352 research outputs found
Recommended from our members
Molecular structure determination for photogenerated intermediates in photoinduced electron transfer reactions using steady-state and transient XAFS
Many photoinduced electron transfer reactions are accompanied by nuclear rearrangements of the molecules involved. In order to understand the reactivities of the molecules and the reaction mechanisms, precise information on the molecular structural changes accompanying the electron transfer is often required. We present here conventional XAFS and transient energy dispersive XAFS studies on structures of excited and photoinduced charge separated state of porphyrin and porphyrin based supermolecules, and structures of TiO{sub 2} colloid and the heavymetal ions that bind to the colloid surfaces during photocatalytic reductions
Preparation, characterization and anti-ageing activity of Gastrodia elata blume polysaccharide
Gastrodia elata Blume polysaccharide (GEP) was extracted and then chemically characterised. Its antioxidant activity was evaluated in vitro and in vivo. The results of the in vitro investigation show that GEP consists of glucose with molecular weight of 875 185 Da and exhibits high hydroxyl radical scavenging, as well as 2,2-diphenyl-1- picrylhydrazyl activity and reducing capacity. For antioxidant activity in vivo, D-galactose-induced-aged mice were orally administered with three different doses of GEP over a period of 6 weeks. The administration of GEP dosedependently increased the body weight gain rates, liver and brain indices, superoxide dismutase and glutathione peroxidase activities, and malondialdehyde levels in the sera and brains of ageing mice. These results suggest that GEP exhibits high antioxidant activity and can retard human ageing associated with free radicals
The superconductivity at 18 K in LiFeAs system
A new iron arsenide superconducting system LiFeAs was found that crystallizes
into a tetragonal structure with space group P4/nmm. The superconductivity with
Tc up to 18 K was observed in the compounds. This simple 111 type layered iron
arsenide superconductor can be viewed as an analogue of the infinite layer
structure of copper oxides.Comment: 11 pages 3 Figure
Carbon nanotubes adhesion and nanomechanical behavior from peeling force spectroscopy
Applications based on Single Walled Carbon Nanotube (SWNT) are good example
of the great need to continuously develop metrology methods in the field of
nanotechnology. Contact and interface properties are key parameters that
determine the efficiency of SWNT functionalized nanomaterials and nanodevices.
In this work we have taken advantage of a good control of the SWNT growth
processes at an atomic force microscope (AFM) tip apex and the use of a low
noise (1E-13 m/rtHz) AFM to investigate the mechanical behavior of a SWNT
touching a surface. By simultaneously recording static and dynamic properties
of SWNT, we show that the contact corresponds to a peeling geometry, and
extract quantities such as adhesion energy per unit length, curvature and
bending rigidity of the nanotube. A complete picture of the local shape of the
SWNT and its mechanical behavior is provided
Observational constraint on generalized Chaplygin gas model
We investigate observational constraints on the generalized Chaplygin gas
(GCG) model as the unification of dark matter and dark energy from the latest
observational data: the Union SNe Ia data, the observational Hubble data, the
SDSS baryon acoustic peak and the five-year WMAP shift parameter. It is
obtained that the best fit values of the GCG model parameters with their
confidence level are ()
, ()
. Furthermore in this model, we can see that the
evolution of equation of state (EOS) for dark energy is similar to quiessence,
and its current best-fit value is with the confidence
level .Comment: 9 pages, 5 figure
BESII Detector Simulation
A Monte Carlo program based on Geant3 has been developed for BESII detector
simulation. The organization of the program is outlined, and the digitization
procedure for simulating the response of various sub-detectors is described.
Comparisons with data show that the performance of the program is generally
satisfactory.Comment: 17 pages, 14 figures, uses elsart.cls, to be submitted to NIM
- …