AOC reduction by biologically active filtration

L'objectif de ce projet était de fournir un guide pratique de l'application des techniques de traitement biologique aux opérations de traitement actuel des eaux. Les études furent centrées sur la production d'une eau biologiquement équilibrée, sur la stabilité (l'équilibre) des désinfectants, et sur la formation moins importante de sous-produits désinfectants. Notamment, l'étude a montré que les procéssus biologiques peuvent satisfaire les besoins de la pratique aussi bien que les exigences régulatrices de l'industrie de l'eau.Le système de surveillance et de contrôle des niveaux du carbone organique assimilable (COA) des éffluents de la "Swimming River Treatment Plant" a montré que des données >100 µq/L pourraient expliquer d'une part, l'apparition des bactéries conformes dans le système de distribution et d'autre part la transgression potentielle des règlements récemment révisés de la "Limite Maximum de Contaminants de Coliformes" des Etats-Unis. L'optimum du traitement a été établi à 100 µg/L could be related to the occurrence of coliform bacteria in the distribution system. A treatment goal of <100 µg/L was established for biologically active treatment processes. Granular activated carbon (GAC) filters were found to support a larger bacterial population, and thus, provide better biological removal of AOC and total organic carton (TOC). All biologically active filters showed good performance relative to effluent turbidity levels, and headloss development. Preozonation of raw water increased AOC levels an average of 2.3 fold, and always increased filter effluent AOC levels relative to nonozonated water. Application of free chlorine to GAC filters did not inhibit biological activity. Application of chloramines to GAC filters showed a slight inhibitory affect relative to free chlorine. Effluent AOC levels averaged 82 µg/L at an EBCT of 5 min, and decreased to an average of 57 µg/L at 20 min EBCT. EBCT did affect TOC removals, with efficiencies averaging 29, 33, 42, and 51 % removal at EBCTs of 5, 10, 15 and 20 min, respectively. Trihalomethane formation potentials (THMFP) were related to TOC levels. Processes Chat decreased TOC levels also decreased THMFP. A preozonated GAC/sand filter (EBCT 10 min) achieved an annual average 54 % removal of THMFP precursors. Post disinfection of biologically treated effluents reduced HPC bacterial counts by 2-2.5log10. Post chlorination or chloramination of prechlorinated GAC/sand effluents resulted in a 20 %, or a 44 % (respectively) increase in AOC levels. Post disinfection of preozonated water resulted in small (<8%) AOC increases. Despite increases in AOC levels, prechlorinated water had lower AOC levels than preozonated water, even after post disinfection

Infrared Spectroscopic Study of Vibrational Modes across the Orthorhombic Tetragonal Phase Transition in Methylammonium Lead Halide Single Crystals

Single crystals of the methylammonium MA lead halides MAPbI3, MAPbBr3, and MAPbCl3 have been investigated using infrared spectroscopy with the aim of analyzing structural and dynamical aspects of processes that enable the ordering of the MA molecule in the orthorhombic crystal structure of these hybrid perovskites. Our temperature dependent studies were focused on the analysis of the CH NH rocking, C N stretching, and CH NH bending modes of the MA molecule in the 800 1750 cm 1 frequency range. They deliver a direct comparison of the behaviors of the three halides on crossing the orthorhombic tetragonal phase transition in MA lead halide single crystals. Drastic changes of all vibrational modes close to the phase transition were clearly observed. Additional spectral features that were not discussed previously are pointed out. The transformation of the two dimensional orthorhombic hydrogen bond layers into a more three dimensional arrangement in the tetragonal phase seems to be an important feature providing deeper insights into the mechanisms that lead to a free rotating MA molecule in the inorganic host structure. The change of the molecule site symmetry in the tetragonal crystal structure seems to be an important feature of the orthorhombic tetragonal phase transition. For low temperatures, it can be stated that the iodide is stronger influenced by hydrogen bonding than the bromide and the chlorid

A 12-month follow-up study of treating overweight schizophrenic patients with aripiprazole

Objective: To investigate the feasibility of switching overweight schizophrenic patients to aripiprazole and to assess the impact of 12 months of aripiprazole treatment on weight in routine practice. Method: This was a non-controlled cohort study in overweight schizophrenic patients. Data were collected before treatment with aripiprazole was started and at 12-month follow-up. Results: A total of 53 patients were included; of these 55% continued using aripiprazole for 12 months. Aripiprazole treatment for 12 months (P = 0.027) and stopping clozapine or olanzapine treatment (P = 0.038) predicted weight loss (>= 3 kg). Patients receiving aripiprazole monotherapy (n = 16, mean -3.0 kg) had similar weight loss than patients receiving aripiprazole in addition to another antipsychotic drug (n = 13, mean -4.4 kg). Conclusion: In routine practice once aripiprazole treatment was started, more than half of the patients remained on aripiprazole and most of them lost weight. Adding aripiprazole to clozapine gave similar weight loss as monotherapy with aripiprazole

Optical constants of Cu2ZnGeS4 bulk crystals

The dielectric functions of Cu2 ZnGeS4 bulk crystals grown by the Bridgman method were measured over the energy range 1.4 to 4.7 eV at room temperature using variable angle spectroscopic ellipsometry. The observed structures in the dielectric functions were adjusted using the Adachi's model and attributed to interband transitions E0, E1A, and E1B at :(000), N (A):2π /a (0.5 0.5 0.5), and T (Z):2π /a (0 0 0.5) points of the first Brillouin zone, respectively. The model parameters (threshold energy, strength, and broadening) have been determined using the simulated annealing algorithm. The decrease in the first gap, E0, has been attributed to a higher Ge-S hybridization. The spectral dependence of the complex refractive index, the absorption coefficient, and the normal-incidence reflectivity were also derived. © 2010 American Institute of Physics.Peer Reviewe

Routes to develop a [S]/([S]+[Se]) gradient in wide band-gap Cu2ZnGe(S,Se)4 thin-film solar cells

Wide band-gap kesterite-based solar cells are very attractive to be used for tandem devices as well as for semi-transparent photovoltaic cells. Here, Cu2ZnGe(S,Se)4 (CZGSSe) thin films have been grown by sulfurization of co-evaporated Cu2ZnGeSe4. The influence of a NaF precursor layer and of a Se capping film on CZGSSe absorbers and solar cells has been investigated. It has been found that the distribution of [S]/([S]+[Se]) through the CZGSSe absorber layer is strongly dependent on the Na content. Na promotes the diffusion of S towards the bulk of the absorber layer. Thicker NaF layers>6 nm lead to a higher S content in the bulk of the absorber layer, but to a decreased accumulation of sulphur at the surface, as detected by GIXRD, GD-OES, and Raman spectroscopy measurements. A relationship between Jsc, FF and Na-content supplied was found; higher Na content resulted in improved solar cell efficiencies. It has also been possible to modify the [S]/([S]+[Se])-gradient throughout the CZGSSe film by the absence of the Se capping layer, achieving devices with 2.7% performance and Eg = 2.0 eV. This work reveals two ways to control the [S]/([S]+[Se]) depth-profile to produce wide band gap CZGSSe absorber layers for efficient solar cells

The investigation of dangerous geological processes resulting in land subsidence while designing the main gas pipeline in South Yakutia

The number of gas main accidents has increased recently due to dangerous geological processes in underdeveloped areas located in difficult geological conditions. The paper analyses land subsidence caused by karst and thermokarst processes in the right of way, reveals the assessment criteria for geological hazards and creates zoning schemes considering the levels of karst and thermorkarst hazards

Structural characterization of off stoichiometric kesterite type Cu2ZnGeSe4 compound semiconductors from cation distribution to intrinsic point defect density

The substitution of Ge4 for Sn4 in Cu2ZnSn S,Se 4 CZTSSe kesterite type absorber layers for thin film solar cells has proven to enhance the opto electronic properties of the material. By cationic substitution, in general, the optical bandgap can be more readily designed for the purpose of bandgap engineering, and the substitution of Sn4 by Ge4 , in particular, widens the optical bandgap such that it can be employed both for photovoltaics as well as solar fuel quarrying by photocatalytic water splitting. This work is an experimental study of intrinsic point defects in off stoichiometric kesterite type Cu2ZnGeSe4 CZGSe by means of neutron powder diffraction. We revealed the existence of copper vacancies VCu , various cation antisite defects CuZn, ZnCu, ZnGe, CuGe as well as interstitials Cui, Zni in a wide range of off stoichiometric polycrystalline material synthesized by solid state reaction. In addition to the off stoichiometry type specific defects, Cu Zn disorder is always present in the kesterite type CZGSe phase. While compositional changes are clearly reflected by the tetragonal deformation c 2a, the lattice parameters a, c seem differently responding to point defect types and concentration variations, respectively. The CuGe antisite defect which is known to greatly deteriorate the opto electronic properties exists only in Cu rich CZGSe, but appears already in CZGSe with Cu Zn Ge amp; 8776;1. Furthermore we showed by diffuse reflectance hyperspectral imaging a widening of the energy bandgap in off stoichiometric kesterite type CZGSe with decreasing Cu Zn G

Structural and Optoelectronic Characterization of AgxCu1 x ZnSnSe4 solid solution

As the open circuit voltage in CZTSSe devices is believed to be limited by absorber band tailing caused by the exceptionally high density of Cu Zn disorder, replacing of Cu with Ag this density is predicted to drop. In this study, neutron diffraction and diffuse reflectance were applied to evaluate the crystal structure and optoelectronic properties of the Ag 1 x Cu x 2 ZnSnSe 4 solid solution ACZTSe . The results allow us to suggest that in spite of both end members of the solid solution being reported to crystallize in kesterite type structure, at least Ag 1 x Cu x 2 ZnSnSe4 with x 0.17 and 0.46 crystallize in the stannite type structure and thus block Cu Zn disorde

Antiperiodic dynamical 6-vertex model I: Complete spectrum by SOV, matrix elements of the identity on separate states and connections to the periodic 8-vertex model

The spin-1/2 highest weight representations of the dynamical 6-vertex and the standard 8-vertex Yang-Baxter algebra on a finite chain are considered in this paper. For the antiperiodic dynamical 6-vertex transfer matrix defined on chains with an odd number of sites, we adapt the Sklyanin's quantum separation of variable (SOV) method and explicitly construct SOV representations from the original space of representations. We provide the complete characterization of eigenvalues and eigenstates proving also the simplicity of its spectrum. Moreover, we characterize the matrix elements of the identity on separated states by determinant formulae. The matrices entering in these determinants have elements given by sums over the SOV spectrum of the product of the coefficients of separate states. This SOV analysis is not reduced to the case of the elliptic roots of unit and the results here derived define the required setup to extend to the dynamical 6-vertex model the approach recently developed in [1]-[5] to compute the form factors of the local operators in the SOV framework, these results will be presented in a future publication. For the periodic 8-vertex transfer matrix, we prove that its eigenvalues have to satisfy a fixed system of equations. In the case of a chain with an odd number of sites, this system of equations is the same entering in the SOV characterization of the antiperiodic dynamical 6-vertex transfer matrix spectrum. This implies that the set of the periodic 8-vertex eigenvalues is contained in the set of the antiperiodic dynamical 6-vertex eigenvalues. A criterion is introduced to find simultaneous eigenvalues of these two transfer matrices and associate to any of such eigenvalues one nonzero eigenstate of the periodic 8-vertex transfer matrix by using the SOV results. Moreover, a preliminary discussion on the degeneracy of the periodic 8-vertex spectrum is also presented.Comment: 36 pages, main modifications in section 3 and one appendix added, no result modified for the dynamical 6-vertex transfer matrix spectrum and the matrix elements of identity on separate states for chains with an odd number of site

The Interplay Between GUT and Flavour Symmetries in a Pati-Salam x S4 Model

Both Grand Unified symmetries and discrete flavour symmetries are appealing ways to describe apparent structures in the gauge and flavour sectors of the Standard Model. Both symmetries put constraints on the high energy behaviour of the theory. This can give rise to unexpected interplay when building models that possess both symmetries. We investigate on the possibility to combine a Pati-Salam model with the discrete flavour symmetry $S_4$ that gives rise to quark-lepton complementarity. Under appropriate assumptions at the GUT scale, the model reproduces fermion masses and mixings both in the quark and in the lepton sectors. We show that in particular the Higgs sector and the running Yukawa couplings are strongly affected by the combined constraints of the Grand Unified and family symmetries. This in turn reduces the phenomenologically viable parameter space, with high energy mass scales confined to a small region and some parameters in the neutrino sector slightly unnatural. In the allowed regions, we can reproduce the quark masses and the CKM matrix. In the lepton sector, we reproduce the charged lepton masses, including bottom-tau unification and the Georgi-Jarlskog relation as well as the two known angles of the PMNS matrix. The neutrino mass spectrum can present a normal or an inverse hierarchy, and only allowing the neutrino parameters to spread into a range of values between $\lambda^{-2}$ and $\lambda^2$, with $\lambda\simeq0.2$. Finally, our model suggests that the reactor mixing angle is close to its current experimental bound.Comment: 62 pages, 4 figures; references added, version accepted for publication in JHE