163 research outputs found
Frequency Shifts and Linewidth Changes of Infrared-Active Phonons in Double-Layered High-Temperature Superconductors
We calculate frequency shifts and changes in linewidths of infrared-active
phonons within a shell model for the bare phononic system coupled to an
electronic double-layer structure with inter-layer charge transfer. The
theoretical concept is applied to YBaCuO yielding a good description of
experimental results in the normal state as well as at the transition to the
superconducting state.Comment: 8 pages, LaTex, SISSA-CM-93-00
Raman scattering study of (KSr)FeAs ( = 0.0, 0.4)
Polarized Raman spectra of non-superconducting SrFeAs and
superconducting KSrFeAs ( K) are reported.
All four phonon modes (A + B + 2E) allowed by symmetry, are
found and identified. Shell model gives reasonable description of the spectra.
No detectable anomalies are observed near the tetragonal-to-orthorhombic
transition in SrFeAs or the superconducting transition in
KSrFeAs.Comment: 4 pages, 4 figures, 2 table
Thermoelectric properties of Zn_5Sb_4In_(2-δ)(δ=0.15)
The polymorphic intermetallic compound Zn_5Sb_4In_(2−δ) (δ = 0.15(3)) shows promising thermoelectric properties at low temperatures, approaching a figure of merit ZT of 0.3 at 300 K. However, thermopower and electrical resistivity changes discontinuously at around 220 K. Measurement of the specific heat locates the previously unknown temperature of the order-disorder phase transition at around 180 K. Investigation of the charge carrier concentration and mobility by Hall measurements and infrared reflection spectroscopy indicate a mixed conduction behavior and the activation of charge carriers at temperatures above 220 K. Zn_5Sb_4In_(2−δ) has a low thermal stability, and at temperatures above 470 K samples decompose into a mixture of Zn, InSb, and Zn_4Sb_3
-Martin boundary of killed random walks in the quadrant
We compute the -Martin boundary of two-dimensional small steps random
walks killed at the boundary of the quarter plane. We further provide explicit
expressions for the (generating functions of the) discrete -harmonic
functions. Our approach is uniform in , and shows that there are three
regimes for the Martin boundary.Comment: 18 pages, 2 figures, to appear in S\'eminaire de Probabilit\'e
Raman and Infrared-Active Phonons in Hexagonal HoMnO Single Crystals: Magnetic Ordering Effects
Polarized Raman scattering and infrared reflection spectra of hexagonal
HoMnO single crystals in the temperature range 10-300 K are reported.
Group-theoretical analysis is performed and scattering selection rules for the
second order scattering processes are presented. Based on the results of
lattice dynamics calculations, performed within the shell model, the observed
lines in the spectra are assigned to definite lattice vibrations. The magnetic
ordering of Mn ions, which occurs below T=76 K, is shown to effect both
Raman- and infrared-active phonons, which modulate Mn-O-Mn bonds and,
consequently, Mn exchange interaction.Comment: 8 pages, 6 figure
The anomaly of the oxygen bond-bending mode at 320 cm and the additional absorption peak in the c-axis infrared conductivity of underdoped YBaCuO single crystals revisited by ellipsometricmeasurements
We have performed ellipsometric measurements of the far-infrared c-axis
dielectric response of underdoped YBaCuO single
crystals. Here we report a detailed analysis of the temperature-dependent
renormalization of the oxygen bending phonon mode at 320 cm and the
formation of the additional absorption peak around 400-500 cm. For a
strongly underdoped YBaCuO crystal with T=52 K we
find that, in agreement with previous reports based on conventional reflection
measurements, the gradual onset of both features occurs well above T at
T*150 K. Contrary to some of these reports, however, our data establish
that the phonon anomaly and the formation of the additional peak exhibit very
pronounced and steep changes right at T. For a less underdoped
YBaCuO crystal with T=80 K, the onset temperature of
the phonon anomaly almost coincides with T. Also in contrast to some
previous reports, we find for both crystals that a sizeable fraction of the
spectral weight of the additional absorption peak cannot be accounted for by
the spectral-weight loss of the phonon modes but instead arises from a
redistribution of the electronic continuum. Our ellipsometric data are
consistent with a model where the bilayer cuprate compounds are treated as a
superlattice of intra- and inter-bilayer Josephson-junctions
Phonon and magnon scattering of antiferromagnetic Bi2Fe4O9
The phonon structure of antiferromagnetic Bi2Fe4O9 (space group Pbnm No. 55, TN≈240 K) was studied theoretically by calculations of lattice dynamics and experimentally between 10 and 300 K by polarized Raman spectroscopy. Most of the 12Ag+12B1g+9B2g+9B3g Raman modes were unambiguously identified. Strong second-order scattering was observed for ab-plane-confined incident and scattered light polarizations. In addition to the phonon-scattering, broad Raman bands with typical characteristics of magnon scattering appear below TN. The magnon bands are analyzed on the basis of magnetic structure of Bi2Fe4O9 and attributed to two- magnon excitations
Phonons and Magnetic Excitations in Mott-Insulator LaTiO
The polarized Raman spectra of stoichiometric LaTiO (T K) were
measured between 6 and 300 K. In contrast to earlier report on half-metallic
LaTiO, neither strong background scattering, nor Fano shape of the
Raman lines was observed. The high frequency phonon line at 655 cm
exhibits anomalous softening below T: a signature for structural
rearrangement. The assignment of the Raman lines was done by comparison to the
calculations of lattice dynamics and the nature of structural changes upon
magnetic ordering are discussed. The broad Raman band, which appears in the
antiferromagnetic phase, is assigned to two-magnon scattering. The estimated
superexchange constant meV is in excellent agreement with the
result of neutron scattering studies.Comment: 4 pages, 5 figure
Solvability of singular integral equations with rotations and degenerate kernels in the vanishing coefficient case
By means of Riemann boundary value problems and of certain convenient systems of linear algebraic equations, this paper deals with the solvability of a class of singular integral equations with rotations and degenerate kernel within the case of a coefficient vanishing on the unit circle. All the possibilities about the index of the coefficients in the corresponding equations are considered and described in detail, and explicit formulas for their solutions are obtained. An example of application of the method is shown at the end of the last section
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