Corrigendum to "Fractional release factors of long-lived halogenated organic compounds in the tropical stratosphere" published in Atmos. Chem. Phys., 10, 1093–1103, 2010

We have noted a computational error in the calculation of the averaged Fractional Release Factors (FRFs) relative to the averaged FRF of CFCl3 (CFC-11). ..

Southern hemispheric halon trends and global halon emissions, 1978–2011

The atmospheric records of four halons, H-1211 (CBrClF2), H-1301 (CBrF3), H-2402 (CBrF2CBrF2) and H-1202 (CBr2F2), measured from air collected at Cape Grim, Tasmania, between 1978 and 2011, are reported. Mixing ratios of H-1211, H-2402 and H-1202 began to decline in the early to mid-2000s, but those of H-1301 continue to increase up to mid-2011. These trends are compared to those reported by NOAA (National Oceanic and Atmospheric Administration) and AGAGE (Advanced Global Atmospheric Experiment). The observations suggest that the contribution of the halons to total tropospheric bromine at Cape Grim has begun to decline from a peak in 2008 of about 8.1 ppt. An extrapolation of halon mixing ratios to 2060, based on reported banks and predicted release factors, shows this decline becoming more rapid in the coming decades, with a contribution to total tropospheric bromine of about 3 ppt in 2060. Top-down global annual emissions of the halons were derived using a two-dimensional atmospheric model. The emissions of all four have decreased since peaking in the late 1980s–mid-1990s, but this decline has slowed recently, particularly for H-1301 and H-2402 which have shown no decrease in emissions over the past five years. The UEA (University of East Anglia) top-down model-derived emissions are compared to those reported using a top-down approach by NOAA and AGAGE and the bottom-up estimates of HTOC (Halons Technical Options Committee). The implications of an alternative set of steady-state atmospheric lifetimes are discussed. Using a lifetime of 14 yr or less for H-1211 to calculate top-down emissions estimates would lead to small, or even negative, estimated banks given reported production data. Finally emissions of H-1202, a product of over-bromination during the production process of H-1211, have continued despite reported production of H-1211 ceasing in 2010. This raises questions as to the source of these H-1202 emissions

Mining candidate causal relationships in movement patterns

This is an Accepted Manuscript of an article published by Taylor & Francis in the International Journal of Geographical Information Science on 01 October 2013, available online: http://wwww.tandfonline.com/10.1080/13658816.2013.841167In many applications, the environmental context for, and drivers of movement patterns are just as important as the patterns themselves. This paper adapts standard data mining techniques, combined with a foundational ontology of causation, with the objective of helping domain experts identify candidate causal relationships between movement patterns and their environmental context. In addition to data about movement and its dynamic environmental context, our approach requires as input definitions of the states and events of interest. The technique outputs causal and causal-like relationships of potential interest, along with associated measures of support and confidence. As a validation of our approach, the analysis is applied to real data about fish movement in the Murray River in Australia. The results demonstrate the technique is capable of identifying statistically significant patterns of movement indicative of causal and causal-like relationships. 1365-8816Australian Research Council Discovery Projec

Increasing concentrations of dichloromethane, CH2Cl2, inferred from CARIBIC air samples collected 1998–2012

Atmospheric concentrations of dichloromethane, CH2Cl2, a regulated toxic air pollutant and minor contributor to stratospheric ozone depletion, were reported to have peaked around 1990 and to be declining in the early part of the 21st century. Recent observations suggest this trend has reversed and that CH2Cl2 is once again increasing in the atmosphere. Despite the importance of ongoing monitoring and reporting of atmospheric CH2Cl2, no time series has been discussed in detail since 2006. The CARIBIC project (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container) has analysed the halocarbon content of whole-air samples collected at altitudes of between ~10–12 km via a custom-built container installed on commercial passenger aircraft since 1998, providing a long-term record of CH2Cl2 observations. In this paper we present this unique CH2Cl2 time series, discussing key flight routes which have been used at various times over the past 15 years. Between 1998 and 2012 increases were seen in all northern hemispheric regions and at different altitudes, ranging from ~7–10 ppt in background air to ~13–15 ppt in regions with stronger emissions (equating to a 38–69% increase). Of particular interest is the rising importance of India as a source of atmospheric CH2Cl2: based on CARIBIC data we provide regional emission estimates for the Indian subcontinent and show that regional emissions have increased from 3–14 Gg yr^-1 (1998–2000) to 16–25 Gg yr^-1 (2008). Potential causes of the increasing atmospheric burden of CH2Cl2 are discussed. One possible source is the increased use of CH2Cl2 as a feedstock for the production of HFC-32, a chemical used predominantly as a replacement for ozone-depleting substances in a variety of applications including air conditioners and refrigeration

Tunneling properties at the interface between superconducting Sr2RuO4 and a Ru micro-inclusion

We have investigated the magnetic field and temperature dependence of the tunneling spectra of the eutectic system Sr2RuO4-Ru. Electric contacts to individual Ru lamellae embedded in Sr2RuO4 enable the tunneling spectra at the interface between ruthenate and a Ru microinclusion to be measured. A zero bias conductance peak (ZBCP) was observed in the bias voltage dependence of the differential conductance, suggesting that Andreev bound states are present at the interface. The ZBCP starts to appear at a temperature well below the superconducting transition temperature. The onset magnetic field of the ZBCP is also considerably smaller than the upper critical field when the magnetic field is parallel to the ab-plane. We propose that the difference between the onset of the ZBCP and the onset of superconductivity can be understood in terms of the existence of the single-component state predicted by Sigrist and Monien.Comment: 4 pages, 4 figures, to appear in J. Phys. Soc. Jpn. vol. 74 no.

The Effect of Al on the Formation of a CrTaO₄ Layer in Refractory High Entropy Alloys Ta-Mo-Cr-Ti-xAl

In this study, the effect of Al on the high temperature oxidation of Al-containing refractory high entropy alloys (RHEAs) Ta-Mo-Cr-Ti-xAl (x = 5; 10; 15; 20 at%) was examined. Oxidation experiments were performed in air for 24 h at 1200 °C. The oxidation kinetics of the alloy with 5 at% Al is notably affected by the formation of gaseous MoO3 and CrO3, while continuous mass gain was detected for alloys with the higher Al concentrations. The alloys with 15 and 20 at% Al form relatively thin oxide scales and a zone of internal corrosion due to the formation of dense CrTaO4 scales at the interface oxide/substrate. The alloys with 5 and 10 at% Al exhibit, on the contrary, thick and porous oxide scales because of fast growing Ta2O5. The positive influence of Al on the formation of Cr2O3 followed by the growth of CrTaO4 to yield a compact scale is explained by getter and nucleation effects

A record of carbonyl sulfide from Antarctic ice over the last 1000 years

Carbonyl sulfide (COS) is a trace gas, present in the troposphere, and also in the stratosphere, where it contributes to the stratospheric sulfate aerosol layer. It has both natural and anthropogenic sources. Natural processes include uptake by plants, while oceans, wetlands, volcanism and biomass burning all contribute to natural COS emissions. We have measured COS in Antarctic ice cores from Dronning Maud Land, drilled in 1998, the DE08 core drilled at Law Dome in 1987, and the DSS0506 core drilled in 2006. Ice samples with COS gas ages between about 1050 AD and the early 20th centrury have been examined. A large volume ice crusher at the CSIRO Marine and Atmospheric Research laboratory was used to extract air from bubbles occluded in the ice cores. These air samples were analysed for CO2, CH4, CO and 13CO2 at CSIRO, and then for COS and several halocarbons at the University of East Anglia on a high sensitivity gas chromatograph/tri-sector mass spectrometer system. Initial results indicate that good sample integrity can be achieved. Measurements from the DML samples indicate low and uniform abundances across the last few hundred years, and at concentrations significantly below those in the modernday atmosphere. Measurements in more recent ice from DE08 show the start of increasing concentrations in the early 1900s, confirming earlier evidence that the global atmospheric abundance of COS has increased as a result of industrial activity during the 20th century