Electrolyte management in porous battery components. Static measurements

The interaction between the porous hydrogen and nickel electrodes and microporous separator with respect to electrolyte management in nickel/hydrogen cells has been investigated. The distribution of electrolyte among the components has been measured and correlated with the pore size distributions, total void volume, and resistance of a variety of electrodes and separators. Calculations are used to show the effects of systematically varying these properties

Pore size engineering applied to the design of separators for nickel-hydrogen cells and batteries

Pore size engineering in starved alkaline multiplate cells involves adopting techniques to widen the volume tolerance of individual cells. Separators with appropriate pore size distributions and wettability characteristics (capillary pressure considerations) to have wider volume tolerances and an ability to resist dimensional changes in the electrodes were designed. The separators studied for potential use in nickel-hydrogen cells consist of polymeric membranes as well as inorganic microporous mats. In addition to standard measurements, the resistance and distribution of electrolyte as a function of total cell electrolyte content were determined. New composite separators consisting of fibers, particles and/or binders deposited on Zircar cloth were developed in order to engineer the proper capillary pressure characteristics in the separator. These asymmetric separators were prepared from a variety of fibers, particles and binders

Development of a lightweight nickel electrode

Nickel electrodes made using lightweight plastic plaque are about half the weight of electrodes made from state of the art sintered nickel plaque. This weight reduction would result in a significant improvement in the energy density of batteries using nickel electrodes (nickel hydrogen, nickel cadmium and nickel zinc). These lightweight electrodes are suitably conductive and yield comparable capacities (as high as 0.25 AH/gm (0.048 AH/sq cm)) after formation. These lightweight electrodes also show excellent discharge performance at high rates

Recent advances in Ni-H2 technology at NASA Lewis Research Center

The NASA Lewis Research Center has concentrated its efforts on advancing the Ni-H2 system technology for low Earth orbit applications. Component technology as well as the design principles were studied in an effort to understand the system behavior and failure mechanisms in order to increase performance and extend cycle life. The design principles were previously addressed. The component development is discussed, in particular the separator and nickel electrode and how these efforts will advance the Ni-H2 system technology

Intensity enhancement of O VI ultraviolet emission lines in solar spectra due to opacity

Opacity is a property of many plasmas, and it is normally expected that if an emission line in a plasma becomes optically thick, its intensity ratio to that of another transition that remains optically thin should decrease. However, radiative transfer calculations undertaken both by ourselves and others predict that under certain conditions the intensity ratio of an optically thick to thin line can show an increase over the optically thin value, indicating an enhancement in the former. These conditions include the geometry of the emitting plasma and its orientation to the observer. A similar effect can take place between lines of differing optical depth. Previous observational studies have focused on stellar point sources, and here we investigate the spatially-resolved solar atmosphere using measurements of the I(1032 A)/I(1038 A) intensity ratio of O VI in several regions obtained with the Solar Ultraviolet Measurements of Emitted Radiation (SUMER) instrument on board the Solar and Heliospheric Observatory (SoHO) satellite. We find several I(1032 A)/I(1038 A) ratios observed on the disk to be significantly larger than the optically thin value of 2.0, providing the first detection (to our knowledge) of intensity enhancement in the ratio arising from opacity effects in the solar atmosphere. Agreement between observation and theory is excellent, and confirms that the O VI emission originates from a slab-like geometry in the solar atmosphere, rather than from cylindrical structures.Comment: 17 pages, 4 figures, ApJ Letters, in pres

High-velocity feature of the class I methanol maser in G309.38-0.13

The Australia Telescope Compact Array (ATCA) has been used to map class I methanol masers at 36 and 44 GHz in G309.38-0.13. Maser spots are found at nine locations in an area of 50''x30'', with both transitions reliably detected at only two locations. The brightest spot is associated with shocked gas traced by 4.5 micron emission. The data allowed us to make a serendipitous discovery of a high-velocity 36-GHz spectral feature, which is blue-shifted by about 30 km/s from the peak velocity at this frequency, but spatially located close to (within a few arcseconds of) the brightest maser spot. We interpret this as indicating an outflow parallel to the line of sight. Such a high velocity spread of maser features, which has not been previously reported in the class I methanol masers associated with a single molecular cloud, suggests that the outflow most likely interacts with a moving parcel of gas.Comment: 6 pages, 2 figures, accepted by MNRAS Letter

Study of a Large NaI(Tl) Crystal

Using a narrow band positron beam, the response of a large high-resolution NaI(Tl) crystal to an incident positron beam was measured. It was found that nuclear interactions cause the appearance of additional peaks in the low energy tail of the deposited energy spectrum

Electrostatics of Gapped and Finite Surface Electrodes

We present approximate methods for calculating the three-dimensional electric potentials of finite surface electrodes including gaps between electrodes, and estimate the effects of finite electrode thickness and an underlying dielectric substrate. As an example we optimize a radio-frequency surface-electrode ring ion trap, and find that each of these factors reduces the trapping secular frequencies by less than 5% in realistic situations. This small magnitude validates the usual assumption of neglecting the influences of gaps between electrodes and finite electrode extent.Comment: 9 pages, 9 figures (minor changes

United Kingdom: Citizenship education in the United Kingdom: comparing England, Northern Ireland, Scotland and Wales

Purpose: In this country case study the authors undertake a comparative analysis of citizenship education across the four nations of the UK. The curriculum and contexts in England, Scotland, Wales and Northern Ireland are first described. Then the article considers how each national example engages with fundamental expectations of citizenship education, specifically in relation to questions of citizenship status and the relationship between citizens and the state; political identity; and active citizenship processes. Approach: Drawing on the authors’ collective experience and insights into policy and practice in each nation, we started with a ‘generative conversation’ to identify key issues for inclusion in this case study. Findings: The article unearths a variety of constraints and problems, and situates these in a broader policyscape in which policy accretion and policy approximation generate a permissive culture, which has undermined the promise of citizenship education as an entitlement for all young people