Nucleus Driven Electronic Pulsation

We derive and solve by the spectral method the equations for a neutral system of ultra-relativistic electrons that are compressed to the radius of the nucleus and subject to a driving force. This driving force can be thought of as originating from a nuclear breathing mode, a possibility we discuss in detail

Is the Sun Lighter than the Earth? Isotopic CO in the Photosphere, Viewed through the Lens of 3D Spectrum Synthesis

We consider the formation of solar infrared (2-6 micron) rovibrational bands of carbon monoxide (CO) in CO5BOLD 3D convection models, with the aim to refine abundances of the heavy isotopes of carbon (13C) and oxygen (18O,17O), to compare with direct capture measurements of solar wind light ions by the Genesis Discovery Mission. We find that previous, mainly 1D, analyses were systematically biased toward lower isotopic ratios (e.g., R23= 12C/13C), suggesting an isotopically "heavy" Sun contrary to accepted fractionation processes thought to have operated in the primitive solar nebula. The new 3D ratios for 13C and 18O are: R23= 91.4 +/- 1.3 (Rsun= 89.2); and R68= 511 +/- 10 (Rsun= 499), where the uncertainties are 1 sigma and "optimistic." We also obtained R67= 2738 +/- 118 (Rsun= 2632), but we caution that the observed 12C17O features are extremely weak. The new solar ratios for the oxygen isotopes fall between the terrestrial values and those reported by Genesis (R68= 530, R6= 2798), although including both within 2 sigma error flags, and go in the direction favoring recent theories for the oxygen isotope composition of Ca-Al inclusions (CAI) in primitive meteorites. While not a major focus of this work, we derive an oxygen abundance of 603 +/- 9 ppm (relative to hydrogen; 8.78 on the logarithmic H= 12 scale). That the Sun likely is lighter than the Earth, isotopically speaking, removes the necessity to invoke exotic fractionation processes during the early construction of the inner solar system

Modelling floods in the Ammer catchment: limitations and challenges with a coupled meteo-hydrological model approach

International audienceNumerous applications of hydrological models have shown their capability to simulate hydrological processes with a reasonable degree of certainty. For flood modelling, the quality of precipitation data ? the key input parameter ? is very important but often remains questionable. This paper presents a critical review of experience in the EU-funded RAPHAEL project. Different meteorological data sources were evaluated to assess their applicability for flood modelling and forecasting in the Bavarian pre-alpine catchment of the Ammer river (709 km2), for which the hydrological aspects of runoff production are described as well as the complex nature of floods. Apart from conventional rain gauge data, forecasts from several Numerical Weather Prediction Models (NWP) as well as rain radar data are examined, scaled and applied within the framework of a GIS-structured and physically based hydrological model. Multi-scenario results are compared and analysed. The synergetic approach leads to promising results under certain meteorological conditions but emphasises various drawbacks. At present, NWPs are the only source of rainfall forecasts (up to 96 hours) with large spatial coverage and high temporal resolution. On the other hand, the coarse spatial resolution of NWP grids cannot yet address, adequately, the heterogeneous structures of orographic rainfields in complex convective situations; hence, a major downscaling problem for mountain catchment applications is introduced. As shown for two selected Ammer flood events, a high variability in prediction accuracy has still to be accepted at present. Sensitivity analysis of both meteo-data input and hydrological model performance in terms of process description are discussed and positive conclusions have been drawn for future applications of an advanced meteo-hydro model synergy.</p

Field-induced structural aging in glasses at ultra low temperatures

In non-equilibrium experiments on the glasses Mylar and BK7, we measured the excess dielectric response after the temporary application of a strong electric bias field at mK--temperatures. A model recently developed describes the observed long time decays qualitatively for Mylar [PRL 90, 105501, S. Ludwig, P. Nalbach, D. Rosenberg, D. Osheroff], but fails for BK7. In contrast, our results on both samples can be described by including an additional mechanism to the mentioned model with temperature independent decay times of the excess dielectric response. As the origin of this novel process beyond the "tunneling model" we suggest bias field induced structural rearrangements of "tunneling states" that decay by quantum mechanical tunneling.Comment: 4 pages, 4 figures, accepted at PRL, corrected typos in version

Probing molecular interaction in ionic liquids by low frequency spectroscopy: Coulomb energy, hydrogen bonding and dispersion forces

Ionic liquids are defined as salts composed solely of ions with melting points below 100 °C. These remarkable liquids have unique and fascinating properties and offer new opportunities for science and technology. New combinations of ions provide changing physical properties and thus novel potential applications for this class of liquid materials. To a large extent, the structure and properties of ionic liquids are determined by the intermolecular interaction between anions and cations. In this perspective we show that far infrared and terahertz spectroscopy are suitable methods for studying the cation-anion interaction in these Coulomb fluids. The interpretation of the measured low frequency spectra is supported by density functional theory calculations and molecular dynamics simulations. We present results for selected aprotic and protic ionic liquids and their mixtures with molecular solvents. In particular, we focus on the strength and type of intermolecular interaction and how both parameters are influenced by the character of the ions and their combinations. We show that the total interaction between cations and anions is a result of a subtle balance between Coulomb forces, hydrogen bonds and dispersion forces. For protic ionic liquids we could measure distinct vibrational modes in the low frequency spectra indicating clearly the cation-anion interaction characterized by linear and medium to strong hydrogen bonds. Using isotopic substitution we have been able to dissect frequency shifts related to pure interaction strength between cations and anions and to different reduced masses only. In this context we also show how these different types of interaction may influence the physical properties of ionic liquids such as the melting point, viscosity or enthalpy of vaporization. Furthermore we demonstrate that low frequency spectroscopy can also be used for studying ion speciation. Low vibrational features can be assigned to contact ion pairs and solvent separated ion pairs. In conclusion we showed how detailed knowledge of the low frequency spectra can be used to understand the change in interaction strength and structure by variation of temperature, solvent polarity and solvent concentration in ionic liquids and their mixtures with molecular solvents. In principle the used combination of methods is suitable for studying intermolecular interaction in pure molecular liquids and their solutions including additive materials such as nanoparticles

Influence of Random Internal Fields on the Tunneling of OH Defects in NaCl Crystals

Alkali halide crystals doped with certain impurity ions show a low temperature behaviour, which differs significantly from that of pure crystals. The origin of these characteristic differences are tunneling centers formed by atomic or molecular impurity ions. We have investigated the dielectric susceptibility of hydroxyl ions in NaCl crystals at very low concentrations (below 30 ppm), where interactions are believed to be negligible. We find that the temperature dependence of the susceptibility is noticeably different from what one would expect for isolated defects in a symmetric environment. We propose that the origin of these deviations are random internal strains arising from imperfections of the host crystal. We will present the experimental data and a theoretical model which allows a quantitative understanding on a microscopic basis.Comment: 3 pages 3 figures, REVTeX, submitted to the proceedings of the PHONONS 2001 conferenc

Operation of a Stark decelerator with optimum acceptance

With a Stark decelerator, beams of neutral polar molecules can be accelerated, guided at a constant velocity, or decelerated. The effectiveness of this process is determined by the 6D volume in phase space from which molecules are accepted by the Stark decelerator. Couplings between the longitudinal and transverse motion of the molecules in the decelerator can reduce this acceptance. These couplings are nearly absent when the decelerator operates such that only every third electric field stage is used for deceleration, while extra transverse focusing is provided by the intermediate stages. For many applications, the acceptance of a Stark decelerator in this so-called $s=3$ mode significantly exceeds that of a decelerator in the conventionally used ($s=1$) mode. This has been experimentally verified by passing a beam of OH radicals through a 2.6 meter long Stark decelerator. The experiments are in quantitative agreement with the results of trajectory calculations, and can qualitatively be explained with a simple model for the 6D acceptance. These results imply that the 6D acceptance of a Stark decelerator in the $s=3$ mode of operation approaches the optimum value, i.e. the value that is obtained when any couplings are neglected.Comment: 13 pages, 11 figure

Vacuum spacetimes with a spacelike, hypersurface-orthogonal Killing vector: reduced equations in a canonical frame

The Newman-Penrose equations for spacetimes having one spacelike Killing vector are reduced -- in a geometrically defined "canonical frame'' -- to a minimal set, and its differential structure is studied. Expressions for the frame vectors in an arbitrary coordinate basis are given, and coordinate-independent choices of the metric functions are suggested which make the components of the Ricci tensor in the direction of the Killing vector vanish.Comment: 13 pages, no figures, LaTeX, to be published in Class. Quantum Gravity; v2: added/rephrased content, corrected typos, changed 1 referenc