Peierls barrier characteristic and anomalous strain hardening provoked by dynamic-strain-aging strengthening in a body-centered-cubic high-entropy alloy

The temperature effect on the mechanical behavior of the HfNbTaTiZr high entropy alloy (HEA) was investigated at 77–673 K. The decrease of the yield strength with increasing the temperature was mechanistically analyzed by considering contributions from various strengthening mechanisms. An anomalous dependence of strain hardening on temperature was observed and was justified to be caused by dynamic strain aging (DSA) as an extra strengthening mechanism at elevated temperatures. A model was constructed to split the overall strain hardening into forest hardening and DSA hardening, both of which were theoretically quantified at all temperatures considered. The work quantifies the height of Peierls barriers in the bcc HfNbTaTiZr HEA, and reveals dynamic strain aging as the strengthening mechanism causing the anomalous strain hardening at elevated temperatures

Pollution control can help mitigate future climate change impact on European grayling in the UK

Aim: We compare the performance of habitat suitability models using climate data only or climate data together with water chemistry, land cover and predation pressure data to model the distribution of European grayling (Thymallus thymallus). From these models, we (a) investigate the relationship between habitat suitability and genetic diversity; (b) project the distribution of grayling under future climate change; and (c) model the effects of habitat mitigation on future distributions. Location: United Kingdom. Methods: Maxent species distribution modelling was implemented using a Simple model (only climate parameters) or a Full model (climate, water chemistry, land use and predation pressure parameters). Areas of high and low habitat suitability were designated. Associations between habitat suitability and genetic diversity for both neutral and adaptive markers were examined. Distribution under minimal and maximal future climate change scenarios was modelled for 2050, incorporating projections of future flow scenarios obtained from the Centre for Ecology and Hydrology. To examine potential mitigation effects within habitats, models were run with manipulation of orthophosphate, nitrite and copper concentrations. Results: We mapped suitable habitat for grayling in the present and the future. The Full model achieved substantially higher discriminative power than the Simple model. For low suitability habitat, higher levels of inbreeding were observed for adaptive, but not neutral, loci. Future projections predict a significant contraction of highly suitable areas. Under habitat mitigation, modelling suggests that recovery of suitable habitat of up to 10% is possible. Main conclusions: Extending the climate-only model improves estimates of habitat suitability. Significantly higher inbreeding coefficients were found at immune genes, but not neutral markers in low suitability habitat, indicating a possible impact of environmental stress on evolutionary potential. The potential for habitat mitigation to alleviate distributional changes under future climate change is demonstrated, and specific recommendations are made for habitat recovery on a regional basis

Synthesis and characterization of hybrid organic-inorganic materials based on sulphonated polyamideimide and silica

The preparation of hybrid organic–inorganic membrane materials based on a sulphonated polyamideimide resin and silica filler has been studied. The method allows the sol–gel process to proceed in the presence of a high molecular weight polyamideimide, resulting in well dispersed silica nanoparticles (<50 nm) within the polymer matrix with chemical bonding between the organic and inorganic phases. Tetraethoxysilane (TEOS) was used as the silica precursor and the organosilicate networks were bonded to the polymer matrix via a coupling agent aminopropyltriethoxysilane (APTrEOS). The structure and properties of these hybrid materials were characterized via a range of techniques including FTIR, TGA, DSC, SEM and contact angle analysis. It was found that the compatibility between organic and inorganic phases has been greatly enhanced by the incorporation of APTrEOS. The thermal stability and hydrophilic properties of hybrid materials have also been significantly improved

Pulse Dynamics of an All-Normal-Dispersion Ring Fiber Laser Under Four Different Pulse Regimes

Based on the coupled Ginzburg-Landau equations and Jones matrices of the waveplates considered, a numerical model of an all-normal-dispersion fiber laser mode-locked by nonlinear polarization rotation has been proposed. The operating characteristics of the fiber laser discussed were studied numerically. It has been found that the proposed all-normal-dispersion mode-locked fiber laser (AND-MLFL) could deliver dissipative solitons (DSs) with a M-shaped and U-shaped spectrum, the splitting pulse with a divided spectrum and the amplifier similaritons. The evolution of the intra-cavity pulse and spectrum has been calculated under different regimes and the effects of group velocity dispersion (GVD) and nonlinearity are analyzed. When the fiber laser delivers DSs or causes pulse splitting, nonlinear effects dominate the pulse evolution. With the increase of the accumulated nonlinear phase shift, the operation states change from DS with a M-shaped spectrum to a U-shaped spectrum, and then to the splitting pulse. In the case of amplifier similaritons, both the GVD and nonlinearity play important roles in pulse evolution. The effect of nonlinear polarization rotation and filtering on the pulse reshaping has been analyzed. When the fiber laser delivers DSs with a M-shaped spectrum, the filter has a very weak effect on the pulse and on spectral reshaping. However, when the fiber laser operates in the amplifier similariton state, the filter plays a key role in pulse and spectral reshaping, whereas the nonlinear polarization rotation become less dominant. The dependence of the operational states on the filter bandwidth, fiber length, small signal gain coefficient and orientation of waveplates has also been calculated. A Yb-doped doubled-cladding fiber laser, mode-locked by nonlinear polarization rotation, has also been demonstrated and all of the four pulse regimes are obtained experimentally

A highly divergent Encephalomyocarditis virus isolated from nonhuman primates in Singapore

10.1186/1743-422X-10-248Virology Journal10

Characterization of Turing diffusion-driven instability on evolving domains

In this paper we establish a general theoretical framework for Turing diffusion-driven instability for reaction-diffusion systems on time-dependent evolving domains. The main result is that Turing diffusion-driven instability for reaction-diffusion systems on evolving domains is characterised by Lyapunov exponents of the evolution family associated with the linearised system (obtained by linearising the original system along a spatially independent solution). This framework allows for the inclusion of the analysis of the long-time behavior of the solutions of reaction-diffusion systems. Applications to two special types of evolving domains are considered: (i) time-dependent domains which evolve to a final limiting fixed domain and (ii) time-dependent domains which are eventually time periodic. Reaction-diffusion systems have been widely proposed as plausible mechanisms for pattern formation in morphogenesis