Economic Geology Models 1. Geochemical Exploration and Metallogenic Studies, Northern Chile

Research was initiated in 1998 on geo-chemical methods of exploration for copper porphyry deposits buried under thick, lithified piedmont gravel cover in the Atacama Desert, Chile. Early data suggest that mineralized, saline groundwater has been episodically forced up through fracture zones to the surface during earthquakes, creating geochemical anomalies above ore deposits. Follow-up research supported by the Canadian Mining Industry Research Organization (CAMIRO) examined the composition of both groundwater and surface anomalies, confirming a link between the two. Further work suggests that the geo-chemical anomalies are the surface expression of a process common to the metallogenic evolution of many deposits. Porphyry intrusion and hypo-gene mineralization are controlled by faults, and are followed by supergene enrichment in a semi-arid climate. After burial by Miocene gravels, the climate changed to hyper-arid; estimates of the onset of hyperaridity vary from mid-Miocene (11–14 Ma) to Pliocene (~3–5 Ma). Since then, saline dewatering of the basement along long-lived faults has converted the original super-gene copper oxide assemblage, formed in equilibrium with meteoric water and lacking atacamite, to one containing atacamite [Cu2Cl(OH)3], the copper mineral especially associated with northern Chile. This interpretation is supported by studies showing that the salinity of fluid inclusions in atacamite is similar to that of local groundwater and that atacamite is considerably younger than the co-existing supergene alteration. SOMMAIRE La recherche décrite ici et initiée en 1998 visait à mettre au point des méth-odes d'exploration de gisements de porphyres cuprifères enfouis sous d'épaisses couches lithifiées de graviers dans le désert d'Atacama au Chili. Des données préliminaires indiquent que des eaux souterraines salines minéralisées ont été poussées épisodiquement jusqu'à la surface, à travers des zones de fractures, à l'occasion de séismes, créant ainsi des anomalies au-dessus de gisements minéraux. Une recherche subséquente appuyée par la Canadian Mining Industry Research Organization (CAMIRO) qui a porté sur la composition de l'eau souterraine et des anomalies de surface, a permis de confirmer l'existence d'un lien entre les deux. Les résultats de travaux subséquents permettent de croire que ces anomalies géochimiques sont l'expression en surface d'un processus commun à l'évolution métallogénique de nombreux gisements. L'intrusion porphyrique et la minéralisation hypogène sont tributaires de failles, auxquelles s'est ensuite ajouté un enrichissement supergène sous climat semi-aride. Après l'enfouissement au Miocène par des graviers, le climat est devenu hyper-aride; selon les estimations le climat serait devenu hyperaride entre le Miocène moyen (11-14 Ma) et le Pliocène (~3-5 Ma). Depuis, l'assèchement des eaux salines du socle le long de failles persistantes a entraîné une conversion de l'assemblage original d'oxydes de cuivre supergène - lequel s'était formé en état d'équilibre en milieu d'eau météorique et qui était dépourvu d'atacamite - en un assemblage contenant de l'atacamite [Cu2Cl(OH)3], ce minéral de cuivre typique du Chili du nord. Cette interprétation est corroboré par des études montrant que la salinité des inclusions fluides dans l'atacamite est semblable à celle de l'eau souterraine locale et que l'atacamite est significativement plus jeune que l'altération supergène coexistante

Spatiotemporal and multi-isotope assessment of metal sedimentation in the Great Lakes.

This study investigates spatiotemporal dynamics in metal sedimentation in the North American Great Lakes and their underlying biogeochemical controls. Bulk geochemical and isotope analyses of n=72 surface and core sediment samples show that metal (Cu, Zn, Pb) concentrations and their isotopic compositions vary spatially across oligotrophic to mesotrophic settings, with intra-lake heterogeneity being similar or higher than inter-lake (basin-scale) variability. Concentrations of Cu, Zn, and Pb in sediments from Lake Huron and Lake Erie vary from 5 to 73 mg/kg, 18 to 580 mg/kg, and 5 to 168 mg/kg, respectively, but metal enrichment factors were small (<2) across the surface- and core sediments. The isotopic signatures of surface sediment Cu (δ65Cu between -1.19‰ and +0.96‰), Zn (δ66Zn between -0.09‰ and +0.41‰) and Pb (206/207Pb from 1.200 to 1.263) indicate predominantly lithogenic metal sourcing. In addition, temporal trends in sediment cores from Lake Huron and Lake Erie show uniform metal concentrations, minor enrichment, and Zn and Pb isotopic signatures suggestive of negligible in-lake biogeochemical fractionation. In contrast, Cu isotopic signatures and correlation to chlorophyll and macronutrient levels suggest more differentiation from source variability and/or redox-dependent fractionation, likely related to biological scavenging. Our results are used to derive baseline metal sedimentation fluxes and will help optimize water quality management and strategies for reducing metal loads and enrichment in the Great Lakes and beyond

Atud Gabbro-Diorite Complex: Glimpse of the Cryogenian Mixing, Assimilation, Storage, and Homogenization Zone beneath the Eastern Desert of Egypt

We analysed gabbroic and dioritic rocks from the Atud igneous complex in the Eastern Desert of Egypt to understand better the formation of juvenile continental crust of the Arabian–Nubian Shield. Our results show that the rocks are the same age (U–Pb zircon ages of 694.5 ± 2.1 Ma for two diorites and 695.3 ± 3.4 Ma for one gabbronorite). These are partial melts of the mantle and related fractionates (εNd₆₉₀ = +4.2 to +7.3, ⁸⁷Sr/⁸⁶Sr_i = 0.70246–0.70268, zircon δ¹⁸O ∼ +5‰). Trace element patterns indicate that Atud magmas formed above a subduction zone as part of a large and long-lived (c. 60 myr) convergent margin. Atud complex igneous rocks belong to a larger metagabbro–epidiorite–diorite complex that formed as a deep crustal mush into which new pulses of mafic magma were periodically emplaced, incorporated and evolved. The petrological evolution can be explained by fractional crystallization of mafic magma plus variable plagioclase accumulation in a mid- to lower crustal MASH zone. The Atud igneous complex shows that mantle partial melting and fractional crystallization and plagioclase accumulation were important for Cryogenian crust formation in this part of the Arabian–Nubian Shield

Louisville seamount subduction and its implication on mantle flow beneath the central Tonga–Kermadec arc

Subduction of intraplate seamounts beneath a geochemically depleted mantle wedge provides a seldom opportunity to trace element recycling and mantle flow in subduction zones. Here we present trace element and Sr, Nd and Pb isotopic compositions of lavas from the central Tonga–Kermadec arc, west of the contemporary Louisville–Tonga trench intersection, to provide new insights into the effects of Louisville seamount subduction. Elevated 206Pb/204Pb, 208Pb/204Pb, 86Sr/87Sr in lavas from the central Tonga–Kermadec arc front are consistent with localized input of subducted alkaline Louisville material (lavas and volcaniclastics) into sub-arc partial melts. Furthermore, absolute Pacific Plate motion models indicate an anticlockwise rotation in the subducted Louisville seamount chain that, combined with estimates of the timing of fluid release from the subducting slab, suggests primarily trench-normal mantle flow beneath the central Tonga–Kermadec arc system

Submarine Magmatic-Hydrothermal Systems at the Monowai Volcanic Centre, Kermadec Arc

Authors listed on this Accepted Manuscript vary slightly from those listed on the Version of Record. Harold L. Gibson is an additional author on the published version.The Monowai volcanic centre (MVC) is located at the mid-point along the ~2530 km long Tonga-Kermadec arc system, is probably the most hydrothermally active submarine volcanic system globally. The MVC is comprised of a large elongate caldera (Monowai caldera, 7.9 x 5.7 km; 35 km²; depth to caldera floor is 1590 m), which has formed within an older caldera some 84 km² in area. To the south of the nested caldera system is a large composite volcano, Monowai cone, which rises to within ~ 100 m of the sea surface and has been volcanically active for at least several decades. Despite the large size, mafic volcanic rocks dominate the MVC; basalts are the most common rock type recovered; less common are basaltic andesites and andesites. Hydrothermal plume mapping during the 2004 NZAPLUME III cruise showed at least three major hydrothermal systems associated with the caldera and cone. Monowai cone has hydrothermal venting from the summit. This summit plume is gas-rich and acidic; plume samples show a pH shift of -2.00 pH units, δ³He up to 358 ‰, H₂S concentrations up to 32 μM and CH₄ concentrations up to 900 nM. The summit plume is also metal-rich with elevated total dissolvable Fe (TDFe up to 4200 nM), TDMn (up to 412 nM), and TDFe/TDMn (up to 20.4). Monowai caldera has a major hydrothermal vent system with plumes extending from ~ 1000 to 1400 m depth. The caldera plume has lower values for TDFe, although ranges to higher TDMn concentrations than the summit plume, and is relatively gas-poor (no H₂S detected, pH shift of -0.06 pH units, CH₄ concentrations up to 26 nM). Hydrothermal vents have been observed associated with prominent basaltic andesite ridges (Mussel Ridge) proximal to the southwest wall of the caldera (1025 – 1171 m depth). However, the composition of the hydrothermal plumes in the caldera are different to the vents, indicating that the source of the caldera plumes is at greater depth and is more metal-rich and therefore likely higher temperature. Minor plumes detected as light scattering anomalies down the northern flank of Monowai caldera most likely represent resuspension of volcanic debris. Particulate samples from both the cone sites and the caldera site are enriched in Al, Ti, Ca, Mg, Si, and S, with the cone summit plume especially enriched in K, As, W and Cu, Pb, Zn. The elevated Ti and Al suggest acidic water-rock reactions and intense high-sulfidation alteration of the host volcanic rocks. Observations from submersible dives with Pisces V in 2005 and the remotely operated vehicle ROPOS in 2007 of Mussel Ridge indicate numerous low temperature vents (< 60°C), with a large biomass of vent-associated fauna, in particular large accumulations of the mussel Bathymodiolus sp. and the tubeworm Lamellibrachia sp. We interpret the Monowai volcanic centre as possessing a robust high-sulfidation magmatic-hydrothermal system, with significant differences in the style and composition of venting at the cone and caldera sites. At Monowai cone, the large shifts in pH, elevated TDFe and TDFe/TDMn, and H₂S-, CH₄- and ³He-rich nature of the plume fluids coupled with elevated Ti, P, V, S and Al in the particulates indicates significant magmatic volatile ± metal contributions to the hydrothermal system and aggressive acidic water-rock interaction. By contrast, Monowai caldera has low TDFe/TDMn in hydrothermal plumes; however, end-member vent fluid compositions, combined with presence of alunite, sulfide minerals and native sulfur in samples from Mussel Ridge suggest recent acid volatile-rich venting and active Fe-sulfide formation in the subsurface, and the potential for the presence of significant SMS mineralization

Pleistocene recycling of copper at a porphyry system, Atacama Desert, Chile: Cu isotope evidence

International audienceWe present Cu isotope data of hypogene and supergene minerals from the Late Paleocene Spence Cu-Mo porphyry in the Atacama Desert of northern Chile. Chalcopyrite displays a restricted range of δ65Cu values within the values reported for primary porphyry Cu sulfides (+ 0.28‰ to + 0.34‰, n = 6). Supergene chalcocite samples show heavier and remarkably homogeneous δ65Cu values, between + 3.91‰ and + 3.95‰ (n = 6), consistent with previous models of Cu leaching and enrichment in porphyry systems. Secondary Cu minerals from the oxide zone show a wider range of composition, varying from + 1.28‰ and + 1.37‰ for chrysocolla (n = 6) to very light Cu isotope signatures reported for atacamite between -5.72‰ to -6.77‰ (n = 17). These data suggest redox cycling of Cu during supergene enrichment of the Spence Cu deposit, characterized by a first stage of supergene chalcocite formation from acidic, isotopically-heavy leach fluids of meteoric origin down-flowing in a semi-arid climate (44 to ~ 15-9 Ma). Reworking of the initial supergene copper assemblage, during the Pleistocene, by rising neutral and chlorine-rich deep formation waters under well-established hyper-arid climate conditions lead to the formation of atacamite with extremely fractionated Cu compositions. Essentially coeval chrysocolla formed by dissolution of atacamite during short episodes of wetter climatic conditions occurring in the latest Pleistocene