14,499 research outputs found
Long-term evolution of highly alkaline steel slag drainage waters
© 2015, Springer International Publishing Switzerland. The disposal of slag generated by the steel industry can have negative consequences upon the surrounding aquatic environment by the generation of high pH waters, leaching of potentially problematic trace metals, and rapid rates of calcite precipitation which smother benthic habitats. A 36-year dataset was collated from the long-term ambient monitoring of physicochemical parameters and elemental concentrations of samples from two steel slag leachate-affected watercourses in northern England. Waters were typified by elevated pH ( > 10), high alkalinity, and were rich in dissolved metals (e.g. calcium (Ca), aluminium (Al), and zinc (Zn)). Long-term trend analysis was performed upon pH, alkalinity, and Ca concentration which, in addition to Ca flux calculations, were used to highlight the longevity of pollution arising as a result of the dumping and subsequent leaching of steel slags. Declines in calcium and alkalinity have been modest over the monitoring period and not accompanied by significant declines in water pH. If the monotonic trends of decline in alkalinity and calcium continue in the largest of the receiving streams, it will be in the region of 50–80 years before calcite precipitation would be expected to be close to baseline levels, where ecological impacts would be negligible
C-Cl Bond Fission, Hcl Elimination, And Secondary Radical Decomposition In The 193 Nm Photodissociation Of Allyl Chloride
The primary photodissociation dynamics of allyl chloride upon excitation at 193 nm is investigated in a crossed laser-molecular beam scattering apparatus. Tunable vacuum ultraviolet (VUV) photoionization of the products provides a unique ability to learn about the secondary reaction products of the nascent photoproducts formed. The data show evidence for four significant primary reaction channels: a previously unidentified low kinetic energy C-Cl bond fission channel producing unstable allyl radicals, an excited state C-Cl bond fission channel producing Cl atoms with high translational energy, an HCl elimination pathway releasing significant energy to product translation to HCl and its momentum-matched mass 40 partner, and an HCl elimination channel producing low kinetic energy HCl products and predominantly unstable mass 40 products. The measured branching of these primary reaction channels of [all C-Cl] : [fast C-Cl] : [slow C-Cl] : [fast HCl] : [slow HCl] : [all HCl] is 1.00: 0.971: 0.029: 0.291: 0.167: 0.458 (where fast refers to the high recoil kinetic energy channels). The high internal energy allyl radicals formed in the slow C-Cl fission pathway of allyl chloride further dissociate/isomerize, as do the unstable mass 40 products formed in the HCl elimination pathways, and these products are investigated. Photoionization efficiency (PIE) curves of the HCl product suggest that a three-centered elimination mechanism contributes significantly to an observed HCl elimination reaction. (C) 2002 American Institute of Physics
Variability of stellar granulation and convective blueshift with spectral type and magnetic activity. I. K and G main sequence stars
In solar-type stars, the attenuation of convective blueshift by stellar
magnetic activity dominates the RV variations over the low amplitude signal
induced by low mass planets. Models of stars that differ from the Sun will
require a good knowledge of the attenuation of the convective blueshift to
estimate its impact on the variations. It is therefore crucial to precisely
determine not only the amplitude of the convective blueshift for different
types of stars, but also the dependence of this convective blueshift on
magnetic activity, as these are key factors in our model producing the RV. We
studied a sample of main sequence stars with spectral types from G0 to K2 and
focused on their temporally averaged properties: the activity level and a
criterion allowing to characterise the amplitude of the convective blueshift.
We find the differential velocity shifts of spectral lines due to convection to
depend on the spectral type, the wavelength (this dependence is correlated with
the Teff and activity level), and on the activity level. This allows us to
quantify the dependence of granulation properties on magnetic activity for
stars other than the Sun. The attenuation factor of the convective blueshift
appears to be constant over the considered range of spectral types. We derive a
convective blueshift which decreases towards lower temperatures, with a trend
in close agreement with models for Teff lower than 5800 K, but with a
significantly larger global amplitude. We finally compare the observed RV
variation amplitudes with those that could be derived from our convective
blueshift using a simple law and find a general agreement on the amplitude. Our
results are consistent with previous results and provide, for the first time,
an estimation of the convective blueshift as a function of Teff, magnetic
activity, and wavelength, over a large sample of G and K main sequence stars
Electronic phase diagrams of carriers in self-assembled InAs/GaAs quantum dots: violation of Hund's rule and the Aufbau principle for holes
We study the orbital and spin configurations of up to six electrons or holes
charged into self-assembled InAs/GaAs quantum dots via single-particle
pseudopotential and many-particle configuration interaction method. We find
that while the charging of {\it electrons} follows both Hund's rule and the
Aufbau principle, the charging of {\it holes} follows a non-trivial charging
pattern which violates both the Aufbau principle and Hund's rule, and is robust
against the details of the quantum dot size. The predicted hole charging
sequence offers a new interpretation of recent charging experiments
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Fractal scattering dynamics of the three-dimensional HOCl molecule
We compare the 2D and 3D classical fractal scattering dynamics of Cl and HO for energies just above dissociation of the HOCl molecule, using a realistic potential energy surface for the HOCl molecule and techniques developed to analyze 3D chaotic scattering processes. For parameter regimes where the HO dimer initially has small vibrational energy, only small intervals of initial conditions show fractal scattering behavior and the scattering process is well described by a 2D model. For parameter regimes where the HO dimer initially has large vibrational energy, the scattering process is fully 3D and is dominated by fractal behavior.Robert A. Welch Foundation F-1051CONACyT 79988DGAPA IN110110Physic
Photoionisation and Heating of a Supernova Driven, Turbulent, Interstellar Medium
The Diffuse Ionised Gas (DIG) in galaxies traces photoionisation feedback
from massive stars. Through three dimensional photoionisation simulations, we
study the propagation of ionising photons, photoionisation heating and the
resulting distribution of ionised and neutral gas within snapshots of
magnetohydrodynamic simulations of a supernova driven turbulent interstellar
medium. We also investigate the impact of non-photoionisation heating on
observed optical emission line ratios. Inclusion of a heating term which scales
less steeply with electron density than photoionisation is required to produce
diagnostic emission line ratios similar to those observed with the Wisconsin
H{\alpha} Mapper. Once such heating terms have been included, we are also able
to produce temperatures similar to those inferred from observations of the DIG,
with temperatures increasing to above 15000 K at heights |z| > 1 kpc. We find
that ionising photons travel through low density regions close to the midplane
of the simulations, while travelling through diffuse low density regions at
large heights. The majority of photons travel small distances (< 100pc);
however some travel kiloparsecs and ionise the DIG.Comment: 10 pages, 13 figures, accepted to MNRA
Modeling Human Ad Hoc Coordination
Whether in groups of humans or groups of computer agents, collaboration is
most effective between individuals who have the ability to coordinate on a
joint strategy for collective action. However, in general a rational actor will
only intend to coordinate if that actor believes the other group members have
the same intention. This circular dependence makes rational coordination
difficult in uncertain environments if communication between actors is
unreliable and no prior agreements have been made. An important normative
question with regard to coordination in these ad hoc settings is therefore how
one can come to believe that other actors will coordinate, and with regard to
systems involving humans, an important empirical question is how humans arrive
at these expectations. We introduce an exact algorithm for computing the
infinitely recursive hierarchy of graded beliefs required for rational
coordination in uncertain environments, and we introduce a novel mechanism for
multiagent coordination that uses it. Our algorithm is valid in any environment
with a finite state space, and extensions to certain countably infinite state
spaces are likely possible. We test our mechanism for multiagent coordination
as a model for human decisions in a simple coordination game using existing
experimental data. We then explore via simulations whether modeling humans in
this way may improve human-agent collaboration.Comment: AAAI 201
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