Impact interaction of in-flight high-energy molten volcanic ash droplets with jet engines

© 2019 The turbine technology incorporated in jet engines is inherently vulnerable to attack by environmental silicate debris. Amongst the various kinds of such debris, volcanic ash is a particular threat as its glass softens to a liquid at temperatures of 500–800 °C, far below jet engine operating temperatures of ∼1500 °C. As a result, ingested re-molten droplets impact and form splats on the protective thermal barrier coatings (TBCs). Investigation of the damage to jet engines ensuing from this process has, to date been restricted to forensic observations after critical encounters. Here, we employ a thermal spray technology to recreate the ‘in-situ’ generation of molten volcanic ash droplets and observe their morphological evolution and interaction with TBCs. The mechanism of splat formation is found to depend both on substrate topography and on in-flight droplet characteristics, whereby splat circularity increases with surface roughness and with the product of the Weber and Reynolds numbers. The experiments reveal that the molten ash droplet adhesion rate is dictated by droplet temperature and viscosity, ash concentration and substrate roughness. A new dimensionless number, S, is developed to quantify the molten ash droplet adhesion rate to both substrate topography and in-flight droplet characteristics. These findings provide a greatly improved basis for the quantification of the hazard potential of volcanic ash to jet engines and should be incorporated into protocols for operational aviation response during volcanic crises

a comparison of morphological and petrological methods

In planetary sciences, the emplacement of lava flows is commonly modelled using a single rheological parameter (apparent viscosity or apparent yield strength) calculated from morphological dimensions using Jeffreysʼ and Hulmeʼs equations. The rheological parameter is then typically further interpreted in terms of the nature and chemical composition of the lava (e.g., mafic or felsic). Without the possibility of direct sampling of the erupted material, the validity of this approach has remained largely untested. In modern volcanology, the complex rheological behaviour of lavas is measured and modelled as a function of chemical composition of the liquid phase, fractions of crystals and bubbles, temperature and strain rate. Here, we test the planetary approach using a terrestrial basaltic lava flow from the Western Volcanic Zone in Iceland. The geometric parameters required to employ Jeffreysʼ and Hulmeʼs equations are accurately estimated from high-resolution HRSC-AX Digital Elevation Models. Samples collected along the lava flow are used to constrain a detailed model of the transient rheology as a function of cooling, crystallisation, and compositional evolution of the residual melt during emplacement. We observe that the viscosity derived from the morphology corresponds to the value estimated when significant crystallisation inhibits viscous deformation, causing the flow to halt. As a consequence, the inferred viscosity is highly dependent on the details of the crystallisation sequence and crystal shapes, and as such, is neither uniquely nor simply related to the bulk chemical composition of the erupted material. This conclusion, drawn for a mafic lava flow where crystallisation is the primary process responsible for the increase of the viscosity during emplacement, should apply to most of martian, lunar, or mercurian volcanic landforms, which are dominated by basaltic compositions. However, it may not apply to felsic lavas where vitrification resulting from degassing and cooling may ultimately cause lava flows to halt

Sintering of vesiculating pyroclasts

Hot volcanic pyroclasts can sinter, vesiculate, and outgas in concert – a combination of processes which remains poorly constrained. And yet this combination of processes can occur coincidently during deposition from pyroclastic density currents, in conduit-filling pyroclastic debris, and in tuffisites. In many of these settings, it is the sintering-driven evolution of permeability that is key to gas transport through the evolving deposit. Here, we experimentally and theoretically investigate the evolution of the permeable networks during sintering of hot fragmental volcanic systems, which are hydrous and oversaturated at the experimental conditions. Firstly, we find that vesiculation results in shutting of the inter-granular porous network as bubble growth drives expansion of the particles into one another, destroying interconnected pores. Secondly, we observe that degassing by diffusion out of the particle edge results in contraction of the vesicular particles, re-opening pore spaces between them. Therefore, we find that vesiculation, and diffusive outgassing compete to determine both the intra-fragment vesicularity and the permeability during sintering. The development of intra-fragment vesicularity directly impacts the inter-fragment pore space and its connectivity, which decreases during vesiculation and subsequently increases during diffusive outgassing, prompting complex, non-linear permeability evolution.The relative dominance of these processes is fragment size dependent; proportionally, fine fragments lose gas at a higher rate than coarser fragments during diffusive outgassing due to larger surface area to volume ratios. As the systems progress, larger fragments retain a higher proportion of gas and so attain greater vesicularities than finer ones – and therefore, the coarse fragmental pyroclasts experience a greater, yet transient, reduction in connected porosity and permeability. We suggest that where vesiculation is sufficient, it can lead to the complete loss of connected porosity and the sealing of permeable pathways much earlier than in a sintering-only system. Our results suggest that classical sintering models must be modified to account for these vesiculation and diffusive degassing processes, and that only a combined vesiculation, sintering, and diffusive outgassing model can resolve the evolution of permeability in hot clastic volcanic systems

Crystal plasticity as an indicator of the viscous-brittle transition in magmas

Understanding the flow of multi-phase (melt, crystals and bubbles) magmas is of great importance for interpreting eruption dynamics. Here we report the first observation of crystal plasticity, identified using electron backscatter diffraction, in plagioclase in andesite dome lavas from Volcán de Colima, Mexico. The same lavas, deformed experimentally at volcanic conduit temperature and load conditions, exhibit a further, systematic plastic response in the crystalline fraction, observable as a lattice misorientation. At higher stress, and higher crystal fraction, the amount of strain accommodated by crystal plasticity is larger. Crystal plastic distortion is highest in the intact segments of broken crystals, which have exceeded their plastic limit. We infer that crystal plasticity precludes failure and can punctuate the viscous-brittle transition in crystal-bearing magmas at certain shallow magmatic conditions. Since crystal plasticity varies systematically with imposed conditions, this raises the possibility that it may be used as a strain marker in well-constrained systems

Eruptive shearing of tube pumice: pure and simple

Abstract. Understanding the physico-chemical conditions extant and mechanisms operative during explosive volcanism is essential for reliable forecasting and mitigation of volcanic events. Rhyolitic pumices reflect highly vesiculated magma whose bubbles can serve as a strain indicator for inferring the state of stress operative immediately prior to eruptive fragmentation. Obtaining the full kinematic picture reflected in bubble population geometry has been extremely difficult, involving dissection of a small number of delicate samples. The advent of reliable high-resolution tomography has changed this situation radically. Here we demonstrate via the use of tomography how a statistically powerful picture of the shapes and connectivity of thousands of individual bubbles within a single sample of tube pumice emerges. The strain record of tube pumice is dominated by simple shear (not pure shear) in the late deformational history of vesicular magma before eruption. This constraint in turn implies that magma ascent is conditioned by a velocity gradient at the point of origin of tube pumice. Magma ascent accompanied by simple shear should enhance high eruption rates inferred independently for these highly viscous systems. </jats:p

Magma mixing enhanced by bubble segregation

In order to explore the materials' complexity induced by bubbles rising through mixing magmas, bubble-advection experiments have been performed, employing natural silicate melts at magmatic temperatures. A cylinder of basaltic glass was placed below a cylinder of rhyolitic glass. Upon melting, bubbles formed from interstitial air. During the course of the experimental runs, those bubbles rose via buoyancy forces into the rhyolitic melt, thereby entraining tails of basaltic liquid. In the experimental run products, these plume-like filaments of advected basalt within rhyolite were clearly visible and were characterised by microCT and high-resolution EMP analyses. The entrained filaments of mafic material have been hybridised. Their post-experimental compositions range from the originally basaltic composition through andesitic to rhyolitic composition. Rheological modelling of the compositions of these hybridised filaments yield viscosities up to 2 orders of magnitude lower than that of the host rhyolitic liquid. Importantly, such lowered viscosities inside the filaments implies that rising bubbles can ascend more efficiently through pre-existing filaments that have been generated by earlier ascending bubbles. MicroCT imaging of the run products provides textural confirmation of the phenomenon of bubbles trailing one another through filaments. This phenomenon enhances the relevance of bubble advection in magma mixing scenarios, implying as it does so, an acceleration of bubble ascent due to the decreased viscous resistance facing bubbles inside filaments and yielding enhanced mass flux of mafic melt into felsic melt via entrainment. In magma mixing events involving melts of high volatile content, bubbles may be an essential catalyst for magma mixing. Moreover, the reduced viscosity contrast within filaments implies repeated replenishment of filaments with fresh end-member melt. As a result, complex compositional gradients and therefore diffusion systematics can be expected at the filament-host melt interface, due to the repetitive nature of the process. However, previously magmatic filaments were tacitly assumed to be of single-pulse origin. Consequently, the potential for multi-pulse filaments has to be considered in outcrop analyses. As compositional profiles alone may remain ambiguous for constraining the origin of filaments, and as 3-D visual evidence demonstrates that filaments may have experienced multiple bubbles passages even when featuring standard diffusion gradients, therefore, the calculation of diffusive timescales may be inadequate for constraining timescales in cases where bubbles have played an essential role in magma mixing. Data analysis employing concentration variance relaxation in natural samples can distinguish conventional single-pulse filaments from advection via multiple bubble ascent advection in natural samples, raising the prospect of yet another powerful application of this novel petrological tool

Absolute Paleointensity Study of Miocene Tiva Canyon Tuff, Yucca Mountain, Nevada: Role of Fine‐Particle Grain‐Size Variations

Fine‐grained, Ti‐poor titanomagnetite in the ~12.7 Ma Tiva Canyon (TC) Tuff systematically increases in grain size from superparamagnetic (SP) at the flow base to single domain (SD) at a few meters height. This allows us to examine the role of grain‐size variation on paleointensity, within the transition from SP to stable SD. We present magnetic properties from two previously unreported sections of the TC Tuff, as well as Thellier‐type paleointensity estimates from the lowermost ~7.0 m of the flow. Magnetic hysteresis, frequency‐dependent susceptibility, and thermomagnetic data show that sample grain‐size distribution is dominated by SP in the lower ~3.6 m, transitioning upwards to mostly stable SD. Paleointensity results are closely tied to stratigraphic height and to magnetic properties linked to domain state. SD samples have consistent absolute paleointensity values of 28.5 ± 1.94 μT (VADM of 51.3 ZAm2) and behaved ideally during paleointensity experiments. The samples including a significant SP fraction have consistently higher paleointensities and less ideal behavior but would likely pass many traditional quality‐control tests. We interpret the SD remanence to be a primary thermal remanent magnetization but discuss the possibility of a partial thermal‐chemical remanent magnetization if microcrystal growth continued at T \u3c Tc and/or the section is affected by post‐emplacement vapor‐phase alteration. The link between paleointensity and domain state is stronger than correlations with water content or other evidence of alteration and suggests that the presence of a significant SP population may adversely impact paleointensity results, even in the presence of a stable SD fraction

Topological inversions in coalescing granular media control fluid-flow regimes

Sintering—or coalescence—of viscous droplets is an essential process in many natural and industrial scenarios. Current physical models of the dynamics of sintering are limited by the lack of an explicit account of the evolution of microstructural geometry. Here, we use high-speed time-resolved x-ray tomography to image the evolving geometry of a sintering system of viscous droplets, and use lattice Boltzmann simulations of creeping fluid flow through the reconstructed pore space to determine its permeability. We identify and characterize a topological inversion, from spherical droplets in a continuous interstitial gas, to isolated bubbles in a continuous liquid. We find that the topological inversion is associated with a transition in permeability-porosity behavior, from Stokes permeability at high porosity, to percolation theory at low porosity. We use these findings to construct a unified physical description that reconciles previously incompatible models for the evolution of porosity and permeability during sintering

Transcriptional Basis of Mouse and Human Dendritic Cell Heterogeneity

Dendritic cells (DCs) play a critical role in orchestrating adaptive immune responses due to their unique ability to initiate T cell responses and direct their differentiation into effector lineages. Classical DCs have been divided into two subsets, cDC1 and cDC2, based on phenotypic markers and their distinct abilities to prime CD8 and CD4 T cells. While the transcriptional regulation of the cDC1 subset has been well characterized, cDC2 development and function remain poorly understood. By combining transcriptional and chromatin analyses with genetic reporter expression, we identified two principal cDC2 lineages defined by distinct developmental pathways and transcriptional regulators, including T-bet and RORgt, two key transcription factors known to define innate and adaptive lymphocyte subsets. These novel cDC2 lineages were characterized by distinct metabolic and functional programs. Extending our findings to humans revealed conserved DC heterogeneity and the presence of the newly defined cDC2 subsets in human cancer