1,958 research outputs found

    Quick Analysis of Organic Amendments via Portable X-ray Fluorescence Spectrometry

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    The determination of heavy metals in soils and organic amendments, such as compost, manure, biofertilizer, and sludge, generally involves the digestion of samples with aqua regia, and the determination of those in the solution using various techniques. Portable X-ray fluorescence (PXRF) has many advantages in relation to traditional analytical techniques. However, PXRF determines the total elemental content and, until now, its use for the analysis of organic amendments has been limited. The objective of this work is the calibration of a PXRF instrument to determine the aqua regia-soluble elemental contents directly in solid samples of organic amendments. Our proposal will avoid the digestion step and the use of other laboratory techniques. Using a training set of samples, calibration functions were obtained that allow the determination of the aqua regia-soluble contents from the PXRF readings of total contents. The calibration functions (obtained by multiple linear regression) allowed the quantitative determination of the aqua regia-soluble contents of Fe, K, P, S, Zn, Cu, Pb, Sr, Cr, and Mn, as well as the organic matter content and a semi-quantitative assessment of Al, Ca, V, Ba, Ni, and As contents. The readings of Si, Fe, Al, Ca, K, or S were used as correction factors, indicating that the calibrations functions found are truly based on the chemical composition of the sample matrix. This study will allow a fast, cheap, and reliable field analysis of organic amendments and of other biomass-based materials.Spanish Ministry of Science, Innovation and Universities, and the European Regional Development Fund, European Union, (AEI/FEDER, UE), grant number CGL2016-78937-R

    “La importancia de la Gestión de la Experiencia del Consumidor en el sector del lujo”.

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    El aumento de la digitalización de la industria de la moda, el crecimiento de la competitividad del mercado, y la existencia de un consumidor más exigente e informado saturado del marketing tradicional, ha dado lugar a un marketing enfocado en la creación de experiencias. El objetivo principal de mi trabajo es analizar la Experiencia del Consumidor en el ámbito de la industria del lujo. En este trabajo se estudiarán las características únicas del lujo y a sus consumidores. Por otro lado, estudiaremos el termino gestión de la experiencia del consumidor, de donde viene y sus últimas aplicaciones. También tendré en cuenta el factor actual de la pandemia del Covid-19. Intentaremos explicar cómo se debe de aplicar este enfoque de marketing específico en el mundo del lujo. Tras el trabajo teórico, realizaré una serie de entrevistas en profundidad a dos perfiles dentro del mundo del lujo: el consumidor y los expertos. Los resultados obtenidos en las entrevistas serán de gran ayuda ya que se harán a perfiles muy concretos, tendrán la libertad de expresarse y surgirán nuevas preguntas.<br /

    Examining Teamwork Competencies and Team Performance in Experiential Entrepreneurship Education: Emergent Intragroup Conflict as a Learning Triggering Event

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    Purpose Although the importance of teamwork competencies and effective conflict management in entrepreneurship education is recognised, we have limited knowledge of how these factors interact to influence performance in entrepreneurial teams. This research explores teamwork competencies as a predictor of entrepreneurial team performance and the moderating effect of emerging cognitive and interpersonal team conflict as levers in entrepreneurship learning. Design/methodology/approach A time-lagged survey method was used to collect data from 49 teams (156 individuals) of undergraduate students in an experiential new venture creation course. A predictive model of entrepreneurial team performance through hierarchical regression analyses and moderated-moderation analyses was tested. Findings Results reveal that teamwork competencies have a significant and direct influence on entrepreneurial team performance and that intragroup conflict strengthens that relationship when high levels of cognitive conflict and low levels of interpersonal conflict emerge. Practical implications The findings have implications for the design of entrepreneurial training programs, which will benefit from interventions aimed at teamwork competency development that incorporate strategies promoting constructive cognitive conflict while preventing the emergence of interpersonal conflict. Originality/value This study is a step forward in entrepreneurship education research from the perspective of social and interpersonal processes by identifying the patterns of intra-team conflict that lead to more effective entrepreneurial teams and more productive use of teamwork competencies in a learning-by-doing entrepreneurial context

    Examining teamwork competencies and team performance in experiential entrepreneurship education: emergent intragroup conflict as a learning triggering event

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    Purpose – Although the importance of teamwork competencies and effective conflict management in entrepreneurship education is recognised, we have limited knowledge of how these factors interact to influence performance in entrepreneurial teams. This research explores teamwork competencies as a predictor of entrepreneurial team performance and the moderating effect of emerging cognitive and interpersonal team conflict as levers in entrepreneurship learning. Design/methodology/approach –Atime-lagged survey method was used to collect data from 49 teams (156 individuals) of undergraduate students in an experiential new venture creation course. A predictive model of entrepreneurial team performance through hierarchical regression analyses and moderated-moderation analyses was tested. Findings – Results reveal that teamwork competencies have a significant and direct influence on entrepreneurial team performance and that intragroup conflict strengthens that relationship when high levels of cognitive conflict and low levels of interpersonal conflict emerge. Practical implications – The findings have implications for the design of entrepreneurial training programs, which will benefit from interventions aimed at teamwork competency development that incorporate strategies promoting constructive cognitive conflict while preventing the emergence of interpersonal conflict. Originality/value – This study is a step forward in entrepreneurship education research from the perspective of social and interpersonal processes by identifying the patterns of intra-team conflict that lead to more effective entrepreneurial teams and more productive use of teamwork competencies in a learning-by-doing entrepreneurial context

    Features associated to woody hosts in the bacterial pathogen of olive plants Pseudomonas savastanoi pv. savastanoi

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    The causal agent of olive knot disease, Pseudomonas savastanoi pv. savastanoi, belongs to the Pseudomonas syringae complex, a bacterial group causing diseases in a broad variety of both woody and herbaceous plant species. Here we summarize our results regarding a set of P. savastanoi pv. savastanoi features exclusively found in the genomes of bacteria from the P. syringae complex isolated from woody hosts. Comparative genomics and evolutionary studies allowed us to identify a 15 kb genomic island (WHOP, from woody host and Pseudomonas), carrying a set of genes involved in degradation of phenolic compounds and exclusively found in bacterial pathogens of woody hosts. Deletion of several WHOP-encoded genes in Pseudomonas savastanoi pv. savastanoi NCPPB 3335 revealed that they play a role in the virulence of the strain in woody olive plants but not in in vitro-grown (nonwoody) plants. In addition, several type III secretion system effectors belonging to the HopAF, HopAO and HopBL families were shown to be clustered across the P. syringae complex according to the woody/herbaceous nature of their host of isolation. Further functional analyses of these virulence factors are needed to facilitate the design of novel strategies directed to control bacterial pathogens of woody hosts.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

    Comparative Analysis of the Type III Secretion System Effector Repertoires of Pseudomonas savastanoi Pathovars Pathogenic on Woody Hosts

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    Comunicación de tipo pósterThe species Pseudomonas savastanoi, a member of the Pseudomonas syringae complex, includes four pathovars causing knots or excrescences in woody hosts: P. savastanoi pv. savastanoi (Psv), pv. fraxini (Psf), pv. nerii (Psn) and pv. retacarpa (Psr), comprising isolates from olive, ash, oleander and broom plants, respectively. Pathogenicity of P. savastanoi is dependent, among other factors, on the type III secretion system (T3SS) and its effector (T3E) repertoire. Furthermore, a putative role in the interaction with woody hosts has been suggested for several of these T3E. The recent availability of the genome sequences of several P. savastanoi strains isolated from different hosts has facilitated bioinformatics predictions of their T3SS genes and T3E pools, the study of their distribution in other strains of the P. syringae complex isolated from woody hosts and the functional analysis of several of these secreted proteins. As previously reported for Psv, Psn and Psf, here we show that pathogenicity of Psr ICMP16945, is also dependent on the T3SS. Psv strains NCPPB 3335, ICMP4352 and PseNe107 share a core set of at least 22 T3E, 18 of which are also encoded in Psn ICMP16943, Psf ICMP7711 and Psr ICMP16945. However, these three strains encode truncated versions of 1-2 of these 18 T3E and, Psr ICMP16945 contains three pathovarspecific T3E. Our results also show that several T3E, including HopAO1, are phylogenetically clustered across the P. syringae complex according to the woody/herbaceous nature of their host of isolation, suggesting host specialization of these effectors in this complex.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tec

    Design of Acoustic Bifocal Lenses Using a Fourier-Based Algorithm

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    [EN] In this work, we develop a new design method based on fast Fourier transform (FFT) for implementing zone plates (ZPs) with bifocal focusing profiles. We show that the FFT of the governing binary sequence provides a discrete sequence of the same length, which indicates the location of the main foci at the ZP focusing profile. Then, using reverse engineering and establishing a target focusing profile, we are capable of generating a binary sequence that provides a ZP with the desired focusing profile. We show that this design method, based on the inverse fast Fourier transform (IFFT), is very flexible and powerful and allows to tailor the design of bifocal ZPs to achieve focusing profiles with the desired foci locations and resolutions. The key advantage of our design algorithm, compared to other alternatives presented in previous works, is that our method provides bifocal focusing profiles with an absolute control of the foci locations. Moreover, although we analyze the performance of this novel design algorithm for underwater ultrasonics, it can also be successfully extended to different fields of physics, such as optics or microwaves, where ZPs are widely employed.This work has been supported by the Spanish MICINN RTI2018-100792-B-I00 project and Generalitat Valenciana AICO/2020/139 project.Fuster Escuder, JM.; Pérez-López, S.; Candelas Valiente, P. (2021). Design of Acoustic Bifocal Lenses Using a Fourier-Based Algorithm. Sensors. 21(24):1-17. https://doi.org/10.3390/s21248285S117212

    Recordando a Jaime Salcedo Salcedo

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    This is a simple recognition to the professor and architect Jaime Salcedo Salcedo that highlights his professional achievements and his qualities as a person. The estate was an axis on his life and his words, the most forceful tool to spread his knowledge.En este sencillo reconocimiento del profesor y arquitecto Jaime Salcedo Salcedo, se destacan tanto sus logros profesionales como las cualidades personales. El patrimonio fue un eje en su vida y la palabra el medio más contundente para transmitir su conocimiento

    Spatio-temporal ultrasound beam modulation to sequentially achieve multiple foci with a single planar monofocal lens

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    [EN] Ultrasound focusing is a hot topic due to its multiple applications in many fields, including biomedical imaging, thermal ablation of cancerous tissues, and non destructive testing in industrial environments. In such applications, the ability to control the focal distance of the ultrasound device in real-time is a key advantage over conventional devices with fixed focal parameters. Here, we present a method to achieve multiple time-modulated ultrasound foci using a single planar monofocal Fresnel Zone Plate. The method takes advantage of the focal distance linear dependence on the operating frequency of this kind of lenses to design a sequence of contiguous modulated rectangular pulses that achieve different focal distances and intensities as a function of time. Both numerical simulations and experimental results are presented, demonstrating the feasibility and potential of this technique.This work has been supported by Spanish MICINN project number RTI2018-100792-B-I00 and Generalitat Valenciana project AICO/2020/139. S.P.-L. acknowledges financial support from Universitat Politecnica de Valencia Grant program PAID-01-18.Pérez-López, S.; Fuster Escuder, JM.; Candelas Valiente, P. (2021). Spatio-temporal ultrasound beam modulation to sequentially achieve multiple foci with a single planar monofocal lens. Scientific Reports. 11(1):1-7. https://doi.org/10.1038/s41598-021-92849-xS17111Schmerr, L. W. Fundamentals of Ultrasonic Nondestructive Evaluation. Springer Series in Measurement Science and Technology (Springer International Publishing, 2016).Azhari, H. Basics of Biomedical Ultrasound for Engineers (Wiley, 2010).Fan, X. & Hynynen, K. Ultrasound surgery using multiple sonications—Treatment time considerations. Ultrasound Med. 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Nature 537, 518–522. https://doi.org/10.1038/nature19755 (2016).Brown, M. D., Cox, B. T. & Treeby, B. E. Design of multi-frequency acoustic kinoforms. Appl. Phys. Lett. 111, 244101. https://doi.org/10.1063/1.5004040 (2017).Jiménez-Gambín, S., Jiménez, N., Benlloch, J. M. & Camarena, F. Holograms to focus arbitrary ultrasonic fields through the skull. Phys. Rev. Appl. 12, 014016. https://doi.org/10.1103/PhysRevApplied.12.014016 (2019).Young, M. Zone plates and their aberrations. J. Opt. Soc. Am. 62, 972. https://doi.org/10.1364/JOSA.62.000972 (1972).Rodrigues Ribeiro, R. S., Dahal, P., Guerreiro, A., Jorge, P. A. S. & Viegas, J. Fabrication of Fresnel plates on optical fibres by FIB milling for optical trapping, manipulation and detection of single cells. Sci. Rep. 7, 4485. https://doi.org/10.1038/s41598-017-04490-2 (2017).Kim, H. et al. Metallic Fresnel zone plate implemented on an optical fiber facet for super-variable focusing of light. Opt. 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    M-Bonacci Zone Plates for Ultrasound Focusing

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    [EN] In this work, we present a thorough analysis on M-bonacci zone plates for ultrasound focusing applications. These planar lenses are capable of providing bifocal focusing profiles with equal intensity in both foci and become very appealing for a wide range of scenarios including medical and industrial applications. We show that in high-wavelength domains, such as acoustics or microwaves, the separation between both foci can be finely adjusted at the expense of slightly increasing the distortion of the focusing profile, and we introduce a design parameter to deal with this issue and simplify the design process of these lenses. Experimental measurements are in good agreement with numerical simulations and demonstrate the potential of M-bonacci lenses in ultrasound focusing applications.This work has been supported by Spanish MICINN RTI2018-100792-B-I00 project. S.P.-L. acknowledges financial support from Universitat Politecnica de Valencia grant program PAID-01-18.Pérez-López, S.; Fuster Escuder, JM.; Candelas Valiente, P. (2019). M-Bonacci Zone Plates for Ultrasound Focusing. Sensors. 19(19):1-13. https://doi.org/10.3390/s19194313S1131919Chen, J., Xiao, J., Lisevych, D., Shakouri, A., & Fan, Z. (2018). Deep-subwavelength control of acoustic waves in an ultra-compact metasurface lens. Nature Communications, 9(1). doi:10.1038/s41467-018-07315-6Molerón, M., Serra-Garcia, M., & Daraio, C. (2014). Acoustic Fresnel lenses with extraordinary transmission. Applied Physics Letters, 105(11), 114109. doi:10.1063/1.4896276Li, Y., Yu, G., Liang, B., Zou, X., Li, G., Cheng, S., & Cheng, J. (2014). Three-dimensional Ultrathin Planar Lenses by Acoustic Metamaterials. Scientific Reports, 4(1). doi:10.1038/srep06830Lan, J., Li, Y., Xu, Y., & Liu, X. (2017). Manipulation of acoustic wavefront by gradient metasurface based on Helmholtz Resonators. Scientific Reports, 7(1). doi:10.1038/s41598-017-10781-5Jiménez-Gambín, S., Jiménez, N., Benlloch, J. M., & Camarena, F. (2019). Holograms to Focus Arbitrary Ultrasonic Fields through the Skull. Physical Review Applied, 12(1). doi:10.1103/physrevapplied.12.014016Pérez-López, S., Fuster, J. M., Minin, I. V., Minin, O. V., & Candelas, P. (2019). Tunable subwavelength ultrasound focusing in mesoscale spherical lenses using liquid mixtures. Scientific Reports, 9(1). doi:10.1038/s41598-019-50019-0Veira Canle, D., Kekkonen, T., Mäkinen, J., Puranen, T., Nieminen, H. J., Kuronen, A., … Hæggström, E. (2019). Practical realization of a sub-λ/2 acoustic jet. Scientific Reports, 9(1). doi:10.1038/s41598-019-41335-6Calvo, D. C., Thangawng, A. L., Nicholas, M., & Layman, C. N. (2015). Thin Fresnel zone plate lenses for focusing underwater sound. Applied Physics Letters, 107(1), 014103. doi:10.1063/1.4926607Pérez-López, S., Fuster, J. M., Candelas, P., Rubio, C., & Belmar, F. (2018). On the use of phase correction rings on Fresnel zone plates with ultrasound piston emitters. Applied Physics Letters, 112(26), 264102. doi:10.1063/1.5036712Tarrazó-Serrano, D., Pérez-López, S., Candelas, P., Uris, A., & Rubio, C. (2019). Acoustic Focusing Enhancement In Fresnel Zone Plate Lenses. Scientific Reports, 9(1). doi:10.1038/s41598-019-43495-xRodrigues Ribeiro, R. S., Dahal, P., Guerreiro, A., Jorge, P. A. S., & Viegas, J. (2017). Fabrication of Fresnel plates on optical fibres by FIB milling for optical trapping, manipulation and detection of single cells. Scientific Reports, 7(1). doi:10.1038/s41598-017-04490-2Hristov, H. D., & Rodriguez, J. M. (2012). Design Equation for Multidielectric Fresnel Zone Plate Lens. IEEE Microwave and Wireless Components Letters, 22(11), 574-576. doi:10.1109/lmwc.2012.2224099Clement, G., Nomura, H., & Kamakura, T. (2015). Ultrasound field measurement using a binary lens. IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control, 62(2), 350-359. doi:10.1109/tuffc.2014.006800Pérez-López, S., Fuster, J. M., Candelas, P., & Rubio, C. (2019). On the focusing enhancement of Soret zone plates with ultrasound directional transducers. Applied Physics Letters, 114(22), 224101. doi:10.1063/1.5100219Monsoriu, J. A., Calatayud, A., Remon, L., Furlan, W. D., Saavedra, G., & Andres, P. (2013). Bifocal Fibonacci Diffractive Lenses. IEEE Photonics Journal, 5(3), 3400106-3400106. doi:10.1109/jphot.2013.2248707Machado, F., Ferrando, V., Furlan, W. D., & Monsoriu, J. A. (2017). Diffractive m-bonacci lenses. Optics Express, 25(7), 8267. doi:10.1364/oe.25.008267Saavedra, G., Furlan, W. D., & Monsoriu, J. A. (2003). Fractal zone plates. Optics Letters, 28(12), 971. doi:10.1364/ol.28.000971Furlan, W. D., Saavedra, G., & Monsoriu, J. A. (2007). White-light imaging with fractal zone plates. Optics Letters, 32(15), 2109. doi:10.1364/ol.32.002109Mendoza-Yero, O., Fernández-Alonso, M., Mínguez-Vega, G., Lancis, J., Climent, V., & Monsoriu, J. A. (2009). Fractal generalized zone plates. Journal of the Optical Society of America A, 26(5), 1161. doi:10.1364/josaa.26.001161Ferrando, V., Giménez, F., Furlan, W. D., & Monsoriu, J. A. (2015). Bifractal focusing and imaging properties of Thue–Morse Zone Plates. Optics Express, 23(15), 19846. doi:10.1364/oe.23.019846Xia, T., Cheng, S., & Tao, S. (2018). Generation of three equal-intensity foci based on a modified composite zone plate. Optik, 159, 150-156. doi:10.1016/j.ijleo.2018.01.071Fuster, J., Pérez-López, S., Candelas, P., & Rubio, C. (2018). Design of Binary-Sequence Zone Plates in High Wavelength Domains. Sensors, 18(8), 2604. doi:10.3390/s18082604Nie, L., Cai, X., Maslov, K., Garcia-Uribe, A., Anastasio, M. A., & Wang, L. V. (2012). Photoacoustic tomography through a whole adult human skull with a photon recycler. Journal of Biomedical Optics, 17(11), 110506. doi:10.1117/1.jbo.17.11.110506Chen, M., Knox, H. J., Tang, Y., Liu, W., Nie, L., Chan, J., & Yao, J. (2019). Simultaneous photoacoustic imaging of intravascular and tissue oxygenation. Optics Letters, 44(15), 3773. doi:10.1364/ol.44.003773Ter Haar, >Gail, & Coussios, C. (2007). High intensity focused ultrasound: Physical principles and devices. International Journal of Hyperthermia, 23(2), 89-104. doi:10.1080/02656730601186138Suo, D., Jin, Z., Jiang, X., Dayton, P. A., & Jing, Y. (2017). Microbubble mediated dual-frequency high intensity focused ultrasound thrombolysis: AnIn vitrostudy. Applied Physics Letters, 110(2), 023703. doi:10.1063/1.4973857GyP, S., DY, L., & G, H. (2017). What is on the Horizon for Hyperthermic Cancer Therapy? Journal of Traditional Medicine & Clinical Naturopathy, 06(02). doi:10.4172/2573-4555.1000217Simon, J. C., Sapozhnikov, O. A., Khokhlova, V. A., Wang, Y.-N., Crum, L. A., & Bailey, M. R. (2012). Ultrasonic atomization of tissue and its role in tissue fractionation by high intensity focused ultrasound. Physics in Medicine and Biology, 57(23), 8061-8078. doi:10.1088/0031-9155/57/23/8061Jeong, J. S., Cannata, J. M., & Shung, K. K. (2010). Dual-Focus Therapeutic Ultrasound Transducer for Production of Broad Tissue Lesions. Ultrasound in Medicine & Biology, 36(11), 1836-1848. doi:10.1016/j.ultrasmedbio.2010.08.008Jong Seob Jeong. (2013). Dual concentric-sectored HIFU transducer with phase-shifted ultrasound excitation for expanded necrotic region: a simulation study. IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control, 60(5), 924-931. doi:10.1109/tuffc.2013.264
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