Preparation and characterization of Bi26–2xMn2xMo10O69-d and Bi26.4Mn0.6Mo10–2yMe2yO69-d(Me = V, Fe) solid solutions

Received: 06.06.2017; accepted: 23.06.2017; published: 14.07.2017.Single phase samples of bismuth molybdate, Bi26Mo10O69, doped with Mn on the bismuth sublattice and V, Fe on the molybdenum sublattice were found to crystallize in the triclinic Bi26Mo10O69 structure at low doping levels and in the monoclinic Bi26Mo10O69 structure - at higher dopant concentration. The assumption that all Mn ions have an oxidation state of +2 was confirmed by means of magnetic measurement results analysis using Curie-Weiss law. Conductivity was investigated using impedance spectroscopy. The conductivity of Bi26.4Mn0.6Mo9.6Fe0.4O69-d was 1.2*10-2 S*cm-1 at 973 K and 2.2*10-4 S*cm-1 at 623 K, and the conductivity of Bi26.4Mn0.6Mo9.2V0.8O69-d was 2.2*10-3 S*cm-1 at 973 K and 2.2*10-5 S*cm-1 at 623 K

NMR and LDA evidence for spiral magnetic order in the chain cuprate LiCu2O2

We report on {6,7}Li nuclear magnetic resonance measurements of the spin-chain compound LiCu2O2 in the paramagnetic and magnetically ordered states. Below T about 24 K the NMR lineshape presents a clear signature of incommensurate (IC) static modulation of the local magnetic field consistent with an IC spiral modulation of the magnetic moments. {7}Li NMR reveals strong phason-like dynamical fluctuations extending well below 24 K. We hypothesize that a series of phase transitions at 24.2, 22.5, and 9 K reflects a "Devil's staircase" type behavior generic for IC systems. LDA based calculations of exchange integrals reveal a large in-chain frustration leading to a magnetical spiral.Comment: 4 pages, 4 figure

Crystal structure and conductivity of bismuth-containing complex oxides

In the paper, a comprehensive systematic study of different classes of bismuth containing oxide compounds was carried out. The relationship between composition, temperature and concentration regions of existence of stable, specific structure and properties of solid solutions on the basis of vanadates, molybdates, niobates and bismuth was found. The general regularities of synthesis of solid solutions with different variants of solid-phase and soluble methods were determined. On this basis, the optimal conditions for obtaining single-phase materials were formulated. For the first time the temperature and concentration boundaries of the regions of homogeneity and areas of stable existence of polymorphic modifications of solid solutions were defined and/or refined. The structural parameters of the synthesized phases were determined. By the method of electrochemical impedance spectroscopy the nature and features of impedance spectra, the temperature and concentration dependences of electrical conductivity of ceramic materials based on bismuth containing complex oxides were identified

Correction of artificial jumps in the historical geomagnetic measurements of Coimbra Observatory, Portugal

The Coimbra Magnetic Observatory (International Association of Geomagnetism and Aeronomy code COI) in Portugal has a long history of observation of the geomagnetic field, spanning almost 150 yr since the first geomagnetic measurements in 1866. These long instrumental geomagnetic records provide very important information about variability of geomagnetic elements and indices, their trends and cycles, and can be used to improve our knowledge on the sources that drive variations of the geomagnetic field: liquid core dynamics (internal) and solar forcing (external). <br><br> However, during the long life of the Coimbra Observatory, some inevitable changes in station location, instrument's park and electromagnetic environment have taken place. These changes affected the quality of the data collected at COI causing breaks and jumps in the series of geomagnetic field components and local K index. Clearly, these inhomogeneities, typically shift-like (step-like) or trend-like, have to be corrected or, at least, minimized in order for the data to be used in scientific studies or to be submitted to international databases. <br><br> In this study, the series of local K index and declination of the geomagnetic field are analysed: the former because it allows direct application of standard homogenization methods and the latter because it is the longest continuous series produced at COI. For the homogenization, visual and statistical tests (e.g. standard normal homogeneity test) have been applied directly to the local geomagnetic K index series (from 1951 to 2012). The homogenization of the monthly averages of declination (from 1867 to 2012) has been done using visual analysis and statistical tests applied to the time series of the first differences of declination values, as an approximation to the first time derivative. This allowed not only estimating the level of inhomogeneity of the studied series but also detecting the highly probable homogeneity break points. These points have been cross-checked with the metadata, and the COI series have been compared with reference series from the nearest geomagnetic stations and, in the case of declination series, from the recent geomagnetic field model COV-OBS to set up the required correction factors. As a result, the homogenized series measured in COI are considered to be essentially free of artificial shifts starting from the second half of the 20th century, and ready to be used by the scientific community

Grain sizes and dislocation densities in fcc-metallic materials processed by warm to hot working

Our just received results on the deformation microstructures evolved in a mediumMn austenitic steel during large strain warm to hot rolling were analyzed with a reference to other alloys with face centred cubic lattices and relatively low stacking fault energies. The structural changes were characterized by the development of dynamic recovery (DRV) and dynamic recrystallization (DRX). The deformation grain size decreased while the dislocation density increased with a decrease in deformation temperatur

The χ2\chi^2 - divergence and Mixing times of quantum Markov processes

We introduce quantum versions of the $\chi^2$-divergence, provide a detailed analysis of their properties, and apply them in the investigation of mixing times of quantum Markov processes. An approach similar to the one presented in [1-3] for classical Markov chains is taken to bound the trace-distance from the steady state of a quantum processes. A strict spectral bound to the convergence rate can be given for time-discrete as well as for time-continuous quantum Markov processes. Furthermore the contractive behavior of the $\chi^2$-divergence under the action of a completely positive map is investigated and contrasted to the contraction of the trace norm. In this context we analyse different versions of quantum detailed balance and, finally, give a geometric conductance bound to the convergence rate for unital quantum Markov processes

Influence of thiamine injections on the folic acid balance in white rats organism

The interaction of thiamine and folic acid in the organism of white rats were carried out under intramuscular injections of thiamine. The research was conducted on 120 white Wistar rats weighing 150-200 g, which were divided into two groups, one was injected with thiamine, and the second was a control group. All animals were obtained the standard ration of the vivarium.After intramuscular injections of thiamine in dose 1 mg/kg mass it was established, that folic acid content after 60-240 min after injection decrease in small intestine and muscles of animals. Meanwhile, this indication in liver and blood increased.These data achieve that thiamine injection leads to changes of folic acid content in different tissue