Rapid removal of ammonium from domestic wastewater using polymer hydrogels

To date, technologies to recover ammonium from domestic wastewater from the mainstream have not found widespread application. This is largely due to the low ammonium concentrations in these wastewater streams. This paper reports on the use of polymer hydrogels for rapid sorption of ammonium from domestic wastewater coupled with efficient regeneration by mild acid washing. The sorption capacity of the hydrogel was 8.8-32.2 mg NH4-N/g, which corresponds to removal efficiencies ranging from 68% to 80% NH4-N, increasing proportionally with the initial ammonium concentration. It was, however, unaffected by changes in pH, as the sorption capacity remained constant from pH 5.0-8.0. Importantly, effective regeneration of the hydrogels under mildly acidic conditions (i.e. pH 4.0) was demonstrated with minimal loss in sorption performance following multiple sorption/desorption cycles. Overall, this study highlights the potential of low-cost polymer hydrogels for achieving mainstream ammonium recovery from domestic wastewater

Extrusion induced low-order starch matrices: enzymic hydrolysis and structure

Waxy, normal and highwaymen maize starches were extruded with water as sole plasticizer to achieve low-order starch matrices. Of the three starches, we found that only high-amylose extrudate showed lower digestion rate/extent than starches cooked in excess water. The ordered structure of high-amylose starches in cooked and extruded forms was similar, as judged by NMR, XRD and DSC techniques, but enzyme resistance was much greater for extruded forms. Size exclusion chromatography suggested that longer chains were involved in enzyme resistance. We propose that the local molecular density of packing of amylose chains can control the digestion kinetics rather than just crystallinity, with the principle being that density sufficient to either prevent/limit binding and/or slow down catalysis can be achieved by dense amorphous packing

Strong Ocean Melting Feedback During the Recent Retreat of Thwaites Glacier

Accelerating ice loss from Thwaites Glacier is contributing approximately 5% of global sea-level rise, and could add tens of centimeters to sea level over the coming centuries. We use an ocean model to calculate sub-ice melting for a succession of Digital Elevation Models of the main trunk of Thwaites Glacier from 2011 to 2022. The ice evolution during this period induces a strong geometrical feedback onto melting. Ice thinning and retreat provides a larger melting area, thicker and better-connected sub-ice water column, and steeper ice base. This leads to stronger sub-ice ocean currents, increasing melting by over 30% without any change in forcing from wider ocean conditions. This geometrical feedback over just 12 years is comparable to melting changes arising from plausible century-scale changes in ocean conditions and subglacial meltwater inflow. These findings imply that ocean-driven ice loss from Thwaites Glacier may only be weakly influenced by anthropogenic emissions mitigation

Seawater softening of suture zones inhibits fracture propagation in Antarctic ice shelves

Suture zones are abundant on Antarctic ice shelves and widely observed to impede fracture propagation, greatly enhancing ice-shelf stability. Using seismic and radar observations on the Larsen C Ice Shelf of the Antarctic Peninsula, we confirm that such zones are highly heterogeneous, consisting of multiple meteoric and marine ice bodies of diverse provenance fused together. Here we demonstrate that fracture detainment is predominantly controlled by enhanced seawater content in suture zones, rather than by enhanced temperature as previously thought. We show that interstitial seawater can reduce fracture-driving stress by orders of magnitude, promoting both viscous relaxation and the development of micro cracks, the incidence of which scales inversely with stress intensity. We show how simple analysis of viscous buckles in ice-penetrating radar data can quantify the seawater content of suture zones and their modification of the ice-shelf’s stress regime. By limiting fracture, enhancing stability and restraining continental ice discharge into the ocean, suture zones act as vital regulators of Antarctic mass balance

An updated seabed bathymetry beneath Larsen C Ice Shelf, west Antarctic

Abstract. In recent decades, rapid ice-shelf disintegration along the Antarctic Peninsula has had a global impact through enhancing outlet glacier flow, and hence sea level rise, and the freshening of Antarctic Bottom Water. Ice shelf thinning due to basal melting results from the circulation of relatively warm water in the underlying ocean cavity. However, the effect of sub-shelf circulation on future ice-shelf stability cannot be predicted accurately with computer simulations if the geometry of the ice-shelf cavity is unknown. To address this deficit for Larsen C Ice Shelf, west Antarctica, we integrate new water-column thickness measurements with existing observations. We present these new data here along with an updated bathymetry grid of the ocean cavity. Key findings include relatively deep seabed to the south-east of the Kenyon Peninsula, along the grounding line and around the key ice shelf pinning point of Bawden Ice Rise. In addition, we can confirm that the cavity’s southern trough stretches from Mobiloil Inlet to the open ocean. These areas of deep seabed will influence ocean circulation and tidal mixing, and will therefore affect the basal-melt distribution. These results will help constrain models of ice-shelf cavity circulation with the aim of improving our understanding of sub-shelf processes and their potential influence on ice shelf stability. The data set comprises all point measurements of seabed depth and a gridded data product, derived using additional measurements of both offshore seabed depth and the thickness of grounded ice. We present all new depth measurements here as well as a compilation of previously published measurements used in the gridding process. The gridded data product is included in the supplementary material. The underlying seismic data sets which were used to determine bed depth and ice thickness are available at https://doi.org/10.5285/315740B1-A7B9-4CF0-9521-86F046E33E9A (Brisbourne et al., 2019), https://doi.org/10.5285/5D63777D-B375-4791-918F-9A5527093298 (Booth, 2019), https://doi.org/10.5285/FFF8AFEE-4978-495E-9210-120872983A8D (Kulessa and Bevan, 2019) and https://doi.org/10.5285/147BAF64-B9AF-4A97-8091-26AEC0D3C0BB (Booth et al., 2019). </jats:p

An updated seabed bathymetry beneath Larsen C Ice Shelf, Antarctic Peninsula

Abstract. In recent decades, rapid ice shelf disintegration along the Antarctic Peninsula has had a global impact through enhancing outlet glacier flow and hence sea level rise and the freshening of Antarctic Bottom Water. Ice shelf thinning due to basal melting results from the circulation of relatively warm water in the underlying ocean cavity. However, the effect of sub-shelf circulation on future ice shelf stability cannot be predicted accurately with computer simulations if the geometry of the ice shelf cavity is unknown. To address this deficit for Larsen C Ice Shelf, West Antarctica, we integrate new water column thickness measurements from recent seismic campaigns with existing observations. We present these new data here along with an updated bathymetry grid of the ocean cavity. Key findings include a relatively deep seabed to the southeast of the Kenyon Peninsula, along the grounding line and around the key ice shelf pinning-point of Bawden Ice Rise. In addition, we can confirm that the cavity's southern trough stretches from Mobiloil Inlet to the open ocean. These areas of deep seabed will influence ocean circulation and tidal mixing and will therefore affect the basal-melt distribution. These results will help constrain models of ice shelf cavity circulation with the aim of improving our understanding of sub-shelf processes and their potential influence on ice shelf stability. The datasets are comprised of all the new point measurements of seabed depth. We present the new depth measurements here, as well as a compilation of previously published measurements. To demonstrate the improvements to the sub-shelf bathymetry map that these new data provide we include a gridded data product in the Supplement of this paper, derived using the additional measurements of both offshore seabed depth and the thickness of grounded ice. The underlying seismic datasets that were used to determine bed depth and ice thickness are available at https://doi.org/10.5285/315740B1-A7B9-4CF0-9521-86F046E33E9A (Brisbourne et al., 2019), https://doi.org/10.5285/5D63777D-B375-4791-918F-9A5527093298 (Booth, 2019), https://doi.org/10.5285/FFF8AFEE-4978-495E-9210-120872983A8D (Kulessa and Bevan, 2019) and https://doi.org/10.5285/147BAF64-B9AF-4A97-8091-26AEC0D3C0BB (Booth et al., 2019). </jats:p

Ice and firn heterogeneity within Larsen C Ice Shelf from borehole optical televiewing

Research was funded by the UK Natural Environmental Research Council grants NE/L006707/1 and NE/L005409/1 and a HEFCW/Aberystwyth University Capital Equipment Grant to B.H. Data will be available via the project website (www.projectmidas.org) and the UK Polar Data Centre (https://www.bas.ac.uk/data/uk-pdc/) from mid-2017.We use borehole optical televiewing (OPTV) to explore the internal structure of Larsen C Ice Shelf (LCIS). We report a suite of five ~90 m long OPTV logs, recording a light-emitting diode-illuminated, geometrically correct image of the borehole wall, from the northern and central sectors of LCIS collected during austral spring 2014 and 2015. We use a thresholding-based technique to estimate the refrozen ice content of the ice column and exploit a recently calibrated density-luminosity relationship to reveal its structure. All sites are dense and strongly influenced by surface melt, with frequent refrozen ice layers and mean densities, between the depths of 1.87 and 90 m, ranging from 862 to 894 kg m−3. We define four distinct units that comprise LCIS and relate these to ice provenance, dynamic history, and past melt events. These units are in situ meteoric ice with infiltration ice (U1), meteoric ice which has undergone enhanced densification (U2), thick refrozen ice (U3), and advected continental ice (U4). We show that the OPTV-derived pattern of firn air content is consistent with previous estimates, but that a significant proportion of firn air is contained within U4, which we interpret to have been deposited inland of the grounding line. The structure of LCIS is strongly influenced by the E-W gradient in föhn-driven melting, with sites close to the Antarctic Peninsula being predominantly composed of refrozen ice. Melting is also substantial toward the ice shelf center with >40% of the overall imaged ice column being composed of refrozen ice.Publisher PDFPeer reviewe

Anorectic and aversive effects of GLP-1 receptor agonism are mediated by brainstem cholecystokinin neurons, and modulated by GIP receptor activation

This work was funded by an MRC Career Development Award (MR/ P009824/1 and MR/P009824/2) to GD’A, as well as an MRC grant to SML/GD’A (MR/T032669/1), a BBSRC grant to SML (BB/M001067/1), and an additional direct contribution from Eli Lilly. D.J.H. was sup- ported by MRC (MR/N00275X/1 and MR/S025618/1), Diabetes UK (17/ 0005681), and the European Research Council (ERC) under the Eu- ropean Union’s Horizon 2020 research and innovation programme (Starting Grant 715884 to D.J.H.). AC was supported for part of this project by a travel grant from the Italian Society of Pharmacology and a fellowship from the Veronesi Foundation (Italy).Peer reviewedPublisher PD