Examples of heterogeneous catalytic processes for fine chemistry

Fine chemicals are highly pure substances that are commercially produced by chemical reactions for highly specialized applications. In most cases, however, these reactions involve stoichiometric and highly polluting steps. A possible solution is the development of processes using enzymatic, homogeneous or heterogeneous catalysts. In this review, selected examples of clean heterogeneously-catalyzed reactions applied to the synthesis of fine chemicals are reported for the purpose of highlighting the growing need for more sustainable industrial processes, i.e., processes that produce minimal waste and avoid as much as possible the use of toxic and/or hazardous reagents and solvents. A thorough knowledge of catalyst properties, reaction conditions and interactions with the reacting substrate are essential for optimizing the synthesis, thus making it possible to move on from laboratory to industrial production

Teams in New Ventures: Gender, Human Capital and Motivation

Purpose- This paper dismantles the idea that sex per se explains entrepreneurial outcomes and demonstrates the influence of a gendered motivation on forging and shaping new venture teams, which is a disruptive choice affecting the future of start-ups. Methods- A two-level research model is validated on data from the PSED II, with a system of simultaneous equations. Firstly, we test if team features affect the performance of new ventures; then, we investigate determinants of team features with a focus on sex and motivation of nascent entrepreneurs. Findings- Human capital (HC) in terms of education and experience of team members consistently explains venture evolution only when considering the larger team of affiliates. The HC gathered by nascent entrepreneurs is not due to the simplistic sex condition, but rather to a gendered motivation related to the inferior need of achievement of women. Research limitations- Limitations of discretionary scoring assigned to items of the PSED II survey are present, but unavoidable when processing qualitative data. Social and Practical implications- Women need to be (culturally) educated on how to re-balance their personal motivation towards entrepreneurship by fostering their incentives for achievement. Political and educational programs could trigger success in the creation of new businesses led by women. Originality/value- This paper contributes to the literature on nascent entrepreneurship, focusing on the entrepreneurial teams in the initial phase of business creation, and provides the basis for further studies aimed at eradicating the stereotypes of gender roles that lead women to self-exclusion and organizational errors

Anisotropic in-plane optical conductivity in detwinned Ba(Fe1-xCox)2As2

We study the anisotropic in-plane optical conductivity of detwinned Ba(Fe1-xCox)2As2 single crystals for x=0, 2.5% and 4.5% in a broad energy range (3 meV-5 eV) across their structural and magnetic transitions. For temperatures below the Neel transition, the topology of the reconstructed Fermi surface, combined with the distinct behavior of the scattering rates, determines the anisotropy of the low frequency optical response. For the itinerant charge carriers, we are able to disentangle the evolution of the Drude weights and scattering rates and to observe their enhancement along the orthorhombic antiferromagnetic a-axis with respect to the ferromagnetic b-axis. For temperatures above Ts, uniaxial stress leads to a finite in-plane anisotropy. The anisotropy of the optical conductivity, leading to a significant dichroism, extends to high frequencies in the mid- and near-infrared regions. The temperature dependence of the dichroism at all dopings scales with the anisotropy ratio of the dc conductivity, suggesting the electronic nature of the structural transition. Our findings bear testimony to a large nematic susceptibility that couples very effectively to the uniaxial lattice strain. In order to clarify the subtle interplay of magnetism and Fermi surface topology we compare our results with theoretical calculations obtained from density functional theory within the full-potential linear augmented plane-wave method.Comment: 17 pages, 9 figure

Prenatal parental representations: Influences on perceived romantic couple adjustment and infant's temperament during pregnancy and after the infant's birth

Objective: The present work aimed to evaluate the differences between fathers' and mothers' prenatal parental representations, the differences between pre- and postnatal perceptions of couple adjustment, and whether the quality of prenatal parental representations is associated with the perception of couple adjustment and with the perception of infant temperament at 3 months. Background: Within a multifactorial, transactional model, several studies indicated that prenatal parental representations are relevant to the quality of infant–parent relationship and the child's development. Method: Couples experiencing their first pregnancy (n = 40) (mothers: Mage = 33.7 years, SD = 5,1 years; fathers: (Mage = 37.4 years, SD = 5.6 years) responded to the Parental Representations Interview During Pregnancy and the Dyadic Adjustment Scale during the seventh month of pregnancy. When couples' infant was 3 months of age, the parents completed the Infant Behavior Questionnaire-R to assess infant temperament. Results: Analyses revealed that mothers and fathers who had an unbalanced and unintegrated parental representation perceived their couple adjustment as less cohesive, and this was related to a more negative perception of the child's temperament. Conclusions: Prenatal parental representations were found to be a significant variable in terms of their influence on the quality of pre- and postnatal parents' romantic couple adjustment and on the infant's temperament. Implications: It is important to include both mothers and fathers to further our understanding of parental influence on a child's development and to enhance the efficacy of preventive programs since pregnancy

Multiresistant Salmonella enterica serovar 4,[5],12:i:- in Europe: a new pandemic strain?

A marked increase in the prevalence of S. enterica serovar 4,[5],12:i:- with resistance to ampicillin, streptomycin, sulphonamides and tetracyclines (R-type ASSuT) has been noted in food-borne infections and in pigs/pig meat in several European countries in the last ten years. One hundred and sixteen strains of S. enterica serovar 4,[5],12:i:- from humans, pigs and pig meat isolated in England and Wales, France, Germany, Italy, Poland, Spain and the Netherlands were further subtyped by phage typing, pulsed-field gel electrophoresis and multilocus variable number tandem repeat analysis to investigate the genetic relationship among strains. PCR was performed to identify the fljB flagellar gene and the genes encoding resistance to ampicillin, streptomycin, sulphonamides and tetracyclines. Class 1 and 2 integrase genes were also sought. Results indicate that genetically related serovar 4,[5],12:i:- strains of definitive phage types DT193 and DT120 with ampicillin, streptomycin, sulphonamide and tetracycline resistance encoded by blaTEM, strA-strB, sul2 and tet(B) have emerged in several European countries, with pigs the likely reservoir of infection. Control measures are urgently needed to reduce spread of infection to humans via the food chain and thereby prevent the possible pandemic spread of serovar 4,[5],12:i:- of R-type ASSuT as occurred with S. Typhimurium DT104 during the 1990s

FT-IR Investigation of Methoxy Substituted Benzenes Adsorbed on Solid Acid Catalysts

The nature of the interaction on two different catalysts (zeolite BEA and \u3b3-alumina) of some aromatic substrates, 1,2-methylendioxybenzene, 1,2-ethylendioxybenzene, and 1,2-dimethoxybenzene, have been investigated by FT-IR spectroscopy. FT-IR data suggest that the adsorption of 1,2-methylendioxybenzene occurs through oxygen atoms and the molecule maintains the original puckered conformation, whereas the planar structure due to the absence of a fused ring in the case of 1,2- dimethoxybenzene and the twisted conformation of 1,2-ethylendioxybenzene cause an orientation of the molecules parallel to the catalyst surface, with the benzene ring directly interacting to it. The puckered conformation of MDB leads the benzene ring to be electron-deficient, then deactivated toward alkylation, such as confirmed by the obtained catalytic results, which show that MDB is totally not reactive using the investigated heterogeneous catalysts, while in the traditional homogeneous system shows a reactivity comparable to the other considered substrates

Mathematical Structure of Rabi Oscillations in the Strong Coupling Regime

In this paper we generalize the Jaynes--Cummings Hamiltonian by making use of some operators based on Lie algebras su(1,1) and su(2), and study a mathematical structure of Rabi floppings of these models in the strong coupling regime. We show that Rabi frequencies are given by matrix elements of generalized coherent operators (quant--ph/0202081) under the rotating--wave approximation. In the first half we make a general review of coherent operators and generalized coherent ones based on Lie algebras su(1,1) and su(2). In the latter half we carry out a detailed examination of Frasca (quant--ph/0111134) and generalize his method, and moreover present some related problems. We also apply our results to the construction of controlled unitary gates in Quantum Computation. Lastly we make a brief comment on application to Holonomic Quantum Computation.Comment: Latex file, 24 pages. I added a new section (Quantum Computation), so this paper became self-contained in a certain sens

High prevalence of anti-hepatitis e virus antibodies among blood donors in central Italy, february to march 2014

Prevalence of anti-hepatitis E virus (HEV) antibodies is highly variable in developed countries, which seems partly due to differences in assay sensitivity. Using validated sensitive assays, we tested 313 blood donors attending a hospital transfusion unit in central Italy in January and February 2014 for anti-HEV IgG and IgM and HEV RNA. Data on HEV exposure were collected from all donors. Overall anti-HEV IgG prevalence was 49% (153/313). Eating raw dried pig-liver sausage was the only independent predictor of HEV infection (adjusted prevalence rate ratio = 2.14; 95% confidence interval: 1.23–3.74). Three donors were positive for either anti-HEV IgM (n = 2; 0.6%) or HEV RNA (n = 2; 0.6%); they were completely asymptomatic, without alanine aminotransferase (ALT) abnormalities. Of the two HEV RNA-positive donors (both harbouring genotype 3), one was anti-HEV IgG- and IgM-positive, the other was anti-HEV IgG- and IgM-negative. The third donor was positive for anti-HEV IgG and IgM but HEV RNA-negative. HEV infection is therefore hyperendemic among blood donors (80% men 18–64 years-old) from central Italy and associated with local dietary habits. Nearly 1% of donors have acute or recent infection, implying potential transmission to blood recipients. Neither ALT nor anti-HEV IgM testing seems useful to prevent transfusion-transmitted HEV infection. © 2016, European Centre for Disease Prevention and Control

Cholera with severe renal failure in an Italian tourist returning from Cuba, July 2013

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