3,865 research outputs found
Pairing interactions and pairing mechanism in high temperature copper oxide superconductors
The polaron binding energy E_{p} in undoped parent cuprates has been
determined to be about 1.0 eV from the unconventional oxygen-isotope effect on
the antiferromagnetic ordering temperature. The deduced value of E_{p} is in
quantitative agreement with that estimated from independent optical data and
that estimated theoretically from the measured dielectric constants. The
substantial oxygen-isotope effect on the in-plane supercarrier mass observed in
optimally doped cuprates suggests that polarons are bound into the Cooper
pairs. We also identify the phonon modes that are strongly coupled to
conduction electrons from the angle-resolved photoemission spectroscopy,
tunneling spectra, and optical data. We consistently show that there is a very
strong electron-phonon coupling feature at a phonon energy of about 20 meV
along the antinodal direction and that this coupling becomes weaker towards the
diagonal direction. We further show that high-temperature superconductivity in
cuprates is caused by strong electron-phonon coupling, polaronic effect, and
significant coupling with 2 eV Cu-O charge transfer fluctuation.Comment: 11 pages, 7 figure
Molecular Dynamics Simulation of Solvent-Polymer Interdiffusion. I. Fickian diffusion
The interdiffusion of a solvent into a polymer melt has been studied using
large scale molecular dynamics and Monte Carlo simulation techniques. The
solvent concentration profile and weight gain by the polymer have been measured
as a function of time. The weight gain is found to scale as t^{1/2}, which is
expected for Fickian type of diffusion. The concentration profiles are fit very
well assuming Fick's second law with a constant diffusivity. The diffusivity
found from fitting Fick's second law is found to be independent of time and
equal to the self diffusion constant in the dilute solvent limit. We separately
calculated the diffusivity as a function of concentration using the Darken
equation and found that the diffusivity is essentially constant for the
concentration range relevant for interdiffusion.Comment: 17 pages and 7 figure
Temperature Dependence of Low-Lying Electronic Excitations of LaMnO_3
We report on the optical properties of undoped single crystal LaMnO_3, the
parent compound of the colossal magneto-resistive manganites. Near-Normal
incidence reflectance measurements are reported in the frequency range of
20-50,000 cm-1 and in the temperature range 10-300 K. The optical conductivity,
s_1(w), is derived by performing a Kramers-Kronig analysis of the reflectance
data. The far-infrared spectrum of s_1(w) displays the infrared active optical
phonons. We observe a shift of several of the phonon to high frequencies as the
temperature is lowered through the Neel temperature of the sample (T_N = 137
K). The high-frequency s_1(w) is characterized by the onset of absorption near
1.5 eV. This energy has been identified as the threshold for optical
transitions across the Jahn-Teller split e_g levels. The spectral weight of
this feature increases in the low-temperature state. This implies a transfer of
spectral weight from the UV to the visible associated with the paramagnetic to
antiferromagnetic state. We discuss the results in terms of the double exchange
processes that affect the optical processes in this magnetic material.Comment: 7 pages, 5 figure
El perfil de clima escolar: estudio transcultural de la validez de una batería de cuestionarios para evaluar el clima escolar
This paper studies the validity of the School Climate Battery of Questionnaires for Secondary and High School Teachers (SCBQSHST). The battery includes five questionnaires: Quality of Leadership, Quality of Teachers' Support, School Motivational Orientation, Quality of Students' Attitude, and Quality of Parental Support. A total of 178 teachers from Costa Rica were compared with 343 Spanish teachers. Confirmatory factor analyses showed that the questionnaires allow assessing teachers' perceptions of the different dimensions of school climate in a valid and reliable way in both Spain and Costa Rica. Differences in the perception of Spanish and Costa Rican teachers about school climate shown by multigroup confirmatory factor analyses are discussed as well as theoretical and practical implications.Este artículo estudia la validez de la Batería de cuestionarios sobre clima escolar para profesores de Secundaria y
Bachillerato (BQCE-SB). La batería incluye cinco cuestionarios: calidad de liderazgo, calidad de apoyo docente, orientación
motivacional del centro, calidad de las actitudes de los estudiantes y calidad del apoyo de los padres. Un total de 178
docentes de Costa Rica se compararon con 343 docentes españoles. Los análisis factoriales confirmatorios mostraron que
los cuestionarios permiten evaluar de manera válida y confiable las percepciones de los docentes sobre las diferentes
dimensiones del clima escolar, tanto en España como en Costa Rica. Se discuten las diferencias en la percepción de los
docentes españoles y costarricenses sobre el clima escolar que muestran los análisis factoriales confirmatorios multigrupo, así como sus implicaciones teóricas y práctica
Photometry using the Infrared Array Camera on the Spitzer Space Telescope
We present several corrections for point source photometry to be applied to
data from the Infrared Array Camera (IRAC) on the Spitzer Space Telescope.
These corrections are necessary because of characteristics of the IRAC arrays
and optics and the way the instrument is calibrated in-flight. When these
corrections are applied, it is possible to achieve a ~2% relative photometric
accuracy for sources of adequate signal to noise in an IRAC image.Comment: 16 pages, 13 figures. Accepted for publication in the Publications of
the Astronomical Society of the Pacifi
The in-plane electrodynamics of the superconductivity in Bi2Sr2CaCu2O8+d: energy scales and spectral weight distribution
The in-plane infrared and visible (3 meV-3 eV) reflectivity of
Bi2Sr2CaCu2O8+d (Bi-2212) thin films is measured between 300 K and 10 K for
different doping levels with unprecedented accuracy. The optical conductivity
is derived through an accurate fitting procedure. We study the transfer of
spectral weight from finite energy into the superfluid as the system becomes
superconducting. In the over-doped regime, the superfluid develops at the
expense of states lying below 60 meV, a conventional energy of the order of a
few times the superconducting gap. In the underdoped regime, spectral weight is
removed from up to 2 eV, far beyond any conventional scale. The intraband
spectral weight change between the normal and superconducting state, if
analyzed in terms of a change of kinetic energy is ~1 meV. Compared to the
condensation energy, this figure addresses the issue of a kinetic energy driven
mechanism.Comment: 13 pages with 9 figures include
Optical Studies of a Layered Manganite La_{1.2}Sr_{1.8}Mn_2O_7 : Polaron Correlation Effect
Optical conductivity spectra of a cleaved ab-plane of a
La_{1.2}Sr_{1.8}Mn_2O_7 single crystal exhibit a small polaron absorption band
in the mid-infrared region at overall temperatures. With decreasing temperature
(T) to Curie temperature (T_C), the center frequency of the small polaron band
moves to a higher frequency, resulting in a gap-like feature, and that it
collapses to a lower frequency below T_C. Interestingly, with decreasing T, the
stretching phonon mode hardens above T_C and softens below T_C. These
concurring changes of lattice and electronic structure indicate that short
range polaron correlation exist above T_C but disappear with a magnetic
ordering.Comment: 4 pages including 5 figures. submitted to Phys. Rev.
Metal-induced malformations in early Palaeozoic plankton are harbingers of mass extinction
Glacial episodes have been linked to Ordovician–Silurian extinction events, but cooling itself may not be solely responsible for these extinctions. Teratological (malformed) assemblages of fossil plankton that correlate precisely with the extinction events can help identify alternate drivers of extinction. Here we show that metal poisoning may have caused these aberrant morphologies during a late Silurian (Pridoli) event. Malformations coincide with a dramatic increase of metals (Fe, Mo, Pb, Mn and As) in the fossils and their host rocks. Metallic toxins are known to cause a teratological response in modern organisms, which is now routinely used as a proxy to assess oceanic metal contamination. Similarly, our study identifies metal-induced teratology as a deep-time, palaeobiological monitor of palaeo-ocean chemistry. The redox-sensitive character of enriched metals supports emerging ‘oceanic anoxic event’ models. Our data suggest that spreading anoxia and redox cycling of harmful metals was a contributing kill mechanism during these devastating Ordovician–Silurian palaeobiological events
Initial Studies of the Bidirectional Reflectance Distribution Function of Multi-Walled Carbon Nanotube Structures for Stray Light Control Applications
The presentation examines the application of low reflectance surfaces in optical instruments, multi-walled carbon nanotubes (MWCNTs), research objects, MWCNT samples, measurement of 8 deg. directional/hemispherical reflectance, measurement of bidirectional reflectance distribution function (BRDF), and what is current the "blackest ever black"
Charge Ordering Fluctuation and Optical Pseudogap in LaCaMnO
Optical spectroscopy was used to investigate the optical gap (2) due
to charge ordering (CO) and related pseudogap developments with x and
temperature (T) in LaCaMnO (0.48 <= x <= 0.67).
Surprisingly, we found 2/k_{B}T_{CO} is as large as 30 for x ~0.5, and
decreases rapidly with increasing x. Simultaneously, the optical pseudogap,
possibly starting from T^* far above T_{CO} becomes drastically enhanced near
x=0.5, producing non-BCS T-dependence of 2 with the large magnitude
far above T_{CO}, and systematic increase of T^* for x~0.5. These results
unequivocally indicate systematically-enhanced CO correlation when x approaches
0.5 even though T_{CO} decreases.Comment: 5 pages, 4 figures embedded, submitted to Phys. Rev. Let
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