Investigating the Utility of Hyperspectral Sounders in the 9.6 m Band to Improve Ozone Analyses

Currently, hyperspectral sounder brightness temperatures assimilated in the Goddard Earth Observing System - Atmospheric Data Assimilation System (GEOS-ADAS) are limited to assimilating temperature and moisture. The ozone sensitive 9.6 micron region is sensed by several hyperspectral sounders including AIRS (Atmospheric InfraRed Sounder), IASI (Infrared Atmospheric Sounding Interferometer), and CrIS (Cross-track Infrared Sounder). Direct assimilation of brightness temperatures in the 9.6 micron region have been used previously to improve ozone analyses. This has recently been achieved by ECMWF (European Centre for Medium-Range Weather Forecast) (Dragani and McNally, 2013; Eresmaa et al., 2017), and while every system presents its challenges, it should be possible to take advantage of this spectral region using the GEOS-ADAS. For this study, channels were selected from available operational subsets evaluating information content, and minimizing inter-channel correlation. Additionally, information such as channel selections made by other studies, and vertical sensitivities of ozone and temperature were considered in developing the study. The analyses produced show improvements verified against ozonesondes taken from SHADOZ (Southern Hemisphere Additional Ozonesondes), and WOUDC (World Ozone and Ultraviolet Data Center). The addition of ozone channels does degrade forecast skill in the Tropics, on the border of statistical significance. Overall, the addition of these channels in some form could improve ozone analyses in the GEOS-ADAS

Single-shot carrier-envelope-phase measurement in ambient air

The ability to measure and control the carrier envelope phase (CEP) of few-cycle laser pulses is of paramount importance for both frequency metrology and attosecond science. Here, we present a phase meter relying on the CEP-dependent photocurrents induced by circularly polarized few-cycle pulses focused between electrodes in ambient air. The new device facilitates compact single-shot, CEP measurements under ambient conditions and promises CEP tagging at repetition rates orders of magnitude higher than most conventional CEP detection schemes as well as straightforward implementation at longer wavelengths

Kinetic phase diagram for CO oxidation on Pt(210): Pattern formation in the hysteresis and oscillation regions

The reactive behavior of catalytic CO oxidation on Pt(210) is studied by means of combined reaction rate measurements and photoelectron emission microscopy (PEEM). These methods allow an investigation of the phenomena at macroscopic and mesoscopic level, respectively. The external control parameters (flow rate, CO and oxygen partial pressures, surface temperature and scanning rates of pressure and temperature) are systematically varied to reveal various reactive regions in parameter space. The macroscopic measurements for a given temperature and flow rate (under isothermal conditions) show that lower pressures lead to a pronounced clockwise hysteresis in the production rate of CO2, while increasing pressures cause a systematic narrowing leading to a crossing of the two hysteresis branches into a region of counterclockwise hysteresis. A further pressure increase leads to macroscopic temporal oscillations. Mesoscopic spatiotemporal oscillations appear at the same conditions. The resulting macroscopic isothermal kinetic phase diagram exhibits a cross-shaped characteristic similar to that previously obtained for the Pd(110) surface. The mesoscopic lateral distribution of CO and oxygen adsorbed on the surface is monitored with the photoelectron emission microscope during the reaction at isothermal conditions and different constant oxygen pressures. The observed mesoscopic spatiotemporal patterns, such as islands, waves, target patterns and spirals, are correlated via the external control parameters with different regions in the macroscopic isothermal phase diagram. The results are compared with previous data of CO oxidation on other surfaces, like Pd(110) and Pt(110)

Macroscopic and mesoscopic characterization of a bistable reaction system: CO oxidation on Pt(111) surface

The catalytic oxidation of CO by oxygen on a platinum (111) single-crystal surface in a gas-flow reactor follows the Langmuir–Hinshelwood reaction mechanism. It exhibits two macroscopic stable steady states (low reactivity: CO-covered surface; high reactivity: O-covered surface), as determined by mass spectrometry. Unlike other Pt and Pd surface orientations no temporal and spatiotemporal oscillations are formed. Accordingly, CO+O/Pt(111) can be considered as one of the least complicated heterogeneous reaction systems. We measured both the macroscopic and mesoscopic reaction behavior by mass spectrometry and photoelectron emission microscopy (PEEM), respectively, and explored especially the region of the phase transition between low and high reactivity. We followed the rate-dependent width of an observed hysteresis in the reactivity and the kinetics of nucleation and growth of individual oxygen and CO islands using the PEEM technique. We were able to adjust conditions of the external control parameters which totally inhibited the motion of the reaction/diffusion front. By systematic variation of these conditions we could pinpoint a whole region of external control parameters in which the reaction/diffusion front does not move. Parallel model calculations suggest that the front is actually pinned by surface defects. In summary, our experiments and simulation reveal the existence of an “experimental” bistable region inside the “computed” bistable region of the reactivity diagram (S-shaped curve) leading to a novel dollar ($)-shaped curve

Perception of Nuclear Energy and Coal in France and the Netherlands

This study focuses on the perception of large scale application of nuclear energy and coal in the Netherlands and France. The application of these energy-sources and the risks and benefits are judged differently by various group in society. In Europe, France has the highest density of nuclear power plants and the Netherlands has one of the lowest. In both countries scientists and social scientists completed a questionnaire assessing the perception of the large scale application of both energy sources. Furthermore, a number of variables relating to the socio cultural and political circumstances were measured. The results indicate that the French had a higher risk perception and a more negative attitude toward nuclear power than the Dutch. But they also assess the benefits of the use of nuclear power to be higher. Explanations for these differences are discussed

Electro-optic characterization of synthesized infrared-visible light fields

The measurement and control of light field oscillations enable the study of ultrafast phenomena on sub-cycle time scales. Electro-optic sampling (EOS) is a powerful field characterization approach, in terms of both sensitivity and dynamic range, but it has not reached beyond infrared frequencies. Here, we show the synthesis of a sub-cycle infrared-visible pulse and subsequent complete electric field characterization using EOS. The sampled bandwidth spans from 700 nm to 2700 nm (428 to 110 THz). Tailored electric-field waveforms are generated with a two-channel field synthesizer in the infrared-visible range, with a full-width at half-maximum duration as short as 3.8 fs at a central wavelength of 1.7 µm (176 THz). EOS detection of the complete bandwidth of these waveforms extends it into the visible spectral range. To demonstrate the power of our approach, we use the sub-cycle transients to inject carriers in a thin quartz sample for nonlinear photoconductive field sampling with sub-femtosecond resolution

Weight status, BMI and physical fitness in polish youth: relationships between 1986 and 2016

One of the components affecting the level of health is physical fitness and diets, which is also considered the foundation of a healthy lifestyle. Methods: Samples by survey ranged from 871 to 1,417 (boys) and from 843 to 1,326 (girls). Speed (5 m run), agility (figure-8-run), explosive power (vertical jump), flexibility (stand and reach) and cardiovascular fitness (step test) were measured. The Body Mass Index (BMI) of each student was classified as Thin, Normal weight or Overweight/Obese (Owt/Ob) relative to International Obesity Task Force (IOTF) criteria. Fitness items were compared among weight status groups and across surveys with sex-specific analyses of covariance. Regressions of each fitness item on the BMI in the four surveys were done using linear and nonlinear quadratic models. Results: Performances on all fitness tests except flexibility were poorer among Owt/Ob compared to Normal and Thin youth, but performances on fitness tests within weight status groups did not differ consistently across surveys. Conclusions: Relationships between the BMI and fitness tests varied across surveys, but suggested reasonably consistent curvilinear relationships between fitness tests and the BMI among boys more so than girls.info:eu-repo/semantics/publishedVersio