Comparative kinetics study of the catalytic oxidation of benzene and its mono-halogenated derivatives over V2_{2}O5_{5}–WO3_{3}/TiO2_{2} catalyst

The SCR-DeNOx commercial catalysts are reported as possible candidates to remove aromatic VOCs and NO$_{{x}}$ simultaneously. In this paper, we present the kinetic studies of the oxidation of benzene and its mono-halogenated derivatives over V$_{2}$O$_{5}$–WO$_{3}$/TiO$_{2}$ catalyst as typical high-dust SCR-DeNOx system. The kinetic investigation follows the influence of temperature on the conversion of aromatic VOCs to establish the apparent energy activation and dependence on between temperature and the effective constant rate of the catalytic oxidation reaction. The data shows that the catalytic oxidation process takes place after a combined kinetic mechanism, mass transport through pores—chemical transformation

Comparative kinetics study of the catalytic oxidation of benzene and its mono-halogenated derivatives over V2_{2}O5_{5}–WO3_{3}/TiO2_{2} catalyst

The SCR-DeNOx commercial catalysts are reported as possible candidates to remove aromatic VOCs and NO$_{{x}}$ simultaneously. In this paper, we present the kinetic studies of the oxidation of benzene and its mono-halogenated derivatives over V$_{2}$O$_{5}$–WO$_{3}$/TiO$_{2}$ catalyst as typical high-dust SCR-DeNOx system. The kinetic investigation follows the influence of temperature on the conversion of aromatic VOCs to establish the apparent energy activation and dependence on between temperature and the effective constant rate of the catalytic oxidation reaction. The data shows that the catalytic oxidation process takes place after a combined kinetic mechanism, mass transport through pores—chemical transformation

Spectroscopic investigation and chemical fingerprint of Datura innoxia dry biomass

In this study it is presented the application of spectroscopic methods, such as fluorescence study and attenuated total reflection Fourier transform infrared analysis for identification and detection of secondary metabolite specially, hyoscine, and organic functional groups from dry biomass of Datura innoxia vegetative organs. The experimental results confirmed the presence of some important classes of secondary metabolites useful in medicine domain, e.g., alkaloids, terpenes, phenolics, sterols, carbohydrates. Regarding fluorescence study, maximum excitation wavelengths for hyoscine were found to be 345 nm (1-butanol and ethanol). Moreover, the results showed the presence of hyoscine in all structural units which is in according with other studies

Specific interactions within micelle microenvironment in different charged dye/surfactant systems

AbstractThe interactions of two ionic dyes, Crystal Violet and Methyl Orange, with different charged surfactants and also with a nonionic surfactant were investigated using surface tension measurements and visible spectroscopy in pre-micellar and post-micellar regions. It was found that for the water dominant phase systems the dye was localized between the polar heads, at the exterior of the direct micelle shells for all the systems. For the oil dominant phase systems, in case of the same charged dye/surfactant couples, the dye was localized in the micelle shell between the hydrocarbon chain of the surfactant nearby the hydrophilic head groups while for nonionic surfactant and oppositely charged dye/surfactant, localization of dye was between the oxyethylenic head groups towards the interior of the micelle core. Mixed aggregates of the dye and surfactant (below the critical micellar concentration of cationic surfactant), dye-surfactant ion pair and surfactant-micelles were present. The values of equilibrium constants (for TX-114/MO and TX-114/CV systems were 0.97 and 0.98, respectively), partition coefficients between the micellar and bulk water phases and standard free energy (for the nonionic systems were −12.59kJ/mol for MO and −10.97kJ/mol for CV) were calculated for all the studied systems. The partition processes were exothermic and occurred spontaneously

Danube Delta: Water Management on the Sulina Channel in the Frame of Environmental Sustainability

The Danube Delta is the newest land formed by both transporting sediments brought by Danube River, which flows into the Black Sea and by traversing an inland region where water spreads and deposits sediments. Diurnal tidal action is low (only 8–9 cm), therefore the sediments would wash out into the water body faster than the river deposits it. However, a seasonal fluctuation of water level of 20 cm was observed in the Black Sea, contributing to alluvial landscape evolution in the Danube Delta. The Danube Delta is a very low flat plain, lying 0.52 m above Mean Black Sea Level with a general gradient of 0.006 m/km and only 20% of the delta area is below zero level. The main control on deposition, which is a combination of river, wind-generated waves, and tidal processes, depends on the strength of each one. The other two factors that play a major role are landscape position and the grain size distribution of the source sediment entering the delta from the river. The Danube Delta is a natural protected area in the South-Eastern part of Romania, declared a Biosphere Reserve through the UNESCO “Man and Biosphere” Programme. Water is a determining factor for all the human settlements in the Biosphere Reserve, the whole Danube Delta being structured by the three branches of the Danube (Chilia, Sulina and Sfantu Gheorghe (Saint George)). Our case study is focused on the Sulina branch, also named Sulina Channel, which offers the shortest distance between the Black Sea (trough Sulina Port) and Tulcea (the most important city of the Danube Delta from economic, social and cultural points of view) for both fluvial and marine ships. The improvement of water resources management is the main topic of this chapter, in terms of water quality indicators, which will be presented in twenty-nine monitoring points, starting since a few years ago and updated to nowadays. During the study period, significant exceedances of the limit value were detected in case of nitrate-N (3.9–4.6 mg/L) at the confluence (CEATAL 2) with the Saint George branch and in the Sulina Channel after the Wastewaters Treatment Plant (WWTP) discharge area, as well as near two settlements, namely Gorgova and Maliuc. The higher concentrations of Nitrogen-based nutrients were caused by the leakage from the old sewage systems (where these exist) and the diffuse loads

Teachers' Guide to Differentiated Instruction

La publicación consta de 5 secciones, una en inglés y otras en cada uno de los idiomas de los países participantes en el proyecto (griego, rumano, esloveno y español). María Bermúdez-Martínez es coautora del volumen y proof reading de la sección en español.Se adjunta la sección en españolGuía sobre Enseñanza DiversificadaEuropean Union, Proyecto Erasmus + KA2, Proyecto Differentiation of instruction for teacher professional Development and students' Success (DiDeSu) (Erasmus+ 2015-1-CY01-KA201-011845

Effectiveness of the adapted bivalent mRNA COVID-19 vaccines against hospitalisation in individuals aged ≥ 60 years during the Omicron XBB lineage-predominant period: VEBIS SARI VE network, Europe, February to August, 2023

Members of the European Hospital Vaccine Effectiveness Group: Portugal: Ana Paula Rodrigues, Débora Pereira, Susana Costa Maia e Silva, Paula Pinto, Cristina Bárbara, António Pais de Lacerda, Raquel Guiomar and Camila Henriques.The European Medicines Agency (EMA) authorised four adapted bivalent mRNA COVID-19 vaccines for use against COVID-19 in September/October 2022: Comirnaty (BNT162b2; Pfizer-BioNTech) and Spikevax (mRNA-1273; Moderna) Original/Omicron BA.1 and Original/Omicron BA.4–5 [1]. During autumn 2022, all European Union/European Economic Area (EU/EEA) countries had vaccination campaigns in place to administer a booster dose, with several countries using the adapted bivalent vaccines [2]. The Omicron-descendent XBB lineage and XBB.1.5 sub-lineage became variants of interest in March 2023 [3]. We estimated the effectiveness of the COVID-19 bivalent vaccines against hospitalisation with PCR-confirmed SARS-CoV-2 infection among patients aged ≥ 60 years with severe acute respiratory infection (SARI) during the XBB lineage-predominant period.The ‘Vaccine Effectiveness, Burden and Impact Studies studies’ (VEBIS) is a project of the European Centre for Disease Prevention and Control (ECDC) run under the framework con tract No. ECDC/2021/016.info:eu-repo/semantics/publishedVersio

Mechanism of activation of methyltransferases involved in translation by the Trm112 ‘hub’ protein

Methylation is a common modification encountered in DNA, RNA and proteins. It plays a central role in gene expression, protein function and mRNA translation. Prokaryotic and eukaryotic class I translation termination factors are methylated on the glutamine of the essential and universally conserved GGQ motif, in line with an important cellular role. In eukaryotes, this modification is performed by the Mtq2-Trm112 holoenzyme. Trm112 activates not only the Mtq2 catalytic subunit but also two other tRNA methyltransferases (Trm9 and Trm11). To understand the molecular mechanisms underlying methyltransferase activation by Trm112, we have determined the 3D structure of the Mtq2-Trm112 complex and mapped its active site. Using site-directed mutagenesis and in vivo functional experiments, we show that this structure can also serve as a model for the Trm9-Trm112 complex, supporting our hypothesis that Trm112 uses a common strategy to activate these three methyltransferases

2015/16 seasonal vaccine effectiveness against hospitalisation with influenza a(H1N1)pdm09 and B among elderly people in Europe: Results from the I-MOVE+ project

We conducted a multicentre test-negative caseâ\u80\u93control study in 27 hospitals of 11 European countries to measure 2015/16 influenza vaccine effectiveness (IVE) against hospitalised influenza A(H1N1)pdm09 and B among people aged â\u89¥ 65 years. Patients swabbed within 7 days after onset of symptoms compatible with severe acute respiratory infection were included. Information on demographics, vaccination and underlying conditions was collected. Using logistic regression, we measured IVE adjusted for potential confounders. We included 355 influenza A(H1N1)pdm09 cases, 110 influenza B cases, and 1,274 controls. Adjusted IVE against influenza A(H1N1)pdm09 was 42% (95% confidence interval (CI): 22 to 57). It was 59% (95% CI: 23 to 78), 48% (95% CI: 5 to 71), 43% (95% CI: 8 to 65) and 39% (95% CI: 7 to 60) in patients with diabetes mellitus, cancer, lung and heart disease, respectively. Adjusted IVE against influenza B was 52% (95% CI: 24 to 70). It was 62% (95% CI: 5 to 85), 60% (95% CI: 18 to 80) and 36% (95% CI: -23 to 67) in patients with diabetes mellitus, lung and heart disease, respectively. 2015/16 IVE estimates against hospitalised influenza in elderly people was moderate against influenza A(H1N1)pdm09 and B, including among those with diabetes mellitus, cancer, lung or heart diseases