Composition of essential oils from the species Ardisia humilis and Myrsine lineata (Primulaceae).

Poster 2015. SBOE 2015

Sulfur-Modulated Tin Sites Enable Highly Selective Electrochemical Reduction of CO2 to Formate

Electrochemical reduction of carbon dioxide (CO2RR) to formate provides an avenue to the synthesis of value-added carbon-based fuels and feedstocks powered using renewable electricity. Here, we hypothesized that the presence of sulfur atoms in the catalyst surface could promote undercoordinated sites, and thereby improve the electrochemical reduction of CO2 to formate. We explored, using density functional theory, how the incorporation of sulfur into tin may favor formate generation. We used atomic layer deposition of SnSx followed by a reduction process to synthesize sulfur-modulated tin (Sn(S)) catalysts. X-ray absorption near-edge structure (XANES) studies reveal higher oxidation states in Sn(S) compared with that of tin in Sn nanoparticles. Sn(S)/Au accelerates CO2RR at geometric current densities of 55 mA cm−2 at −0.75 V versus reversible hydrogen electrode with a Faradaic efficiency of 93%. Furthermore, Sn(S) catalysts show excellent stability without deactivation (<2% productivity change) following more than 40 hours of operation. With rapid advances in the efficient and cost-effective conversion of sunlight to electrical power, the development of storage technologies for renewable energy is even more urgent. Using renewable electricity to convert CO2 into formate simultaneously addresses the need for storage of intermittent renewable energy sources and the need to reduce greenhouse gas emissions. We report an increase of greater than 4-fold in the current density (hence the rate of reaction) in formate electrosynthesis compared with relevant controls. Our catalysts also show excellent stability without deactivation (<2% productivity change) following more than 40 hours of operation. The electrochemical reduction of carbon dioxide (CO2RR) offers a compelling route to energy storage and high-value chemical manufacture. The presence of sulfur atoms in catalyst surfaces promotes undercoordinated sites, thereby improving the electrochemical reduction of CO2 to formate. The resulting sulfur-modulated tin catalysts accelerate CO2RR at geometric current densities of 55 mA cm−2 at −0.75 V versus RHE with a Faradaic efficiency of 93%

On the Spiral Structure of the Milky Way Galaxy

We consider the possible pattern of the overall spiral structure of the Galaxy, using data on the distribution of neutral (atomic), molecular, and ionized hydrogen, on the base of the hypothesis of the spiral structure being symmetric, i.e. the assumption that spiral arms are translated into each other for a rotation around the galactic center by 180{\deg} (a two-arm pattern) or by 90{\deg} (a four-arm pattern). We demonstrate that, for the inner region, the observations are best represented with a four-arm scheme of the spiral pattern, associated with all-Galaxy spiral density waves. The basic position is that of the Carina arm, reliably determined from distances to HII regions and from HI and H2 radial velocities. This pattern is continued in the quadrants III and IV with weak outer HI arms; from their morphology, the Galaxy should be considered an asymmetric multi-arm spiral. The kneed shape of the outer arms that consist of straight segments can indicate that these arms are transient formations that appeared due to a gravitational instability in the gas disk. The distances between HI superclouds in the two arms that are the brightest in neutral hydrogen, the Carina arm and the Cygnus (Outer) arm, concentrate to two values, permitting to assume the presence of a regular magnetic field in these arms.Comment: 21 pages, 14 fugures; accepted for publication in Astronomichesky Journal (Astron. Rep.

Event by event analysis of collision induced cluster ion fragmentation: sequential monomer evaporation versus fission reactions

IP

P-P Total Cross Sections at VHE from Accelerator Data

Comparison of P-P total cross-sections estimations at very high energies - from accelerators and cosmic rays - shows a disagreement amounting to more than 10 %, a discrepancy which is beyond statistical errors. Here we use a phenomenological model based on the Multiple-Diffraction approach to successfully describe data at accelerator energies. The predictions of the model are compared with data On the basis of regression analysis we determine confident error bands, analyzing the sensitivity of our predictions to the employed data for extrapolation. : using data at 546 and 1.8 TeV, our extrapolations for p-p total cross-sections are only compatible with the Akeno cosmic ray data, predicting a slower rise with energy than other cosmic ray results and other extrapolation methods. We discuss our results within the context of constraints in the light of future accelerator and cosmic ray experimental results.Comment: 26 pages aqnd 11 figure

Analytic models and forward scattering from accelerator to cosmic-ray energies

Analytic models for hadron-hadron scattering are characterized by analytical parametrizations for the forward amplitudes and the use of dispersion relation techniques to study the total cross section $\sigma_{tot}$ and the $\rho$ parameter. In this paper we investigate four aspects related to the application of the model to $pp$ and $\bar{p}p$ scattering, from accelerator to cosmic-ray energies: 1) the effect of different estimations for $\sigma_{tot}$ from cosmic-ray experiments; 2) the differences between individual and global (simultaneous) fits to $\sigma_{tot}$ and $\rho$; 3) the role of the subtraction constant in the dispersion relations; 4) the effect of distinct asymptotic inputs from different analytic models. This is done by using as a framework the single Pomeron and the maximal Odderon parametrizations for the total cross section. Our main conclusions are the following: 1) Despite the small influence from different cosmic-ray estimations, the results allow us to extract an upper bound for the soft pomeron intercept: $1 + \epsilon = 1.094$; 2) although global fits present good statistical results, in general, this procedure constrains the rise of $\sigma_{tot}$; 3) the subtraction constant as a free parameter affects the fit results at both low and high energies; 4) independently of the cosmic-ray information used and the subtraction constant, global fits with the odderon parametrization predict that, above $\sqrt s \approx 70$ GeV, $\rho_{pp}(s)$ becomes greater than $\rho_{\bar{p}p}(s)$, and this result is in complete agreement with all the data presently available. In particular, we infer $\rho_{pp} = 0.134 \pm 0.005$ at $\sqrt s = 200$ GeV and $0.151 \pm 0.007$ at 500 GeV (BNL RHIC energies).Comment: 16 pages, 7 figures, aps-revtex, wording changes, corrected typos, to appear in Physical Review

Observation of confined current ribbon in JET plasmas

we report the identification of a localised current structure inside the JET plasma. It is a field aligned closed helical ribbon, carrying current in the same direction as the background current profile (co-current), rotating toroidally with the ion velocity (co-rotating). It appears to be located at a flat spot in the plasma pressure profile, at the top of the pedestal. The structure appears spontaneously in low density, high rotation plasmas, and can last up to 1.4 s, a time comparable to a local resistive time. It considerably delays the appearance of the first ELM.Comment: 10 pages, 6 figure

The future of Cybersecurity in Italy: Strategic focus area

This volume has been created as a continuation of the previous one, with the aim of outlining a set of focus areas and actions that the Italian Nation research community considers essential. The book touches many aspects of cyber security, ranging from the definition of the infrastructure and controls needed to organize cyberdefence to the actions and technologies to be developed to be better protected, from the identification of the main technologies to be defended to the proposal of a set of horizontal actions for training, awareness raising, and risk management

Levantamento fitossociológico do estrato herbáceo em área de Caatinga pastejada por caprinos durante o período chuvoso.

Objetivou-se realizar o levantamento fitossociológico do estrato herbáceo de uma área de Caatinga pastejada por caprinos durante o período chuvoso (fevereiro a julho), realizado na fazenda experimental Crioula, CE. Numa área de 4,8 ha utilizada durante todo ano por 19 matrizes Anglo-Nubiana foram realizadas coletas mensais para identificação das espécies presentes utilizando uma moldura com dimensão de 1,0 m x 0,25 m, lançada 20 vezes em toda a área. Hyptis suaveolans (L.) Poit e Blainvillea rhomboidea Cass. se destacaram com maiores densidades (DR) e frequências relativas (FR) durante todo período de avaliação. A abundância relativa (ABU) teve como destaque Hyptis suaveolans (L.) Poit e Blainvillea rhomboidea Cass de fevereiro a abril e Cyperus rotundus L. em maio. Apesar do razoável número de espécies monitoradas, a dominância de espécies de pouco ou nenhum valor forrageiro no extrato herbáceo, indicaram elevado nível de degradação da pastagem. Além da heterogeneidade de fatores climáticos, o ciclo de vida efêmero de algumas espécies presentes na área afetou a fitossociológia durante do período chuvoso