5,097 research outputs found
Composition of essential oils from the species Ardisia humilis and Myrsine lineata (Primulaceae).
Poster 2015. SBOE 2015
Recommended from our members
Sulfur-Modulated Tin Sites Enable Highly Selective Electrochemical Reduction of CO2 to Formate
Electrochemical reduction of carbon dioxide (CO2RR) to formate provides an avenue to the synthesis of value-added carbon-based fuels and feedstocks powered using renewable electricity. Here, we hypothesized that the presence of sulfur atoms in the catalyst surface could promote undercoordinated sites, and thereby improve the electrochemical reduction of CO2 to formate. We explored, using density functional theory, how the incorporation of sulfur into tin may favor formate generation. We used atomic layer deposition of SnSx followed by a reduction process to synthesize sulfur-modulated tin (Sn(S)) catalysts. X-ray absorption near-edge structure (XANES) studies reveal higher oxidation states in Sn(S) compared with that of tin in Sn nanoparticles. Sn(S)/Au accelerates CO2RR at geometric current densities of 55 mA cm−2 at −0.75 V versus reversible hydrogen electrode with a Faradaic efficiency of 93%. Furthermore, Sn(S) catalysts show excellent stability without deactivation (<2% productivity change) following more than 40 hours of operation. With rapid advances in the efficient and cost-effective conversion of sunlight to electrical power, the development of storage technologies for renewable energy is even more urgent. Using renewable electricity to convert CO2 into formate simultaneously addresses the need for storage of intermittent renewable energy sources and the need to reduce greenhouse gas emissions. We report an increase of greater than 4-fold in the current density (hence the rate of reaction) in formate electrosynthesis compared with relevant controls. Our catalysts also show excellent stability without deactivation (<2% productivity change) following more than 40 hours of operation. The electrochemical reduction of carbon dioxide (CO2RR) offers a compelling route to energy storage and high-value chemical manufacture. The presence of sulfur atoms in catalyst surfaces promotes undercoordinated sites, thereby improving the electrochemical reduction of CO2 to formate. The resulting sulfur-modulated tin catalysts accelerate CO2RR at geometric current densities of 55 mA cm−2 at −0.75 V versus RHE with a Faradaic efficiency of 93%
On the Spiral Structure of the Milky Way Galaxy
We consider the possible pattern of the overall spiral structure of the
Galaxy, using data on the distribution of neutral (atomic), molecular, and
ionized hydrogen, on the base of the hypothesis of the spiral structure being
symmetric, i.e. the assumption that spiral arms are translated into each other
for a rotation around the galactic center by 180{\deg} (a two-arm pattern) or
by 90{\deg} (a four-arm pattern). We demonstrate that, for the inner region,
the observations are best represented with a four-arm scheme of the spiral
pattern, associated with all-Galaxy spiral density waves. The basic position is
that of the Carina arm, reliably determined from distances to HII regions and
from HI and H2 radial velocities. This pattern is continued in the quadrants
III and IV with weak outer HI arms; from their morphology, the Galaxy should be
considered an asymmetric multi-arm spiral. The kneed shape of the outer arms
that consist of straight segments can indicate that these arms are transient
formations that appeared due to a gravitational instability in the gas disk.
The distances between HI superclouds in the two arms that are the brightest in
neutral hydrogen, the Carina arm and the Cygnus (Outer) arm, concentrate to two
values, permitting to assume the presence of a regular magnetic field in these
arms.Comment: 21 pages, 14 fugures; accepted for publication in Astronomichesky
Journal (Astron. Rep.
Event by event analysis of collision induced cluster ion fragmentation: sequential monomer evaporation versus fission reactions
IP
P-P Total Cross Sections at VHE from Accelerator Data
Comparison of P-P total cross-sections estimations at very high energies -
from accelerators and cosmic rays - shows a disagreement amounting to more than
10 %, a discrepancy which is beyond statistical errors. Here we use a
phenomenological model based on the Multiple-Diffraction approach to
successfully describe data at accelerator energies. The predictions of the
model are compared with data On the basis of regression analysis we determine
confident error bands, analyzing the sensitivity of our predictions to the
employed data for extrapolation. : using data at 546 and 1.8 TeV, our
extrapolations for p-p total cross-sections are only compatible with the Akeno
cosmic ray data, predicting a slower rise with energy than other cosmic ray
results and other extrapolation methods. We discuss our results within the
context of constraints in the light of future accelerator and cosmic ray
experimental results.Comment: 26 pages aqnd 11 figure
Analytic models and forward scattering from accelerator to cosmic-ray energies
Analytic models for hadron-hadron scattering are characterized by analytical
parametrizations for the forward amplitudes and the use of dispersion relation
techniques to study the total cross section and the
parameter. In this paper we investigate four aspects related to the application
of the model to and scattering, from accelerator to cosmic-ray
energies: 1) the effect of different estimations for from
cosmic-ray experiments; 2) the differences between individual and global
(simultaneous) fits to and ; 3) the role of the
subtraction constant in the dispersion relations; 4) the effect of distinct
asymptotic inputs from different analytic models. This is done by using as a
framework the single Pomeron and the maximal Odderon parametrizations for the
total cross section. Our main conclusions are the following: 1) Despite the
small influence from different cosmic-ray estimations, the results allow us to
extract an upper bound for the soft pomeron intercept: ;
2) although global fits present good statistical results, in general, this
procedure constrains the rise of ; 3) the subtraction constant as
a free parameter affects the fit results at both low and high energies; 4)
independently of the cosmic-ray information used and the subtraction constant,
global fits with the odderon parametrization predict that, above GeV, becomes greater than , and
this result is in complete agreement with all the data presently available. In
particular, we infer at GeV and
at 500 GeV (BNL RHIC energies).Comment: 16 pages, 7 figures, aps-revtex, wording changes, corrected typos, to
appear in Physical Review
Observation of confined current ribbon in JET plasmas
we report the identification of a localised current structure inside the JET
plasma. It is a field aligned closed helical ribbon, carrying current in the
same direction as the background current profile (co-current), rotating
toroidally with the ion velocity (co-rotating). It appears to be located at a
flat spot in the plasma pressure profile, at the top of the pedestal. The
structure appears spontaneously in low density, high rotation plasmas, and can
last up to 1.4 s, a time comparable to a local resistive time. It considerably
delays the appearance of the first ELM.Comment: 10 pages, 6 figure
Antibiofilm Activity of Acidic Phospholipase Isoform Isolated from Bothrops erythromelas Snake Venom.
The future of Cybersecurity in Italy: Strategic focus area
This volume has been created as a continuation of the previous one, with the aim of outlining a set of focus areas and actions that the Italian Nation research community considers essential. The book touches many aspects of cyber security, ranging from the definition of the infrastructure and controls needed to organize cyberdefence to the actions and technologies to be developed to be better protected, from the identification of the main technologies to be defended to the proposal of a set of horizontal actions for training, awareness raising, and risk management
Levantamento fitossociológico do estrato herbáceo em área de Caatinga pastejada por caprinos durante o período chuvoso.
Objetivou-se realizar o levantamento fitossociológico do estrato herbáceo de uma área de Caatinga pastejada por caprinos durante o período chuvoso (fevereiro a julho), realizado na fazenda experimental Crioula, CE. Numa área de 4,8 ha utilizada durante todo ano por 19 matrizes Anglo-Nubiana foram realizadas coletas mensais para identificação das espécies presentes utilizando uma moldura com dimensão de 1,0 m x 0,25 m, lançada 20 vezes em toda a área. Hyptis suaveolans (L.) Poit e Blainvillea rhomboidea Cass. se destacaram com maiores densidades (DR) e frequências relativas (FR) durante todo período de avaliação. A abundância relativa (ABU) teve como destaque Hyptis suaveolans (L.) Poit e Blainvillea rhomboidea Cass de fevereiro a abril e Cyperus rotundus L. em maio. Apesar do razoável número de espécies monitoradas, a dominância de espécies de pouco ou nenhum valor forrageiro no extrato herbáceo, indicaram elevado nível de degradação da pastagem. Além da heterogeneidade de fatores climáticos, o ciclo de vida efêmero de algumas espécies presentes na área afetou a fitossociológia durante do período chuvoso
- …