Tailored syngas production from the gasification of biogenic waste in the presence of a CO2 sorbent

5 figures, 1 tableSyngas production via steam gasification is one of the thermochemical processes with the greatest potential for obtaining synthetic fuels from a solid fuel, especially indirect gasification in a dual fluidised bed system where the energy needed for gasification is provided by the circulating material from a high temperature secondary reactor. When the circulating material is a CO2 sorbent, a sorption enhanced gasification (SEG) system results where the circulating solid, in addition to the energy provided by sensible heat, supplies additional heat by means of the exothermic carbonation reaction with the CO2 generated from biomass gasification. In the presented work, the SEG process was studied for a biogenic waste material (consisting of the organic fraction of municipal solid waste) in a 30 kWth bubbling fluidised bed reactor using lime as CO2 sorbent. The effect of the main operating variables (temperature, steam-to-carbon (S/C) ratio and sorbent-to-biomass ratio (Ca/C)) on gas quality was assessed. M-modules (M=(H2-CO2)/(CO+CO2)) between 1.2 to almost 4 have been obtained acting on the variables that mostly affect the permanent gas composition, i.e. gasification temperature and/or sorbent-to-biomass ratio.This work has been carried out as part of the European Commission Horizon 2020 Framework Programme project FLEDGED (Grant agreement No. 727600) and the project WASYNG (No. RTI2018-095575-B-100) funded by the Spanish Ministry of Science, Innovation and Universities. Authors thank also the Regional Aragon Government (DGA) for the economic support under the research group’s programme.Peer reviewe

Optimised production of tailored syngas from municipal solid waste (MSW) by sorption-enhanced gasification

8 figures, 5 tablesSorption-enhanced gasification (SEG) is a promising indirect gasification route for the production of synthetic fuels since it allows the H2, CO and CO2 content of the resulting syngas to be adjusted. This SEG process has been successfully demonstrated at pilot scale for lignocellulosic biomass and other agricultural and forest waste products, mainly focusing on H2-rich gas production. Within this work, the potential application of the SEG process to a material derived from municipal solid waste (MSW) as feedstock is experimentally demonstrated in a 30 kWth bubbling fluidised-bed (BFB) gasifier. The influence of the sorbent-to-biomass ratio, steam excess and gasification temperature has been carefully analysed in order to understand their effect on SEG performance. Moreover, main conditions able to affect the resulting syngas composition, specifically in terms of H2, CO and CO2 content, have been indicated. Gasification temperature turned out to be the variable that most influenced syngas composition due to the limiting mechanisms associated with the carbonation of the CaO used as bed material. This operating variable also determined biomass conversion, together with solids residence time in the gasifier, resulting in a wide variation of fixed carbon conversion under the studied conditions. Finally, tar yield and composition were evaluated as a function of temperature and the sorbent-to-biomass ratio used, resulting in tar contents as low as 7 g/Nm3 (dry gas), consisting mainly of 1-ring aromatic compounds.This work has been supported by the European Commission (FLEDGED project, grant agreement No. 727600); the Spanish Ministry of Science and Innovation, the State Research Agency and the European Founds for Regional Development (No. RTI2018-095575-B-I00, MCI/AEI/FEDER, UE); and the Regional Aragon Government (DGA).Peer reviewe

Salud de personas que conviven con dependientes

Objetivos: Verificar a partir de datos estadísticos, que la presencia en el hogar de una persona dependiente afecta en la salud, comparar las variables que se analizan y aportar datos para futuras investigaciones con personas que conviven con dependientes. Diseño: Estudio descriptivo transversal a través de datos secundarios. Emplazamiento: Encuestas realizadas en hogares aleatorios de todo el territorio nacional a través de la Encuesta Nacional de Salud 2011-2012. Participantes: 11.041 encuestado de entre 40 y 75 años de edad. Mediciones principales: Método de estimación es el modelo logístico (Comando: Logistic para STATA.13) con un análisis de resultado realizado a través de la Odds Ratio con un intervalo de significación menor o igual a 0,10. Resultados: La salud de las personas que conviven con una persona dependiente es generalmente peor que aquellas que no conviven, destacando la percepción de mala salud, el hecho de ser mujer, ser un adulto mayor o persona mayor, ser soltero o viudo. Conclusiones: Con la presencia de una persona dependiente en el hogar pueden aparecer efectos negativos en la salud de las personas, según las características también de éstas

IAA : Información y actualidad astronómica (4)

Sumario : Investigación : Galaxias huéspedes de cuásares.-- El gigante gaseoso y su gran mancha roja.-- Ventana Abierta: Un futuro incierto.-- Charlas con… John Hutchings.-- Actualidad Científica: La edad de la galaxia.-- Sorpresas en el cinturón de Kuiper.-- Actividades IAA.-- Agenda.N

Epidemiología básica. Material docente para prácticas en ciencias de la salud

Material docente teórico práctico para apoyar la enseñanza de la epidemiología. Consta de 4 unidades, cada una de ellas con una introducción teórica y unos ejercicios basados en artículos publicados en inglés en revistas científicas

Plan de parto y nacimiento

Texto en gallego y españo

Association of Candidate Gene Polymorphisms With Chronic Kidney Disease: Results of a Case-Control Analysis in the Nefrona Cohort

Chronic kidney disease (CKD) is a major risk factor for end-stage renal disease, cardiovascular disease and premature death. Despite classical clinical risk factors for CKD and some genetic risk factors have been identified, the residual risk observed in prediction models is still high. Therefore, new risk factors need to be identified in order to better predict the risk of CKD in the population. Here, we analyzed the genetic association of 79 SNPs of proteins associated with mineral metabolism disturbances with CKD in a cohort that includes 2, 445 CKD cases and 559 controls. Genotyping was performed with matrix assisted laser desorption ionizationtime of flight mass spectrometry. We used logistic regression models considering different genetic inheritance models to assess the association of the SNPs with the prevalence of CKD, adjusting for known risk factors. Eight SNPs (rs1126616, rs35068180, rs2238135, rs1800247, rs385564, rs4236, rs2248359, and rs1564858) were associated with CKD even after adjusting by sex, age and race. A model containing five of these SNPs (rs1126616, rs35068180, rs1800247, rs4236, and rs2248359), diabetes and hypertension showed better performance than models considering only clinical risk factors, significantly increasing the area under the curve of the model without polymorphisms. Furthermore, one of the SNPs (the rs2248359) showed an interaction with hypertension, being the risk genotype affecting only hypertensive patients. We conclude that 5 SNPs related to proteins implicated in mineral metabolism disturbances (Osteopontin, osteocalcin, matrix gla protein, matrix metalloprotease 3 and 24 hydroxylase) are associated to an increased risk of suffering CKD