Desorption Dynamics of Heavy Alkali Metal Atoms (Rb, Cs) off the Surface of Helium Nanodroplets

We present a combined ion imaging and density functional theory study of the dynamics of the desorption process of rubidium and cesium atoms off the surface of helium nanodroplets upon excitation of the perturbed $6s$ and $7s$ states, respectively. Both experimental and theoretical results are well represented by the pseudodiatomic model for effective masses of the helium droplet in the desorption reaction of m_eff/m_He~10 (Rb) and 13 (Cs). Deviations from this model are found for Rb excited to the 6p state. Photoelectron spectra indicate that the dopant-droplet interaction induces relaxation into low-lying electronic states of the desorbed atoms in the course of the ejection process.Comment: in press, J. Phys. Chem. A (2014

Ca impurity in small mixed 4^4He-3^3He clusters

The structure of small mixed helium clusters doped with one calcium atom has been determined within the diffusion Monte Carlo framework. The results show that the calcium atom sits at the $^4$He-$^3$He interface. This is in agreement with previous studies, both experimental and theoretical, performed for large clusters. A comparison between the results obtained for the largest cluster we have considered for each isotope shows a clear tendency of the Ca atom to reside in a deep dimple at the surface of the cluster for $^4$He clusters, and to become fully solvated for $^3$He clusters. We have calculated the absorption spectrum of Ca around the $4s4p \leftarrow 4s^2$ transition and have found that it is blue-shifted from that of the free-atom transition by an amount that depends on the size and composition of the cluster.Comment: 24 pages, 11 figures. Accepted on Journal of Chemical Physic

Proximity effect-assisted absorption of spin currents in superconductors

The injection of pure spin current into superconductors by the dynamics of a ferromagnetic contact is studied theoretically. Taking into account suppression of the order parameter at the interfaces (inverse proximity effect) and the energy-dependence of spin-flip scattering, we determine the temperature-dependent ferromagnetic resonance linewidth broadening. Our results agree with recent experiments in Nb|permalloy bilayers [C. Bell et al., arXiv:cond-mat/0702461].Comment: 4 page

Seawater quality control of microcontaminants in fish farm cage systems: Application of passive sampling devices

Increasingly, developed countries are imposing restrictions on chemicals used in aquaculture, and introducing residue monitoring programmes to ensure the highest possible seafood safety standards. Chemotherapeutants, additives or chemical residues in edible tissues of aquaculture products are now attracting attention, and a major issue is the accumulation of microcontaminants in seafood flesh. Environmental quality control is related to the provision of high-quality, safe products. The present paper evaluates the effectiveness of passive sampling devices as tools in environmental monitoring programmes for fish farm cage systems. Capability to detect trace levels of microcontaminants, sampling rates, and accumulation kinetic is assessed. Devices tested were Polar Organic Chemical Integrative Samplers (POCIS), for detecting pharmaceuticals, pesticides and hormone residues; Semi-Permeable Membrane Devices (SPMD), to detect bioaccumulable pollutants; and Diffusive Gradients in Thin films (DGT), for metals.Las restricciones que imponen los países desarrollados al uso de sustancias químicas en la acuicultura para asegurar la salubridad de sus productos son cada vez mayores. También es creciente la preocupación por el control de los aditivos, residuos químicos o los preparados farmacéuticos que pudieran encontrarse en las partes comestibles de las especies acuícolas, así como la acumulación de micro-contaminantes en las mismas. En este trabajo se presenta un estudio sobre el uso de los sistemas de muestreo pasivo para los programas de control ambiental de las piscifactorías de jaulas flotantes. Se valora su capacidad de detectar niveles traza, la tasa de muestreo y la cinética de acumulación de micro-contaminantes. Se han probado los POCIS (Polar Organic Chemical Integrative Samplers) para detectar productos farmacéuticos, pesticidas y residuos hormonales, los SPMD (Semi-Permeable Membrane Devices) para detectar contaminantes bioacumulables y las membranas DGT (Diffusive Gradients in Thin films) para metales.Instituto Español de Oceanografí

Immediate and 24-h post-marathon cardiac troponin T is associated with relative exercise intensity

Purpose We aimed at exploring whether cardiopulmonary ftness, echocardiographic measures and relative exercise intensity were associated with high-sensitivity cardiac troponin T (hs-TNT) rise and normalization following a marathon. Methods Nighty-eight participants (83 men, 15 women; 38.72±3.63 years) were subjected to echocardiographic assessment and a cardiopulmonary exercise test (CPET) before the race. hs-TNT was measured before, immediately after and at 24, 48, 96, 144 and 192 h post-race. Speed and mean heart rate (HR) during the race were relativized to CPET values: peak speed (%VVMAX), peak HR (HR%MAX), speed and HR at the second ventilatory threshold (HR%VT2 and %VVT2). Results Hs-TNT increased from pre- to post-race (5.74±5.29 vs. 50.4±57.04 ng/L; p<0.001), seeing values above the Upper Reference Limit (URL) in 95% of the participants. At 24 h post-race, 39% of the runners still exceeded the URL (High hs-TNT group). hs-TNT rise was correlated with marathon speed %VVT2 (r=0.22; p=0.042), mean HR%VT2 (r=0.30; p=0.007), and mean HR%MAX (r=0.32; p=0.004). Moreover, the High hs-TNT group performed the marathon at a higher Speed %VVT2 (88.21±6.53 vs. 83.49±6.54%; p=0.002) and Speed %VVMAX (72±4.25 vs. 69.40±5.53%; p=0.009). hsTNT showed no signifcant associations with cardiopulmonary ftness and echocardiographic measures, except for a slight correlation with left ventricular end systolic diameter (r=0.26; p=0.018). Conclusion Post-race hs-TNT was above the URL in barely all runners. Magnitude of hs-TNT rise was correlated with exercise mean HR; whereas, its normalization kept relationship with marathon relative speed

Unravelling the size distribution of social groups with information theory in complex networks

The minimization of Fisher’s information (MFI) approach of Frieden et al. [Phys. Rev. E 60, 48 (1999)] is applied to the study of size distributions in social groups on the basis of a recently established analogy between scale invariant systems and classical gases [Phys. A 389, 490 (2010)]. Going beyond the ideal gas scenario is seen to be tantamount to simulating the interactions taking place, for a competitive cluster growth process, in a scale-free ideal; network – a non-correlated network with a connection-degree’s distribution that mimics the scale-free ideal gas density distribution. We use a scaling rule that allows one to classify the final cluster-size distributions using only one parameter that we call the competitiveness, which can be seen as a measure of the strength of the interactions. We find that both empirical; city-size distributions and electoral results can be thus reproduced and classified according to this competitiveness-parameter, that also allow us to infer the maximum number of stable social relationships that one person can maintain, known as the Dunbar number, together with its standard; deviation. We discuss the importance of this number in connection with the empirical phenomenon known as “six-degrees of separation”. Finally, we show that scaled city-size distributions of large countries follow, in general, the same universal distribution.Instituto de Física La Plat

Black holes have no short hair

We show that in all theories in which black hole hair has been discovered, the region with non-trivial structure of the non-linear matter fields must extend beyond 3/2 the horizon radius, independently of all other parameters present in the theory. We argue that this is a universal lower bound that applies in every theory where hair is present. This {\it no short hair conjecture} is then put forward as a more modest alternative to the original {\it no hair conjecture}, the validity of which now seems doubtful.Comment: Published in Physical Review Letters, 13 pages in Late

Galactic periodicity and the oscillating G model

We consider the model involving the oscillation of the effective gravitational constant that has been put forward in an attempt to reconcile the observed periodicity in the galaxy number distribution with the standard cosmological models. This model involves a highly nonlinear dynamics which we analyze numerically. We carry out a detailed study of the bound that nucleosynthesis imposes on this model. The analysis shows that for any assumed value for $\Omega$ (the total energy density) one can fix the value of $\Omega_{\rm bar}$ (the baryonic energy density) in such a way as to accommodate the observational constraints coming from the $^4{\rm He}$ primordial abundance. In particular, if we impose the inflationary value $\Omega=1$ the resulting baryonic energy density turns out to be $\Omega_{\rm bar}\sim 0.021$. This result lies in the very narrow range $0.016 \leq \Omega_{\rm bar} \leq 0.026$ allowed by the observed values of the primordial abundances of the other light elements. The remaining fraction of $\Omega$ corresponds to dark matter represented by a scalar field.Comment: Latex file 29 pages with no figures. Please contact M.Salgado for figures. A more careful study of the model appears in gr-qc/960603

On the Schroedinger Representation for a Scalar Field on Curved Spacetime

It is generally known that linear (free) field theories are one of the few QFT that are exactly soluble. In the Schroedinger functional description of a scalar field on flat Minkowski spacetime and for flat embeddings, it is known that the usual Fock representation is described by a Gaussian measure. In this paper, arbitrary globally hyperbolic space-times and embeddings of the Cauchy surface are considered. The classical structures relevant for quantization are used for constructing the Schroedinger representation in the general case. It is shown that in this case, the measure is also Gaussian. Possible implications for the program of canonical quantization of midisuperspace models are pointed out.Comment: 11 pages, Revtex, no figure

Determination of regulated and emerging mycotoxins in organic and conventional gluten-free flours by LC-MS/MS

Gluten-free cereal products have grown in popularity in recent years as they are perceived as “healthier” alternatives and can be safely consumed by celiac patients, and people with gluten intolerance or wheat allergies. Molds that produce mycotoxins contaminate cereal crops, posing a threat to global food security. Maximum levels have been set for certain mycotoxins in cereal flours; however, little is known about the levels of emerging mycotoxins in these flours. The aim of this study was to develop an efficient, sensitive, and selective method for the detection of four emerging (beauvericin and enniatins A1, B, and B1) and three regulated (aflatoxin B1, zearalenone, and deoxynivalenol) mycotoxins in gluten-free flours. Ultrasound-assisted matrix solid-phase dispersion was used in the extraction of these mycotoxins from flour samples. The validated method was utilized for the LC-MS/MS analysis of conventional and organic wholegrain oat and rice flours. Six of the seven target mycotoxins were detected in these samples. Multi-mycotoxin contamination was found in all flour types, particularly in conventional wholegrain oat flour. Despite the low detection frequency in rice flour, one sample was found to contain zearalenone at a concentration of 83.2 µg/kg, which was higher than the level set by the European Commission for cereal flours. The emerging mycotoxins had the highest detection frequencies; enniatin B was present in 53% of the samples at a maximum concentration of 56 µg/kg, followed by enniatin B1 and beauvericin, which were detected in 46% of the samples, and at levels reaching 21 µg/kg and 10 µg/kg, respectively. These results highlight the need to improve the current knowledge and regulations on the presence of mycotoxins, particularly emerging ones, in gluten-free flours and cereal-based product