254 research outputs found
Using network science to analyze football passing networks: dynamics, space, time and the multilayer nature of the game
From the diversity of applications of Network Science, in this Opinion Paper
we are concerned about its potential to analyze one of the most extended group
sports: Football (soccer in U.S. terminology). As we will see, Network Science
allows addressing different aspects of the team organization and performance
not captured by classical analyses based on the performance of individual
players. The reason behind relies on the complex nature of the game, which,
paraphrasing the foundational paradigm of complexity sciences "can not be
analyzed by looking at its components (i.e., players) individually but, on the
contrary, considering the system as a whole" or, in the classical words of
after-match interviews "it's not just me, it's the team".Comment: 7 pages, 1 figur
Xps Study of the Oxidation State of Uranium Dioxide
In this article we report an investigation of the oxidation state of uranium dioxide using X-Ray Photoelectron Spectroscopy, and by comparing to results obtained in previous studies. We find that uranium dioxide in powder appears to share its six valence electrons with the oxygen atoms to form crystalline UO3
Using Network Science to Analyse Football Passing Networks: Dynamics, Space, Time, and the Multilayer Nature of the Game
Synthesis and electronic properties of donor-linked fullerenes towards photochemical molecular devices
Impact of chorioamnionitis on exhaled nitric oxide and endotracheal aspirate levels of nitrites-nitrates and interleukin-8 in mechanically ventilated preterm neonates.
OBJECTIVES: To assess the influence of maternal chorioamnionitis on early exhaled nitric oxide (NO) and levels of nitrites-nitrates and interleukin (IL)-8 in endotracheal aspirate fluid in mechanically ventilated preterm neonates. STUDY DESIGN: Cross-sectional study. PATIENT-SUBJECT SELECTION: Between September 2007 and August 2009, 54 mechanically ventilated preterm neonates were included. Patients were divided into two groups according to the presence or absence of maternal chorioamnionitis, and those without chorioamnionitis (controls) were further stratified into two subgroups by birth weight < or â„ 2,000 g. METHODOLOGY: The ventilator used was a Babylog 8000. The NO level assessed was the plateau value given by the software of the Sievers NOA apparatus. Collection of endotracheal aspirate fluid samples was performed coinciding with routine aspirations and using the dry technique. RESULTS: The two groups of control neonates showed statistically significant differences in exhaled NO expressed as nl/min and normalized exhaled NO expressed as either nl/min or nl/min/kg, so they are not homogeneous and cannot be used in clinical practice. Serum C-reactive protein and endotracheal aspirate levels of nitrites-nitrates were significantly higher in the chorioamnionitis group than in controls (3.6 vs. 1.07 ”mol/L; P = 0.035). Nitrites-nitrates levels were positively correlated with exhaled NO in ppb (Ï = 0.367; P = 0.006). Minute exhaled endogenous NO was significantly higher in the chorioamnionitis group (0.48 vs. 0.27 nl/min/kg; P = 0.021). CONCLUSIONS: In mechanically ventilated preterm infants weighing <2,000 g, maternal chorioamnionitis was associated with an increase of early exhaled NO (nl/min/kg) and serum levels of C-reactive protein and levels of nitrites-nitrates in endotracheal aspirate fluid
The importance of poetry, hip-hop, and philosophy for an enlisted aviator in the USAF (2000â2004) flying in support of Operation Enduring Freedom and Operation Iraqi Freedom
Fingerprints of Through-Bond and Through-Space Exciton and Charge Ï-Electron Delocalization in Linearly Extended [2.2]Paracyclophanes
New stilbenoid and
thiophenic compounds terminally functionalized
with donorâdonor, acceptorâacceptor, or donorâacceptor
moieties and possessing a central [2.2]Âparacyclophane unit have been
prepared, and their properties interpreted in terms of through-bond
and through space Ï-electron delocalization (i.e., Ï-conjugations).
Based on photophysical data, their excited-state properties have been
described with a focus on the participation of the central [2.2]Âparacyclophane
in competition with through-bond conjugation in the side arms. To
this end, two-photon and one-photon absorption and emission spectroscopy,
as a function of temperature, solvent polarity, and pressure in the
solid state have been recorded. Furthermore, charge delocalization
through the [2.2]Âparacyclophane in the neutral state and in the oxidized
species (radical cations, dications and radical trications) has been
investigated, allowing the elucidation of the vibrational Raman fingerprint
of through-space charge delocalization. Thus, a complementary approach
to both âintermolecularâ excitation and charge delocalizations
in [2.2]Âparacyclophane molecules is shown which can serve as models
of charge and exciton migration in organic semiconductors
Diastereoselective Synthesis of C60/Steroid Conjugates
The design and synthesis of fullereneâsteroid hybrids by using Pratoâs protocol has afforded new fullerene derivatives endowed with epiandrosterone, an important naturally occurring steroid hormone. Since the formation of the pyrrolidine ring resulting from the 1,3-dipolar cyloaddition reaction takes place with generation of a new stereogenic center on the C2 of the five-membered ring, the reaction proceeds with formation of a diastereomeric mixture [compounds 6 and 7 in 70:30 ratio, 8 and 9 in 26:74 ratio (HPLC)] in which the formation of the major diasteroisomers 6 and 9 is consistent with an electrophilic attack of [60]fullerene on the Re face of the azomethine ylide directed by the steroidic unit. The chiroptical properties of these conjugates reveal typical Cotton effects in CD spectra that have been used to assign the absolute configuration of the new fulleropyrrolidines. The electrochemical study of the new compounds reveals the presence of four quasi-reversible reduction waves which are cathodically shifted in comparison with the parent C60, thus ascertaining the proposed structures.Financial support by the Ministerio de Ciencia e InnovacioÌn (MINECO) of Spain (CTQ2011-24652, CTQ2011-27253, PIB2010JP-00196, and CSD2007-00010 projects) and CAM (Madrisolar-2) is acknowledged; A.R. thanks UCM for financial support; M.S. is indebted to Programa del Grupo Santander 2012
Recent advances and perspectives on starch nanocomposites for packaging applications
Starch nanocomposites are popular and abundant materials in packaging sectors. The aim of this work is to review some of the most popular starch nanocomposite systems that have been used nowadays. Due to a wide range of applicable reinforcements, nanocomposite systems are investigated based on nanofiller type such as nanoclays, polysaccharides and carbonaceous nanofillers. Furthermore, the structures of starch and material preparation methods for their nanocomposites are also mentioned in this review. It is clearly presented that mechanical, thermal and barrier properties of plasticised starch can be improved with well-dispersed nanofillers in starch nanocomposites
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