10,568 research outputs found
Timescales of carbon turnover in soils with mixed crystalline mineralogies
Organic matter–mineral associations stabilize much of the carbon
(C) stored globally in soils. Metastable short-range-order (SRO) minerals
such as allophane and ferrihydrite provide one mechanism for long-term
stabilization of organic matter in young soil. However, in soils with few SRO
minerals and a predominance of crystalline aluminosilicate or Fe (and
Al) oxyhydroxide, C turnover should
be governed by chemisorption with those minerals. Here, we correlate mineral
composition from soils containing small amounts of SRO minerals with mean
turnover time (TT) of C estimated from radiocarbon (<sup>14</sup>C) in bulk soil,
free light fraction and mineral-associated organic matter. We varied the
mineral amount and composition by sampling ancient soils formed on different
lithologies in arid to subhumid climates in Kruger National Park (KNP), South
Africa. Mineral contents in bulk soils were assessed using chemical
extractions to quantify Fe oxyhydroxides and SRO minerals. Because of our
interest in the role of silicate clay mineralogy, particularly smectite
(2 : 1) and kaolinite (1 : 1), we separately quantified the mineralogy of
the clay-sized fraction using X-ray diffraction (XRD) and measured <sup>14</sup>C
on the same fraction.
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Density separation demonstrated that mineral associated C accounted for
40–70 % of bulk soil organic C in A and B1 horizons for granite,
nephelinite and arid-zone gabbro soils, and > 80 % in other
soils. Organic matter strongly associated with the isolated clay-sized
fraction represented only 9–47 % of the bulk soil C. The mean TT of C
strongly associated with the clay-sized fraction increased with the amount of
smectite (2 : 1 clays); in samples with > 40 % smectite it
averaged 1020 ± 460 years. The C not strongly associated with
clay-sized minerals, including a combination of low-density C, the C
associated with minerals of sizes between 2 µm and 2 cm (including
Fe oxyhydroxides as coatings), and C removed from clay-sized material by
2 % hydrogen peroxide had TTs averaging 190 ± 190 years in surface
horizons. Summed over the bulk soil profile, we found that smectite content
correlated with the mean TT of bulk soil C across varied lithologies. The SRO
mineral content in KNP soils was generally very low, except for the soils
developed on gabbros under more humid climate that also had very high Fe and
C contents with a surprisingly short, mean C TTs. In younger landscapes, SRO
minerals are metastable and sequester C for long timescales. We hypothesize
that in the KNP, SRO minerals represent a transient stage of mineral
evolution and therefore lock up C for a shorter time.
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Overall, we found crystalline Fe-oxyhydroxides (determined as the difference
between Fe in dithionate citrate and oxalate extractions) to be the strongest
predictor for soil C content, while the mean TT of soil C was best predicted
from the amount of smectite, which was also related to more easily measured
bulk properties such as cation exchange capacity or pH. Combined with
previous research on C turnover times in 2 : 1 vs. 1 : 1 clays, our
results hold promise for predicting C inventory and persistence based on
intrinsic timescales of specific carbon–mineral
interactions
The Surface of 2003 EL_(61) in the Near-Infrared
We report the detection of crystalline water ice on the surface of 2003 EL_(61). Reflectance spectra were collected from the Gemini North telescope in the 1.0 to 2.4 μm wavelength range and from the Keck telescope across the 1.4-2.4 μm wavelength range. The signature of crystalline water ice is obvious in all data collected. Like the surfaces of many outer solar system bodies, the surface of 2003 EL_(61) is rich in crystalline water ice, which is energetically less favored than amorphous water ice at low temperatures, suggesting that resurfacing processes may be taking place. The near-infrared color of the object is much bluer than a pure water ice model. Adding a near-infrared blue component such as hydrogen cyanide or phyllosilicate clays improves the fit considerably, with hydrogen cyanide providing the greatest improvement. The addition of hydrated tholins and bitumens also improves the fit, but is inconsistent with the neutral V - J reflectance of 2003 EL_(61). A small decrease in reflectance beyond 2.3 μm may be attributable to cyanide salts. Overall, the reflected light from 2003 EL_(61) is best fit by a model of 2/3-4/5 pure crystalline water ice and 1/3-1/5 near-infrared blue component such as hydrogen cyanide or kaolinite. The surface of 2003 EL_(61) is unlikely to be covered by significant amounts of dark material such as carbon black, as our pure ice models reproduce published albedo estimates derived from the spin state of 2003 EL_(61)
Liquid rocket performance computer model with distributed energy release Interim final report, 15 Aug. 1969 - 15 Aug. 1970
Liquid propellant rocket engine performance computer program with distributed energy releas
Near Infrared Surface Properties of the Two Intrinsically Brightest Minor Planets (90377) Sedna and (90482) Orcus
We present low resolution K band spectra taken at the Gemini 8 meter
telescope of (90377) Sedna and (90482) Orcus (provisional designations 2003
VB12 and 2004 DW, respectively), currently the two minor planets with the
greatest absolute magnitudes (i.e. the two most reflective minor planets). We
place crude limits on the surface composition of these two bodies using a Hapke
model for a wide variety of assumed albedos. The unusual minor planet (90377)
Sedna was discovered on November 14, 2003 UT at roughly 90 AU with 1.6 times
the heliocentric distance and perihelion distance of any other bound minor
planet. It is the first solar system object discovered between the Kuiper Belt
and the Oort Cloud, and may represent a transition population between the two.
The reflectance spectrum of (90377) Sedna appears largely featureless at the
current signal-to-noise ratio, suggesting a surface likely to be highly
processed by cosmic rays. For large grain models (100 micron to 1 cm) we find
that (90377) Sedna must have less than 70% surface fraction of water ice and
less than 60% surface fraction of methane ice to 3 sigma confidence. Minor
planet (90482) Orcus shows strong water ice absorption corresponding to less
than 50% surface fraction for grain models 25 micron and larger. Orcus cannot
have more than 30% of its surface covered by large (100 mm to 1 cm) methane
grains to 3 sigma confidence.Comment: Accepted for publication in the Astrophysical Journa
The economic ecology of small businesses in Oxfordshire
Report by the Oxfordshire Economic Observatory (OEO) for the Federation of Small Businesses (FSB), Oxfordshire Branch
A "Starless" Core that Isn't: Detection of a Source in the L1014 Dense Core with the Spitzer Space Telescope
We present observations of L1014, a dense core in the Cygnus region previously thought to be starless, but data from the Spitzer Space Telescope show the presence of an embedded source. We propose a model for this source that includes a cold core, heated by the interstellar radiation field, and a low-luminosity internal source. The low luminosity of the internal source suggests a substellar object. If L1014 is representative, other "starless" cores may turn out to harbor central sources
Who the hell was that? Stories, bodies and actions in the world
This article explores a two-way relationship between stories and the experiential actions of bodies in the world. Through an autoethnographic approach, the article presents a series of interlinked story fragments in an effort to show and evoke a feel for the ways in which stories, bodies, and actions influence and shape each other over time. It offers some reflections on the experiences the stories portray from the perspective of a social constructionist conception of narrative theory and suggest that while stories exert a powerful influence on the actions of our bodies, our bodies intrude on or ‘talk back’ to this process because bodies have an existence beyond stories
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