Dispersion of hazardous nanoparticles on beaches around phosphogypsum factories

Anthropogenic occurring nanoparticles (NPs) have been one of the principal catalytic components of marine pollution throughout its history. The phosphogypsum (PG) factories present environmental risks and evident marine pollution in different parts of the world. Many of these factors continue to operate, however, some have already been abandoned by the private sector. The general objective of this manuscript is to analyze the real nanoparticles (NPs) present on a beach in southern Brazil to illustrate the need to create public policies and projects for environmental recovery. This work focused on real representative sampling of suspended sediments (SSs), and on a modern analytical procedure via advanced electron microscopes (field emission scanning electron microscope-FE-SEM and high resolution transmission electron microscope-HR-TEM coupled with an energy dispersive X-ray microanalysis system-EDS) to analyze NPs containing hazardous elements (HEs). The results presented in this work demonstrate who the size, morphology, among other physical-geochemical characteristics influence in the adsorption of HEs by the NPs and their respective agglomerates. This study is of great importance for carrying out the application of advanced techniques and methods to better understand the formation and transport of NPs on beaches, which allows assisting in the management of waste from plaster factories on a global scale

Air pollutants and their degradation of a historic building in the largest metropolitan area in latin america

Historic buildings that comprise the cultural heritage of humanity are in need of preservation on a worldwide scale in regard to degradation resultant from atmospheric pollutants. The Brazilian Public Market, located in the historic center of the mega city of Sao Paulo, is the object of this research, due to its representation of historical Brazilian architecture. The general objective of this manuscript is to analyze the influence of air pollutants on the degradation of the historic Sao Paulo Public Market in the city of Sao~ Paulo, Brazil. Methodologically, between May 2018 and April 2019, samples of sedimented dust were collected at five points on the side walls of the market’s historic structure, for the analysis of accumulated ultrafine particles (UFPs) and nanoparticles (NPs). A total of 20 samples of particulate matter were collected using self-made passive samplers (SMPSs). Using SMPSs, 12 months of accumulation and deposition were used to sample the atmospheric PM1. The results demonstrate the presence of dangerous elements such as: As, Cd, Cr, Pb, Zn. Note that EDS coupled with microscopy techniques, points out the risks to human health, due to the presence of these dangerous elements that accumulate in the building’s structure. The results show that 85% of the NPs sampled contained Pb, and 56% contained Pb and Ti, which are harmful to both historic buildings and human health. Air pollution enables the further deterioration of the Sao Paulo Public Market, which is in need of restoration

Temperature inversion symmetry in the Casimir effect with an antiperiodic boundary condition

We present explicitly another example of a temperature inversion symmetry in the Casimir effect for a nonsymmetric boundary condition. We also give an interpretation for our result.Comment: 4 page

Gravitational Wave Chirp Search: Economization of PN Matched Filter Bank via Cardinal Interpolation

The final inspiral phase in the evolution of a compact binary consisting of black holes and/or neutron stars is among the most probable events that a network of ground-based interferometric gravitational wave detectors is likely to observe. Gravitational radiation emitted during this phase will have to be dug out of noise by matched-filtering (correlating) the detector output with a bank of several $10^5$ templates, making the computational resources required quite demanding, though not formidable. We propose an interpolation method for evaluating the correlation between template waveforms and the detector output and show that the method is effective in substantially reducing the number of templates required. Indeed, the number of templates needed could be a factor $\sim 4$ smaller than required by the usual approach, when the minimal overlap between the template bank and an arbitrary signal (the so-called {\it minimal match}) is 0.97. The method is amenable to easy implementation, and the various detector projects might benefit by adopting it to reduce the computational costs of inspiraling neutron star and black hole binary search.Comment: scheduled for publicatin on Phys. Rev. D 6

Zeta function method and repulsive Casimir forces for an unusual pair of plates at finite temperature

We apply the generalized zeta function method to compute the Casimir energy and pressure between an unusual pair of parallel plates at finite temperature, namely: a perfectly conducting plate and an infinitely permeable one. The high and low temperature limits of these quantities are discussed; relationships between high and low temperature limits are estabkished by means of a modified version of the temperature inversion symmetry.Comment: latex file 9 pages, 3 figure

Cardamonin, a schistosomicidal chalcone from Piper aduncum L. (Piperaceae) that inhibits Schistosoma mansoni ATP diphosphohydrolase

AbstractBackground: Schistosomiasis is one of the world's major public health problems, and praziquantel (PZQ) is the only available drug to treat this neglected disease with an urgent demand for new drugs. Recent studies indicated that extracts from Piper aduncum L. (Piperaceae) are active against adult worms of Schistosoma mansoni, the major etiological agent of human schistosomiasis.Purpose: We investigated the in vitro schistosomicidal activity of cardamonin, a chalcone isolated from the crude extract of P. aduncum. Also, this present work describes, for the first time, the S. mansoni ATP diphosphohydrolase inhibitory activity of cardamonin, as well as, its molecular docking with S. mansoni ATPDase1, in order to investigate its mode of inhibition.Methods: In vitro schistosomicidal assays and confocal laser scanning microscopy were used to evaluate the effects of cardamonin on adult schistosomes. Cell viability was measured by MTT assay, and the S. mansoni ATPase activity was determined spectrophotometrically. Identification of the cardamonin binding site and its interactions on S. mansoni ATPDase1 were made by molecular docking experiments.Results: A bioguided fractionation of the crude extract of P. aduncum was carried out, leading to identification of cardamonin as the active compound, along with pinocembrin and uvangoletin. Cardamonin (25, 50, and 100 µM) caused 100% mortality, tegumental alterations, and reduction of oviposition and motor activity of all adult worms of S. mansoni, without affecting mammalian cells. Confocal laser scanning microscopy showed tegumental morphological alterations and changes on the numbers of tubercles of S. mansoni worms in a dose-dependent manner. Cardamonin also inhibited S. mansoni ATP diphosphohydrolase (IC50 of 23.54 µM). Molecular docking studies revealed that cardamonin interacts with the Nucleotide-Binding of SmATPDase 1. The nature of SmATPDase 1–cardamonin interactions is mainly hydrophobic and hydrogen bonding.Conclusion: This report provides evidence for the in vitro schistosomicidal activity of cardamonin and demonstrated, for the first time, that this chalcone is highly effective in inhibiting S. mansoni ATP diphosphohydrolase, opening the route to further studies of chalcones as prototypes for new S. mansoni ATP diphosphohydrolase inhibitors

Quantum radiation pressure on a moving mirror at finite temperature

We compute the radiation pressure force on a moving mirror, in the nonrelativistic approximation, assuming the field to be at temperature $T.$ At high temperature, the force has a dissipative component proportional to the mirror velocity, which results from Doppler shift of the reflected thermal photons. In the case of a scalar field, the force has also a dispersive component associated to a mass correction. In the electromagnetic case, the separate contributions to the mass correction from the two polarizations cancel. We also derive explicit results in the low temperature regime, and present numerical results for the general case. As an application, we compute the dissipation and decoherence rates for a mirror in a harmonic potential well.Comment: Figure 3 replaced, changes mainly in Sections IV and V, new appendix introduced. To appear in Physical Review

Portuguese Ministers, 1851-1999: Social Background and Paths to Power

Disponível em: http://193.136.113.6/Opac/Pages/Search/Results.aspx?SearchText=UID=bb8aa8d5-c6b6-466a-81bb-fe8a67693cee&DataBase=10449_UNLFCSHThis paper provides an empirical analysis of the impact of regime changes in the composition and patterns of recruitment of the Portuguese ministerial elite throughout the last 150 years. The ‘out-of-type’, violent nature of most regime transformations accounts for the purges in and the extensive replacements of the political personnel, namely of the uppermost officeholders. In the case of Cabinet members, such discontinuities did not imply, however, radical changes in their social profile. Although there were some significant variations, a series of salient characteristics have persisted over time. The typical Portuguese minister is a male in his midforties, of middle-class origin and predominantly urban-born, highly educated and with a state servant background. The two main occupational contingents have been university professors - except for the First Republic (1910-26) - and the military, the latter having only recently been eclipsed with the consolidation of contemporary democracy. As regards career pathways, the most striking feature is the secular trend for the declining role of parliamentary experience, which the democratic regime did not clearly reverse. In this period, a technocratic background rather than political experience has been indeed the privileged credential for a significant proportion of minister