Decoy States and Two Way Quantum Key Distribution Schemes

We study the possible application of the decoy state method on a basic two way quantum key distribution (QKD) scheme to extend its distance. Noting the obvious advantage of such a QKD scheme in allowing for single as well as double photon contributions, we derive relevant lower-bounds on the corresponding gains in a practical decoy state implementation using two intensities for decoy states. We work with two different approaches in this vein and compare these with an ideal infinite decoy state case as well as the simulation of the original.Comment: Much revised from original manuscript. Accepted for publication in Optics Communications (some variations may exist in some wordings in the text

Hamiltonians for one-way quantum repeaters

Quantum information degrades over distance due to the unavoidable imperfections of the transmission channels, with loss as the leading factor. This simple fact hinders quantum communication, as it relies on propagating quantum systems. A solution to this issue is to introduce quantum repeaters at regular intervals along a lossy channel, to revive the quantum signal. In this work we study unitary one-way quantum repeaters, which do not need to perform measurements and do not require quantum memories, and are therefore considerably simpler than other schemes. We introduce and analyze two methods to construct Hamiltonians that generate a repeater interaction that can beat the fundamental repeaterless key rate bound even in the presence of an additional coupling loss, with signals that contain only a handful of photons. The natural evolution of this work will be to approximate a repeater interaction by combining simple optical elements.Comment: 8 pages, 3 figure

Zero-Error Attacks and Detection Statistics in the Coherent One-Way Protocol for Quantum Cryptography

This is a study of the security of the Coherent One-Way (COW) protocol for quantum cryptography, proposed recently as a simple and fast experimental scheme. In the zero-error regime, the eavesdropper Eve can only take advantage of the losses in the transmission. We consider new attacks, based on unambiguous state discrimination, which perform better than the basic beam-splitting attack, but which can be detected by a careful analysis of the detection statistics. These results stress the importance of testing several statistical parameters in order to achieve higher rates of secret bits

Activity of Saccharomyces cerevisiae by Single Entity Electrochemistry

According to the Centers of Disease Control and Prevention, antibiotics decrease in effectiveness as bacteria gain resistance for previously treatable illnesses. Currently, antibiotic susceptibility is typically carried out via the Kirby-Bauer method. Even with automation, this process requires two incubation periods so a less time-consuming technique is desirable. Single entity electrochemistry (SEE) detects changes in current when collisions of individual particles at an ultramicroelectrode (UME) are linked with an electrochemical event. Our group has obtained step-like and spike-like responses of Saccharomyces cerevisiae at the UME surface as a result of adsorption and desorption, respectively. This response is due to the blocking of redox molecules from reaching UME surface and therefore related to several factors including particle geometry. We have used COMSOL software to model blocking events of a stationary particle on the UME. The cell was considered as a sphere to block diffusive flux of redox molecules with magnitude dependent upon location on the XY plane. Future work includes investigating conditions to select for adsorption so that electrochemical communication of cells may be observed using a two-mediator system for probing redox sites extra- and intracellularly. Upon completion of these studies, insights may be gained into collisional dynamics of cells at UMEs as well as real-time monitoring of cell metabolism using SEE.https://scholarscompass.vcu.edu/gradposters/1154/thumbnail.jp

Intra- and intercellular fluctuations in Min-protein dynamics decrease with cell length

Self-organization of proteins in space and time is of crucial importance for the functioning of cellular processes. Often, this organization takes place in the presence of strong random fluctuations due to the small number of molecules involved. We report on stochastic switching of the Min-protein distributions between the two cell halves in short Escherichia coli cells. A computational model provides strong evidence that the macroscopic switching is rooted in microscopic noise on the molecular scale. In longer bacteria, the switching turns into regular oscillations that are required for positioning of the division plane. As the pattern becomes more regular, cell-to-cell variability also lessens, indicating cell length-dependent regulation of Min-protein activity.Comment: Article and Supplementary Information: 26 pages, 12 figure

Entertainment-Education in the New Media Landscape: Stimulating Creative Engagement in Online Communities for Social and Behavioral Change

The Entertainment-Education (EE) strategy uses dramatic serials on radio or TV to motivate audiences to engage in behavioral changes to designed to improve safety, health and equality. This dissertation explores how the EE strategy can be extended to the Internet

Polyelectrolyte Assemblies: Fundamentals And Applications

Charged assemblies bearing opposite or complementary charges span natural (proteins, enzymes, DNA) to synthetic materials (surfactants, synthetic polyelectrolytes). Assembly is facilitated by electrostatic attraction and entropic release of counterions, and most often occurs in aqueous media. Notably decades ago, Michaels described synthetic polyelectrolyte complexes as brittle when dry but “leathery or rubberlike” when wet, which points to the strong effect of water on the mobility of a charged assembly. Here, the molecular origin of the glass transition is quantified for several charged macromolecular systems is investigated using calorimetry and molecular modeling as a function of water content. A general relationship is revealed as it holds for two completely different types of charged systems (pH- and salt-sensitive) and for both polyelectrolyte complexes and polyelectrolyte multilayers, which are made by different paths. This suggests that water facilitates the relaxation of charged assemblies by reducing attractions between oppositely charged intrinsic ion pairs. We further demonstrate the dual role of water and temperature in the dynamics of polyelectrolyte complexes by showing time-temperature and time-water superpositioning in a single polyelectrolyte complex system for the first time. With regard to applications, charged polymers can assemble with functional nanomaterials such as reduced graphene oxide or MXene sheets. These 2D nanomaterials are conductive, facilitating their application as sensors or electrodes for energy storage. Here, the nature of polyelectrolyte-2D nanomaterial assemblies is investigated as thin films. A reversibly stretchable MXene/polyelectrolyte strain sensor and humidity sensor is demonstrated, and the origin of this response is discussed. Also, mechanically robust graphene-based electrodes are presented as assemblies with nanoscale Kevlar