Limits on chemical complexity in diffuse clouds: search for CH3OH and HC5N absorption

Context: An unexpectedly complex polyatomic chemistry exists in diffuse clouds, allowing detection of species such as C2H, C3H2, H2CO and NH3 which have relative abundances that are strikingly similar to those inferred toward the dark cloud TMC-1 Aims: We probe the limits of complexity of diffuse cloud polyatomic chemistry. Methods: We used the IRAM Plateau de Bure Interferometer to search for galactic absorption from low-lying J=2-1 rotational transitions of A- and E-CH3OH near 96.740 GHz and used the VLA to search for the J=8-7 transition of HC5N at 21.3 GHz. Results: Neither CH3OH nor HC5N were detected at column densities well below those of all polyatomics known in diffuse clouds and somewhat below the levels expected from comparison with TMC-1. The HCN/HC5N ratio is at least 3-10 times higher in diffuse gas than toward TMC-1. Conclusions: It is possible to go to the well once (or more) too ofte

The preliminary SOL (Sizing and Optimization Language) reference manual

The Sizing and Optimization Language, SOL, a high-level special-purpose computer language has been developed to expedite application of numerical optimization to design problems and to make the process less error-prone. This document is a reference manual for those wishing to write SOL programs. SOL is presently available for DEC VAX/VMS systems. A SOL package is available which includes the SOL compiler and runtime library routines. An overview of SOL appears in NASA TM 100565

HCO, c-C3H and CF+ : three new molecules in diffuse, translucent and "spiral-arm'' clouds

%methods {We used the EMIR receiver and FTS spectrometer at the IRAM 30m to construct absorption spectra toward bright extra-galactic background sources at 195 kHz spectral resolution ($\approx$ 0.6 \kms). We used the IRAM Plateau de Bure interferometer to synthesize absorption spectra of \hthcop\ and HCO toward the galactic HII region W49.} %results {HCO, \cc3h\ and CF\p\ were detected toward the blazars \bll\ and 3C111 having \EBV\ = 0.32 and 1.65 mag. HCO was observed in absorption from ``spiral-arm'' clouds in the galactic plane occulting W49. The complement of detectable molecular species in the 85 - 110 GHz absorption spectrum of diffuse/translucent gas is now fully determined at rms noise level $\delta_\tau \approx 0.002$ at \EBV\ = 0.32 mag (\AV\ = 1 mag) and $\delta_\tau$/\EBV\ $\approx\ 0.003$ mag$^{-1}$ overall.} %conclusions {As with OH, \hcop\ and \cch, the relative abundance of \cc3h\ varies little between diffuse and dense molecular gas, with N(\cc3h)/N({\it o-c}-\c3h2) $\approx$ 0.1. We find N(CF\p)/N(H$^{13}$CO\p) $\approx 5$, N(CF\p)/N(\cch) $\approx$ 0.005-0.01 and because N(CF\p) increases with \EBV\ and with the column densities of other molecules we infer that fluorine remains in the gas phase as HF well beyond \AV\ = 1 mag. We find N(HCO)/N(H$^{13}$CO\p) = 16 toward \bll, 3C111 and the 40 km/s spiral arm cloud toward W49, implying X(HCO) $\approx 10^{-9}$, about 10 times higher than in dark clouds. The behaviour of HCO is consistent with previous suggestions that it forms from C\p\ and \HH, even when \AV\ is well above 1 mag. The survey can be used to place useful upper limits on some species, for instance N(\hhco)/N(\HH CS) $>$ 32 toward 3C111, compared to 7 toward TMC-1, confirming the possibility of a gas phase formation route to \hhco.}Comment: A\%A in pres

The Sizing and Optimization Language (SOL): A computer language to improve the user/optimizer interface

The nonlinear mathematical programming method (formal optimization) has had many applications in engineering design. A figure illustrates the use of optimization techniques in the design process. The design process begins with the design problem, such as the classic example of the two-bar truss designed for minimum weight as seen in the leftmost part of the figure. If formal optimization is to be applied, the design problem must be recast in the form of an optimization problem consisting of an objective function, design variables, and constraint function relations. The middle part of the figure shows the two-bar truss design posed as an optimization problem. The total truss weight is the objective function, the tube diameter and truss height are design variables, with stress and Euler buckling considered as constraint function relations. Lastly, the designer develops or obtains analysis software containing a mathematical model of the object being optimized, and then interfaces the analysis routine with existing optimization software such as CONMIN, ADS, or NPSOL. This final state of software development can be both tedious and error-prone. The Sizing and Optimization Language (SOL), a special-purpose computer language whose goal is to make the software implementation phase of optimum design easier and less error-prone, is presented

The Sizing and Optimization Language, (SOL): Computer language for design problems

The Sizing and Optimization Language, (SOL), a new high level, special purpose computer language was developed to expedite application of numerical optimization to design problems and to make the process less error prone. SOL utilizes the ADS optimization software and provides a clear, concise syntax for describing an optimization problem, the OPTIMIZE description, which closely parallels the mathematical description of the problem. SOL offers language statements which can be used to model a design mathematically, with subroutines or code logic, and with existing FORTRAN routines. In addition, SOL provides error checking and clear output of the optimization results. Because of these language features, SOL is best suited to model and optimize a design concept when the model consits of mathematical expressions written in SOL. For such cases, SOL's unique syntax and error checking can be fully utilized. SOL is presently available for DEC VAX/VMS systems. A SOL package is available which includes the SOL compiler, runtime library routines, and a SOL reference manual

Does Size Matter? School Consolidation Policy Issues in Arkansas

Providing a reasonable education for all students in Arkansas is a legal responsibility explicitly mandated by the state’s constitution. Consistent with the long-standing American tradition of “grassroots” control of education, public schools in all states are funded and managed first and foremost at the local level. The federal government can and does enact legislation with which schools must conform. Directly or indirectly, federal mandates provide significant amounts of monies to support particular types of school services and programming. But ultimate responsibility for financing and operating schools devolves on state government. In Arkansas, it has been held, the state must provide “a general, suitable, and efficient system of free public schools” (Lakeview v. Huckabee, 2001)

Active cooling design for scramjet engines using optimization methods

A methodology for using optimization in designing metallic cooling jackets for scramjet engines is presented. The optimal design minimizes the required coolant flow rate subject to temperature, mechanical-stress, and thermal-fatigue-life constraints on the cooling-jacket panels, and Mach-number and pressure contraints on the coolant exiting the panel. The analytical basis for the methodology is presented, and results for the optimal design of panels are shown to demonstrate its utility

Effect of a moderate-intensity demonstration walk on accuracy of physical activity self-report.

Background/Objective:Providing a demonstration of a 10-minute bout of moderate-to-vigorous intensity physical activity (MVPA) immediately prior to subjective reporting of MVPA could influence self-reported activity by calibrating both duration and intensity. We assessed the effect of a demonstration of MVPA on subsequent MVPA recall, and explored whether this improved agreement with objective measures of MVPA. Methods:A total of 846 individuals participated in four different physical activity interventions; two of which included a 10-minute moderate-intensity demonstration walk on a treadmill at baseline and 6-month visits immediately prior to reporting MVPA. Participants from three studies also wore accelerometers during the week overlapping with self-reported MVPA. Results:Overall, those completing the demonstration walk reported significantly fewer minutes of MVPA per week at baseline (b = -11.69, standard error = 2.53, p < 0.01). The effect of the demonstration walk at 6 months was not significant (p = 0.06). Correlations with accelerometers at baseline were higher in the two studies with the demonstration walk (ρ = 0.28, 0.26) than the study without (ρ = 0.04). Correlations with accelerometers increased overall from baseline to follow-up. Conclusion:A 10-minute demonstration of MVPA was associated with reporting fewer minutes of MVPA and improved agreement with objective PA measures at baseline. These findings support combining self-report PA assessments with hands-on MVPA demonstrations