Perceptions of Classroom Management Coaching at District A Independent School District

This study addressed teacher retention and research-to-practice gaps in the literature related to classroom management coaching and what types of teacher support are the best and why. The purpose of this qualitative case study was to explore the perceptions of teachers, campus administrators, and campus intervention coaches regarding District A Independent School District’s campus intervention coach model. This study attempted to understand better the perceptions of how the campus intervention coach model influences teachers’ decisions to remain in the profession; how teachers, campus administrators, and campus intervention coaches perceive the campus intervention coach model’s effectiveness in reducing the percentage of students involved in disciplinary referrals; and what recommendations teachers, campus administrators, and campus intervention coaches had on how to improve the campus intervention coach model. The research was conducted using semistructured Zoom interviews of teachers, administrators, and campus intervention coaches in District A Independent School District. Findings indicated that teachers, administrators, and campus intervention coaches perceived building relationships and building teacher efficacy as strategies that influence teachers’ decisions to remain in the profession. Additional findings revealed that teachers, administrators, and campus intervention coaches perceived that assisting teachers with establishing a well managed classroom and setting all students up for success influenced decreasing the percentage of students involved in disciplinary referrals. Recommendations for improving the program in both areas included increasing the coaching workforce, aligning all stakeholders, increasing campus intervention coach presence on campus, and equipping teachers through additional training on Tier 1 and Tier 2 behavior interventions, cultural diversity, and social-emotional learning

Cartilage on the Move: Cartilage Lineage Tracing During Tadpole Metamorphosis

The reorganization of cranial cartilages during tadpole metamorphosis is a set of complex processes. The fates of larval cartilage-forming cells (chondrocytes) and sources of adult chondrocytes are largely unknown. Individual larval cranial cartilages may either degenerate or remodel, while many adult cartilages appear to form de novo during metamorphosis. Determining the extent to which adult chondrocytes/cartilages are derived from larval chondrocytes during metamorphosis requires new techniques in chondrocyte lineage tracing. We have developed two transgenic systems to label cartilage cells throughout the body with fluorescent proteins. One system strongly labels early tadpole cartilages only. The other system inducibly labels forming cartilages at any developmental stage. We examined cartilages of the skull (viscero- and neurocranium), and identified larval cartilages that either resorb or remodel into adult cartilages. Our data show that the adult otic capsules, tecti anterius and posterius, hyale, and portions of Meckel\u27s cartilage are derived from larval chondrocytes. Our data also suggest that most adult cartilages form de novo, though we cannot rule out the potential for extreme larval chondrocyte proliferation or de- and re-differentiation, which could dilute our fluorescent protein signal. The transgenic lineage tracing strategies developed here are the first examples of inducible, skeleton-specific, lineage tracing in Xenopus

Warm HCN, C2H2, and CO in the disk of GV Tau

We present the first high-resolution, ground-based observations of HCN and C2H2 toward the T Tauri binary star system GV Tau. We detected strong absorption due to HCN nu_3 and weak C2H2 (nu_3 and nu_2 + (nu_4 + nu_5)^0_+) absorption toward the primary (GV Tau S) but not the infrared companion. We also report CO column densities and rotational temperatures, and present abundances relative to CO of HCN/CO ~0.6% and C2H2/CO ~1.2% and an upper limit for CH4/CO < 0.37% toward GV Tau S. Neither HCN nor C2H2 were detected toward the infrared companion and results suggest that abundances may differ between the two sources.Comment: 23 pages, 6 figures, accepted by Ap

CO Emission in the Inner Disk Around Young Intermediate-Mass Stars

We present observations that indicate viscous heating contributes significantly to the surface heating of the inner disk region (0.1-5 AU) around young intermediate-mass stars, Herbig AeBe stars, when the inner disk is optically thick. Brgamma flux is known to scale with accretion rate around young stars. We find a trend between Brgamma and CO emissivity, a tracer 1, 500 K gas in the gaseous atmospheres of less evolved inner disk regions in a sample of 25 Herbig AeBe stars, the higher mass analog of T Tauri stars. Evolved Herbig circumstellar disks do not follow this trend as closely. A thermal chemical model of the inner disk region of T Tauri stars by \citet{gla04} explains the strength and line profiles of observed CO rovibrational emission by showing that accretion contributes significantly to heating the protoplanetary disk. This heating produces the required temperatures and column densities for CO emission in the disk. Our results are consistent with these prescribed disk characteristics. Determining conditions and processes in circumstellar disks around young stars will help inform evolutionary theory and constrain timescales of disk dissipation and planet formation

Carboxylic Acid Deoxyfluorination and One-Pot Amide Bond Formation Using Pentafluoropyridine (PFP)

This work describes the application of pentafluoropyridine (PFP), a cheap commercially available reagent, in the deoxyfluorination of carboxylic acids to acyl fluorides. The acyl fluorides can be formed from a range of acids under mild conditions. We also demonstrate that PFP can be utilized in a one-pot amide bond formation via in situ generation of acyl fluorides. This one-pot deoxyfluorination amide bond-forming reaction gives ready access to amides in yields of ≤94%

Volatiles in protoplanetary disks

Volatiles are compounds with low sublimation temperatures, and they make up most of the condensible mass in typical planet-forming environments. They consist of relatively small, often hydrogenated, molecules based on the abundant elements carbon, nitrogen and oxygen. Volatiles are central to the process of planet formation, forming the backbone of a rich chemistry that sets the initial conditions for the formation of planetary atmospheres, and act as a solid mass reservoir catalyzing the formation of planets and planetesimals. This growth has been driven by rapid advances in observations and models of protoplanetary disks, and by a deepening understanding of the cosmochemistry of the solar system. Indeed, it is only in the past few years that representative samples of molecules have been discovered in great abundance throughout protoplanetary disks - enough to begin building a complete budget for the most abundant elements after hydrogen and helium. The spatial distributions of key volatiles are being mapped, snow lines are directly seen and quantified, and distinct chemical regions within protoplanetary disks are being identified, characterized and modeled. Theoretical processes invoked to explain the solar system record are now being observationally constrained in protoplanetary disks, including transport of icy bodies and concentration of bulk condensibles. The balance between chemical reset - processing of inner disk material strong enough to destroy its memory of past chemistry, and inheritance - the chemically gentle accretion of pristine material from the interstellar medium in the outer disk, ultimately determines the final composition of pre-planetary matter. This chapter focuses on making the first steps toward understanding whether the planet formation processes that led to our solar system are universal.Comment: Accepted for publication as a chapter in Protostars and Planets VI, University of Arizona Press (2014), eds. H. Beuther, R. Klessen, C. Dullemond, Th. Hennin

CO Line Emission and Absorption from the HL Tau Disk: Where is all the dust?

We present high-resolution infrared spectra of HL Tau, a heavily embedded young star. The spectra exhibit broad emission lines of hot CO gas as well as narrow absorption lines of cold CO gas. The column density for this cooler material (7.5+/-0.2 x 10^18 cm-2) indicates a large column of absorbing gas along the line of sight. In dense interstellar clouds, this column density of CO gas is associated with Av~52 magnitudes. However, the extinction toward this source (Av~23) suggests that there is less dust along the line of sight than inferred from the CO absorption data. We discuss three possibilities for the apparent paucity of dust along the line of sight through the flared disk: 1) the dust extinction has been underestimated due to differences in circumstellar grain properties, such as grain agglomeration; 2) the effect of scattering has been underestimated and the actual extinction is much higher; or (3) the line of sight through the disk is probing a gas-rich, dust-depleted region, possibly due to the stratification of gas and dust in a pre-planetary disk.Comment: To be published in The Astrophysical Journa

Responses of Vascular Endothelial Cells to Photoembossed Topographies on Poly(Methyl Methacrylate) Films.

Failures of vascular grafts are normally caused by the lack of a durable and adherent endothelium covering the graft which leads to thrombus and neointima formation. A promising approach to overcome these issues is to create a functional, quiescent monolayer of endothelial cells on the surface of implants. The present study reports for the first time on the use of photoembossing as a technique to create polymer films with different topographical features for improved cell interaction in biomedical applications. For this, a photopolymer is created by mixing poly(methyl methacrylate) (PMMA) and trimethylolpropane ethoxylate triacrylate (TPETA) at a 1:1 ratio. This photopolymer demonstrated an improvement in biocompatibility over PMMA which is already known to be biocompatible and has been extensively used in the biomedical field. Additionally, photoembossed films showed significantly improved cell attachment and proliferation compared to their non-embossed counterparts. Surface texturing consisted of grooves of different pitches (6, 10, and 20 µm) and heights (1 µm and 2.5 µm). The 20 µm pitch photoembossed films significantly accelerated cell migration in a wound-healing assay, while films with a 6 µm pitch inhibited cells from detaching. Additionally, the relief structure obtained by photoembossing also changed the surface wettability of the substrates. Photoembossed PMMA-TPETA systems benefited from this change as it improved their water contact angle to around 70°, making it well suited for cell adhesion.This project was supported in part by MRC/EPSRC grant G0502256-77947. Lin Qiu was supported by a joint PhD studentship from Queen Mary University of London and the China Scholarship Council (CSC) between 2010 and 2014

Erratum: Warm HCN, C2H2, and CO in the Disk of GV Tau\u27\u27

This is an Erratum for the article 2007 ApJ 660 157