloc: British geography, travel cultures and the Cold War
This paper considers the role of travel in the generation of geographical knowledge of the eastern bloc by British geographers. Based on oral history and surveys of published work, the paper examines the roles of three kinds of travel experience: individual private travels, tours via state tourist agencies, and tours by academic delegations. Examples are drawn from across the eastern bloc, including the USSR, Poland, Romania, East Germany and Albania. The relationship between travel and publication is addressed, notably within textbooks, and in the Geographical Magazine. The study argues for the extension of accounts of cultures of geographical travel, and seeks to supplement the existing historiography of Cold War geography
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