40,231 research outputs found

    A Laplace Transform Method for Molecular Mass Distribution Calculation from Rheometric Data

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    Polydisperse linear polymer melts can be microscopically described by the tube model and fractal reptation dynamics, while on the macroscopic side the generalized Maxwell model is capable of correctly displaying most of the rheological behavior. In this paper, a Laplace transform method is derived and different macroscopic starting points for molecular mass distribution calculation are compared to a classical light scattering evaluation. The underlying assumptions comprise the modern understanding on polymer dynamics in entangled systems but can be stated in a mathematically generalized way. The resulting method is very easy to use due to its mathematical structure and it is capable of calculating multimodal molecular mass distributions of linear polymer melts

    Measurements in the Turbulent Boundary Layer at Constant Pressure in Subsonic and Supersonic Flow. Part 2: Laser-Doppler Velocity Measurements

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    A description of both the mean and the fluctuating components of the flow, and of the Reynolds stress as observed using a dual forward scattering laser-Doppler velocimeter is presented. A detailed description of the instrument and of the data analysis techniques were included in order to fully document the data. A detailed comparison was made between the laser-Doppler results and those presented in Part 1, and an assessment was made of the ability of the laser-Doppler velocimeter to measure the details of the flows involved

    The moduli space of hypersurfaces whose singular locus has high dimension

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    Let kk be an algebraically closed field and let bb and nn be integers with n3n\geq 3 and 1bn1.1\leq b \leq n-1. Consider the moduli space XX of hypersurfaces in Pkn\mathbb{P}^n_k of fixed degree ll whose singular locus is at least bb-dimensional. We prove that for large ll, XX has a unique irreducible component of maximal dimension, consisting of the hypersurfaces singular along a linear bb-dimensional subspace of Pn\mathbb{P}^n. The proof will involve a probabilistic counting argument over finite fields.Comment: Final version, including the incorporation of all comments by the refere

    Resistivity studies under hydrostatic pressure on a low-resistance variant of the quasi-2D organic superconductor kappa-(BEDT-TTF)2Cu[N(CN)2]Br: quest for intrinsic scattering contributions

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    Resistivity measurements have been performed on a low (LR)- and high (HR)-resistance variant of the kappa-(BEDT-TTF)_2Cu[N(CN)_2]Br superconductor. While the HR sample was synthesized following the standard procedure, the LR crystal is a result of a somewhat modified synthesis route. According to their residual resistivities and residual resistivity ratios, the LR crystal is of distinctly superior quality. He-gas pressure was used to study the effect of hydrostatic pressure on the different transport regimes for both variants. The main results of these comparative investigations are (i) a significant part of the inelastic-scattering contribution, which causes the anomalous rho(T) maximum in standard HR crystals around 90 K, is sample dependent, i.e. extrinsic in nature, (ii) the abrupt change in rho(T) at T* approx. 40 K from a strongly temperature-dependent behavior at T > T* to an only weakly T-dependent rho(T) at T < T* is unaffected by this scattering contribution and thus marks an independent property, most likely a second-order phase transition, (iii) both variants reveal a rho(T) proportional to AT^2 dependence at low temperatures, i.e. for T_c < T < T_0, although with strongly sample-dependent coefficients A and upper bounds for the T^2 behavior measured by T_0. The latter result is inconsistent with the T^2 dependence originating from coherent Fermi-liquid excitations.Comment: 8 pages, 6 figure
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