Influence of Sea-Ice Anomalies on Antarctic Precipitation Using Source Attribution in the Community Earth System Model

We conduct sensitivity experiments using a general circulation model that has an explicit water source tagging capability forced by prescribed composites of pre-industrial sea-ice concentrations (SICs) and corresponding sea surface temperatures (SSTs) to understand the impact of sea-ice anomalies on regional evaporation, moisture transport and sourcereceptor relationships for Antarctic precipitation in the absence of anthropogenic forcing. Surface sensible heat fluxes, evaporation and column-integrated water vapor are larger over Southern Ocean (SO) areas with lower SICs. Changes in Antarctic precipitation and its source attribution with SICs have a strong spatial variability. Among the tagged source regions, the Southern Ocean (south of 50 S) contributes the most (40 %) to the Antarctic total precipitation, followed by more northerly ocean basins, most notably the South Pacific Ocean (27%), southern Indian Ocean (16 %) and South Atlantic Ocean (11 %). Comparing two experiments prescribed with high and low pre-industrial SICs, respectively, the annual mean Antarctic precipitation is about 150 Gt yr1 (or 6 %) more in the lower SIC case than in the higher SIC case. This difference is larger than the model-simulated interannual variability in Antarctic precipitation (99 Gt yr1). The contrast in contribution from the Southern Ocean, 102 Gt yr1, is even more significant compared to the interannual variability of 35 Gt yr1 in Antarctic precipitation that originates from the Southern Ocean. The horizontal transport pathways from individual vapor source regions to Antarctica are largely determined by large-scale atmospheric circulation patterns. Vapor from lower-latitude source regions takes elevated pathways to Antarctica. In contrast, vapor from the Southern Ocean moves southward within the lower troposphere to the Antarctic continent along moist isentropes that are largely shaped by local ambient conditions and coastal topography. This study also highlights the importance of atmospheric dynamics in affecting the thermodynamic impact of sea-ice anomalies associated with natural variability on Antarctic precipitation. Our analyses of the seasonal contrast in changes of basin-scale evaporation, moisture flux and precipitation suggest that the impact of SIC anomalies on regional Antarctic precipitation depends on dynamic changes that arise from SICSST perturbations along with internal variability. The latter appears to have a more significant effect on the moisture transport in austral winter than in summer

Development of a test platform for anti-fouling coatings

Marine fouling, or the growth of marine organisms on fully or partly submerged structures, is an unwanted phenomenon in the marine industry. Bio fouling will increase the hydrodynamic drag of ships, causing an increased fuel consumption, promote the corrosion of the metallic structures and trigger undesired transport of invasive species (IMO and the environment 2009, 2009).The impact is economic as well as environmental. More fuel consumption is synonym for more CO2 and other detrimental emissions, corrosion entails coating and the introduction of toxic substances in the sea and air and the transport of hitch-hikers: non-indigenous species towards locations without natural enemies will harm the local delights of the marine environment.In 2001 the IMO adopted the "International Convention on the Control of Harmful Anti-Fouling Systems on Ships". This convention entered into force 17 September 2008 and prohibited the use of harmful organotins in anti-fouling paints used on ships. A mechanism was established to prevent the future use of other potential harmful substances in anti-fouling systems.The ban on organotins confronted the marine industry with a major challenge. TBT's (TriButylTin) have a negative impact on the marine biotope but till today no equally efficient, harmless, substance has been found. The search for an efficient, economic and ecological friendly novel anti-fouling paint is high on the agenda of IMO, governments, paint producers, ship owners and environmental organizations.All major marine coating producers bring to the market very similar products. Broadly speaking, the present hull anti-fouling systems focus on the following three generic types of AF-coating: firstly, hard coatings, usually biocide-free vinyl esters, reinforced with glass platelets. In actual fact this is not a real anti-fouling coating since fouling will appear over time but it resists mechanical cleaning, even with hard brushes, exceptionally well. Secondly, we have a whole range of soft/smooth paints, often based on silicones or fluoropolymers, rendering the hull surface so slippery that latching onto becomes difficult. Basically this type of coating cleans itself by means of the speed of the ship, the organisms with little adhesion will flush of easily. Finally, the most popular type of fouling protection, have a toxic additive incorporated in the topcoat. Predominantly these additives are copper based products reinforced with booster biocides. Three different techniques are being used to release these toxins in a more or less controlled way. The most primitive system, dating from the 50's, consist out of a soluble matrix, in general colophony mixed with copper, arsenic, zinc, mercury or iron oxides. A few years later, the binder became non-soluble, acrylic resins, vinyl resins or chlorinated rubber polymers were being used together with copper and zinc oxides with or without organometallic compounds. Presently mainly self-polishing copolymers are being used whereby biocides are leached under a controlled manner. While sailing the paint abrades and constantly a new layer of coating, mixed with zinc- or copper oxides emerges.Each of the above described AF-coatings has a very specific and limited field of application. Selecting the correct coating for a specific ship is far from self-evident. Important differences do exist within each coating type, dependent on the manufacturer. Unfortunately, no real objective means of comparing these products exists, neither on performance nor on ecological impact.The aim of this project is to establish an impartial test-protocol and build a platform for testing AF-coatings in a statically and dynamically manner. With knowledge of type, composition and performance of the anti-fouling paints tested we can advise the ship owners in an objective way and evaluate the ecological impact of a paint through a well-founded life cycle analysis

Validation of Two Nonlinear System Identification Techniques Using an Experimental Testbed

The identification of a nonlinear system is performed using experimental data and two different techniques, i.e. a method based on the Wavelet transform and the Restoring Force Surface method. Both techniques exploit the system free response and result in the estimation of linear and nonlinear physical parameters

Starvation Induces Phase-Specific Changes in the Proteome of Mouse Small Intestine

Food deprivation results in metabolic, structural, and functional changes in the small intestine that influences gut mucosal integrity, epithelial cell proliferation, mucin synthesis, and other processes. The underlying mechanisms are still unclear, which lead to the study of molecular effects of short-term and long-term starvation in the intestine of mice. A comparative proteomics approach, combining two-dimensional gel electrophoresis with matrix-assisted laser desorption/ionization time-of-flight mass spectrometry, was used to identify intestinal proteins whose expression is changed under different starvation conditions (0, 12, 24, and 72 h). In total, the expression levels of 80 protein spots changed significantly between the different groups. The results demonstrate that after 12 h of starvation, mainly proteins involved in glycolysis and energy metabolism show decreased expression levels. Starvation for 24 h results in a down-regulation of proteins involved in protein synthesis and amino acid metabolism. Simultaneously, proteins with a protective role, e.g., reg I and II, glutathione peroxidase 3, and carbonic anhydrase 3, are clearly up-regulated. The last starvation phase (72 h) is characterized by increased ezrin expression, which may enhance villus morphogenesis critical for survival. Together, these results provide novel insights in the intestinal starvation response and may contribute to improved nutritional support during conditions characterized by malnutrition

Reconciling the surface temperature–surface mass balance relationship in models and ice cores in Antarctica over the last 2 centuries

Ice cores are an important record of the past surface mass balance (SMB) of ice sheets, with SMB mitigating the ice sheets' sea level impact over the recent decades. For the Antarctic Ice Sheet (AIS), SMB is dominated by large-scale atmospheric circulation, which collects warm moist air from further north and releases it in the form of snow as widespread accumulation or focused atmospheric rivers on the continent. This suggests that the snow deposited at the surface of the AIS should record strongly coupled SMB and surface air temperature (SAT) variations. Ice cores use δ18O as a proxy for SAT as they do not record SAT directly. Here, using isotope-enabled global climate models and the RACMO2.3 regional climate model, we calculate positive SMB–SAT and SMB–δ18O annual correlations over ∼90 % of the AIS. The high spatial resolution of the RACMO2.3 model allows us to highlight a number of areas where SMB and SAT are not correlated, and we show that wind-driven processes acting locally, such as foehn and katabatic effects, can overwhelm the large-scale atmospheric contribution in SMB and SAT responsible for the positive SMB–SAT annual correlations. We focus in particular on Dronning Maud Land, East Antarctica, where the ice promontories clearly show these wind-induced effects. However, using the PAGES2k ice core compilations of SMB and δ18O of Thomas et al. (2017) and Stenni et al. (2017), we obtain a weak annual correlation, on the order of 0.1, between SMB and δ18O over the past ∼150 years. We obtain an equivalently weak annual correlation between ice core SMB and the SAT reconstruction of Nicolas and Bromwich (2014) over the past ∼50 years, although the ice core sites are not spatially co-located with the areas displaying a low SMB–SAT annual correlation in the models. To resolve the discrepancy between the measured and modeled signals, we show that averaging the ice core records in close spatial proximity increases their SMB–SAT annual correlation. This increase shows that the weak measured annual correlation partly results from random noise present in the ice core records, but the change is not large enough to match the annual correlation calculated in the models. Our results thus indicate a positive correlation between SAT and SMB in models and ice core reconstructions but with a weaker value in observations that may be due to missing processes in models or some systematic biases in ice core data that are not removed by a simple average

From vocational training to education: the development of a no-frontiers education policy for Europe?

This article focuses on developments towards an EU educational policy. Education was not included as one of the Community competencies in the Treaty of Rome. The first half of the article analyses the way that the European Court of Justice and the Commission of the European Communities between them managed to develop a series of substantial Community programmes out of Article 128 on vocational training. The second half of the article discusses educational developments in the community following the Treaty on European Union and the Treaty of Amsterdam. Whilst the legal competence of the community now includes education, the author's argument is that the inclusion of an educational competence will not result in further developments to mirror those in the years before the Treaty on Europe</p

Structural and Luminescence Properties of Silica-Based Hybrids Containing New Silylated-Diketonato Europium(III) Complex

A new betadiketonate ligand displaying a trimethoxysilyl group as grafting function and a diketone moiety as complexing site (TTA-Si = 4,4,4-trifluoro-2-(3-trimethoxysilyl)propyl)-1-3-butanedione (C4H3S)COCH[(CH2)3Si(OCH3)3]COCF3) and its highly luminescent europium(III) complex [Eu(TTA-Si)3] have been synthesized and fully characterized. Luminescent silica-based hybrids have been prepared as well with this new complex grafted on the surface of dense silica nanoparticles (28 (+/-3 nm) or on mesoporous silica particles. The covalent bonding of Eu(TTA-Si)3 inside the core of uniform silica nanoparticles (40 (+/- 5 nm) was also achieved. Luminescence properties are discussed in relation to the europium chemical environment involved in each of the three hybrids. The general methodology proposed allowed high grafting ratios and overcame chelate release and tendency to agglomeration, and it could be applied to any silica matrix (in the core or at the surface, nanosized or not, dense or mesoporous) and therefore numerous applications such as luminescent markers and luminophors could be foreseen