Assessment of Models of Chemically Reacting Granular Flows

A report presents an assessment of a general mathematical model of dense, chemically reacting granular flows like those in fluidized beds used to pyrolize biomass. The model incorporates submodels that have been described in several NASA Tech Briefs articles, including "Generalized Mathematical Model of Pyrolysis of Biomass" (NPO-20068) NASA Tech Briefs, Vol. 22, No. 2 (February 1998), page 60; "Model of Pyrolysis of Biomass in a Fluidized-Bed Reactor" (NPO-20708), NASA Tech Briefs, Vol. 25, No. 6 (June 2001), page 59; and "Model of Fluidized Bed Containing Reacting Solids and Gases" (NPO- 30163), which appears elsewhere in this issue. The model was used to perform computational simulations in a test case of pyrolysis in a reactor containing sand and biomass (i.e., plant material) particles through which passes a flow of hot nitrogen. The boundary conditions and other parameters were selected for the test case to enable assessment of the validity of some assumptions incorporated into submodels of granular stresses, granular thermal conductivity, and heating of particles. The results of the simulation are interpreted as partly affirming the assumptions in some respects and indicating the need for refinements of the assumptions and the affected submodels in other respects

Numerical Study of Pyrolysis of Biomass in Fluidized Beds

A report presents a numerical-simulation study of pyrolysis of biomass in fluidized-bed reactors, performed by use of the mathematical model described in Model of Fluidized Bed Containing Reacting Solids and Gases (NPO-30163), which appears elsewhere in this issue of NASA Tech Briefs. The purpose of the study was to investigate the effect of various operating conditions on the efficiency of production of condensable tar from biomass. The numerical results indicate that for a fixed particle size, the fluidizing-gas temperature is the foremost parameter that affects the tar yield. For the range of fluidizing-gas temperatures investigated, and under the assumption that the pyrolysis rate exceeds the feed rate, the optimum steady-state tar collection was found to occur at 750 K. In cases in which the assumption was not valid, the optimum temperature for tar collection was found to be only slightly higher. Scaling up of the reactor was found to exert a small negative effect on tar collection at the optimal operating temperature. It is also found that slightly better scaling is obtained by use of shallower fluidized beds with greater fluidization velocities

Systematic analysis of the kalimantacin assembly line NRPS module using an adapted targeted mutagenesis approach

Kalimantacin is an antimicrobial compound with strong antistaphylococcal activity that is produced by a hybrid trans-acyltransferase polyketide synthase/nonribosomal peptide synthetase system in Pseudomonas fluorescens BCCM_ID9359. We here present a systematic analysis of the substrate specificity of the glycine-incorporating adenylation domain from the kalimantacin biosynthetic assembly line by a targeted mutagenesis approach. The specificity-conferring code was adapted for use in Pseudomonas and mutated adenylation domain active site sequences were introduced in the kalimantacin gene cluster, using a newly adapted ligation independent cloning method. Antimicrobial activity screens and LC-MS analyses revealed that the production of the kalimantacin analogues in the mutated strains was abolished. These results support the idea that further insight in the specificity of downstream domains in nonribosomal peptide synthetases and polyketide synthases is required to efficiently engineer these strains in vivo

SUSY Intertwining Relations of Third Order in Derivatives

The general solution of the intertwining relations between a pair of Schr\"odinger Hamiltonians by the supercharges of third order in derivatives is obtained. The solution is expressed in terms of one arbitrary function. Some properties of the spectrum of the Hamiltonian are derived, and wave functions for three energy levels are constructed. This construction can be interpreted as addition of three new levels to the spectrum of partner potential: a ground state and a pair of levels between successive excited states. Possible types of factorization of the third order supercharges are analysed, the connection with earlier known results is discussed.Comment: 17

Evaluation Of Glueball Masses From Supergravity

In the framework of the conjectured duality relation between large $N$ gauge theory and supergravity the spectra of masses in large $N$ gauge theory can be determined by solving certain eigenvalue problems in supergravity. In this paper we study the eigenmass problem given by Witten as a possible approximation for masses in QCD without supersymmetry. We place a particular emphasis on the treatment of the horizon and related boundary conditions. We construct exact expressions for the analytic expansions of the wave functions both at the horizon and at infinity and show that requiring smoothness at the horizon and normalizability gives a well defined eigenvalue problem. We show for example that there are no smooth solutions with vanishing derivative at the horizon. The mass eigenvalues up to $m^{2}=1000$ corresponding to smooth normalizable wave functions are presented. We comment on the relation of our work with the results found in a recent paper by Cs\'aki et al., hep-th/9806021, which addresses the same problem.Comment: 20 pages,Latex,3 figs,psfig.tex, added refs., minor change

Supersymmetry and Singular Potentials

The breaking of supersymmetry due to singular potentials in supersymmetric quantum mechanics is critically analyzed. It is shown that, when properly regularized, these potentials respect supersymmetry, even when the regularization parameter is removed.Comment: 28 page