Glyoxal 4-nitrophenylhydrazone : triple helices linked into a three-dimensional channel structure

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Hydrogen bonding in C-methylated nitroanilines : the three-dimensional framework structure of 2-methyl-4-nitroaniline

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A triclinic polymorph of benzanilide : disordered molecules form hydrogen-bonded chains

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File Fragmentation over an Unreliable Channel

It has been recently discovered that heavy-tailed file completion time can result from protocol interaction even when file sizes are light-tailed. A key to this phenomenon is the RESTART feature where if a file transfer is interrupted before it is completed, the transfer needs to restart from the beginning. In this paper, we show that independent or bounded fragmentation guarantees light-tailed file completion time as long as the file size is light-tailed, i.e., in this case, heavy-tailed file completion time can only originate from heavy-tailed file sizes. If the file size is heavy-tailed, then the file completion time is necessarily heavy-tailed. For this case, we show that when the file size distribution is regularly varying, then under independent or bounded fragmentation, the completion time tail distribution function is asymptotically upper bounded by that of the original file size stretched by a constant factor. We then prove that if the failure distribution has non-decreasing failure rate, the expected completion time is minimized by dividing the file into equal sized fragments; this optimal fragment size is unique but depends on the file size. We also present a simple blind fragmentation policy where the fragment sizes are constant and independent of the file size and prove that it is asymptotically optimal. Finally, we bound the error in expected completion time due to error in modeling of the failure process

Vision screening in children:a retrospective study of social and demographic factors with regard to visual outcomes

BACKGROUND: Amblyopia and its risk factors have been demonstrated to be more common among children from low socioeconomic backgrounds. We sought to investigate this association in a region with orthoptic-delivered screening and whole population coverage, and to also examine the association of the Health Plan Indicator (HPI) with screening outcome. METHODS: Screening examination outcomes, postcodes and HPIs were extracted from the community child health database for every child who underwent preschool vision screening between March 2010 and February 2011 Tayside. We obtained the Scottish Index of Multiple Deprivation score for every child as a measure of area-based deprivation. We assessed the vulnerability/needs of the individual family through the HPI—‘Core’ (children and families receiving universal health visiting service), ‘Additional’ (receiving additional health/social support) and ‘Intensive’ (receiving high levels of support). The outcomes from follow-up examinations for those who failed screening were extracted from the orthoptic department database. RESULTS: 4365 children were screened during the year 2010–2011 of whom 523 (11.9%) failed. The odds of children from the least deprived socioeconomic group passing the visual screening test was 1.4 times higher than those from the most deprived socioeconomic group (OR 1.4, 95% CI 1.07 to 1.89, p=0.01). The odds of a child from a family assigned as ‘Intensive’ failing the preschool visual screening test was three times greater than the odds of a child from a family assigned as ‘Core’ (OR 3.59, 95% CI 1.6 to 7.8, p=0.001). CONCLUSIONS: We found that children from the most deprived backgrounds and those from unstable homes were more likely to fail preschool vision screening

Marriage, Labor Supply and the Dynamics of the Social Safety Net

The 1996 PRWORA reform introduced time limits on the receipt of welfare in the United States. We use variation by state and across demographic groups to provide reduced form evidence showing that such limits led to a fall in welfare claims (partly due to \banking" benefits for future use), a rise in employment, and a decline in divorce rates. We then specify and estimate a life-cycle model of marriage, labor supply and divorce under limited commitment to better understand the mechanisms behind these behavioral responses, carry out counterfactual analysis with longer run impacts and evaluate the welfare effects of the program. Based on the model, which reproduces the reduced form estimates, we show that among low educated women, instead of relying on TANF, single mothers work more, more mothers remain married, some move to relying only on food stamps and, in ex-ante welfare terms, women are worse off

Effect of forward motion on engine noise

Methods used to determine a procedure for correcting static engine data for the effects of forward motion are described. Data were analyzed from airplane flyover and static-engine tests with a JT8D-109 low-bypass-ratio turbofan engine installed on a DC-9-30, with a CF6-6D high-bypass-ratio turbofan engine installed on a DC-10-10, and with a JT9D-59A high-bypass-ratio turbofan engine installed on a DC-10-40. The observed differences between the static and the flyover data bases are discussed in terms of noise generation, convective amplification, atmospheric propagation, and engine installation. The results indicate that each noise source must be adjusted separately for forward-motion and installation effects and then projected to flight conditions as a function of source-path angle, directivity angle, and acoustic range relative to the microphones on the ground

Enhancement of Copper Sorption through Acid Blue 29 Treated Oil Palm Pressed Fibres

The removal of cupric ions from aqueous solution by natural and dyecoated palm pressed fibres was studied. Sorption was both pH and concentration dependent. The equilibrium data followed the Langmuir isotherm model with maximum copper sorption capacities of 2.41 and 7.71 mg/g for natural and dye-treated fibres respectively. The presence of other metal ions inhibited copper uptake in the following order Pb> Zn > Ni. The suppressing effects of chelators correspond to their log K values. Column studies showed that bed-depth had a more pronounced effect on copper sorption than flow rate

Hydrogen bonding in substituted nitroanilines : isolated nets in 1,3-diamino-4-nitrobenzene and continuously interwoven nets in 3,5-dinitroaniline

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