63 research outputs found

    The fluvial architecture of buried floodplain sediments of the Weiße Elster River (Germany) revealed by a novel method combination of drill cores with two‐dimensional and spatially resolved geophysical measurements

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    The complex and non-linear fluvial river dynamics are characterized by repeated periods of fluvial erosion and re-deposition in different parts of the floodplain. Understanding the fluvial architecture (i.e. the three-dimensional arrangement and genetic interconnectedness of different sediment types) is therefore fundamental to obtain well-based information about controlling factors. However, investigating the fluvial architecture in buried floodplain deposits without natural exposures is challenging. We studied the fluvial architecture of the middle Weiße Elster floodplain in Central Germany, an extraordinary long-standing archive of Holocene flooding and landscape changes in sensitive loess-covered Central European landscapes. We applied a novel systematic approach by coupling two-dimensional transects of electrical resistivity tomography (ERT) measurements and closely spaced core drillings with spatially resolved measurements of electromagnetic induction (EMI) of larger floodplain areas at three study sites. This allowed for (i) time and cost-efficient core drillings based on preceding ERT measurements and (ii) spatially scaling up the main elements of the fluvial architecture, such as the distribution of thick silt-clay overbank deposits and paleochannel patterns from the floodplain transects to larger surrounding areas. We found that fine-grained sand and silt-clay overbank deposits overlying basal gravels were deposited during several periods of intensive flooding. Those were separated from each other by periods of reduced flooding, allowing soil formation. However, the overbank deposits were severely laterally eroded before and during each sedimentation period. This was probably linked with pronounced meandering or even braiding of the river. Our preliminary chronological classification suggests that first fine-grained sedimentation must have occurred during the Early to Middle Holocene, and the last phase of lateral erosion and sedimentation during the Little Ice Age. Our study demonstrates the high archive potential of the buried fluvial sediments of the middle Weiße Elster floodplain and provides a promising time and cost-effective approach for future studies of buried floodplain sediments

    Homogenous Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles: Scope and Mechanistic Studies

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    Über einige neue Derivate der TrichloracrylsĂ€ure

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    Unraveling Location Choice Motives of Castles in the Gorecht seigniory

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    Castle siting has been a less popular theme in castellology; traditional military motives are often used to explain the location choice of castles by applying modern visions on the medieval society. This article tries therefore to unravel the factors that influenced castle siting by (i) creating a model of the medieval landscape, (ii) examining the written sources and (iii) discussing the material remains in the Gorecht seigniory during 1200-1450 AD. Analyzing the data of different disciplines has revealed that active as well as passive stream valleys and infrastructure, especially crossings with jurisdiction borders, were popular spots in the landscape during the entire research period. In addition, interpretation of contemporary sources has shown that the clients were indeed conscious about the jurisdiction borders and that some sites do fit into the traditional vision. Yet, other motives such as hydraulic reasons must be taken into account too, as is shown by the example of the Gronenburg castle

    Structure of the elusive hydrido(methylcyclopentadienyl)dicarbonylmanganate(I) anion, [(η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>Me)Mn(CO)<sub>2</sub>H]-, as determined by single-crystal X-ray diffraction

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    The structure of [K(18-crown-6)][(η5-C5H4Me)Mn(CO)2H] has been determined by single-crystal X-ray diffraction, and the anion is found to adopt a three-legged piano-stool geometry. Its structure is compared with those of related bridging hydride and σ-bond complexes
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