Compressor and Turbine Blade Design by Optimization

Compressor and turbine blade design involves thermodynamical, aerodynamical and mechanical aspects, resulting in an important number of iterations. Inverse methods and optimization procedures help the designer in this long and eventually frustrating process. In this paper an optimization procedure is presented which solves two types of two-dimensional or quasi-three-dimensional problems: the inverse problem, for which a target velocity distribution is imposed, and a more global problem, in which the aerodynamic load is maximized

Ergodicity and Slowing Down in Glass-Forming Systems with Soft Potentials: No Finite-Temperature Singularities

The aim of this paper is to discuss some basic notions regarding generic glass forming systems composed of particles interacting via soft potentials. Excluding explicitly hard-core interaction we discuss the so called `glass transition' in which super-cooled amorphous state is formed, accompanied with a spectacular slowing down of relaxation to equilibrium, when the temperature is changed over a relatively small interval. Using the classical example of a 50-50 binary liquid of N particles with different interaction length-scales we show that (i) the system remains ergodic at all temperatures. (ii) the number of topologically distinct configurations can be computed, is temperature independent, and is exponential in N. (iii) Any two configurations in phase space can be connected using elementary moves whose number is polynomially bounded in N, showing that the graph of configurations has the `small world' property. (iv) The entropy of the system can be estimated at any temperature (or energy), and there is no Kauzmann crisis at any positive temperature. (v) The mechanism for the super-Arrhenius temperature dependence of the relaxation time is explained, connecting it to an entropic squeeze at the glass transition. (vi) There is no Vogel-Fulcher crisis at any finite temperature T>0Comment: 10 pages, 9 figures, submitted to PR

Actes du 21e Colloque de l'AQPC

Également disponible en version papier.Titre de l'écran-titre (visionné le 14 avril 2010)Bibliogr.: p. 9-1

Utilisation de la microtomographie à rayons X pour suivre le séchage convectif de boues d'épuration

peer reviewedX-ray microtomography is proposed as a new tool to investigate the evolution of size, shape and texture of soft materials during a drying operation. This study is focused on the drying of mechanically dewatered sludges from a secondary wastewater treatment. The shrinkage phenomenon is shown to play a crucial role in the control of the drying process. The shrinkage curves are determined by analysing the shape and size of cross sectional microtomographic images of sludge extrudates at different levels of drying. The observation of drying and shrinkage curves allows us to determine 3 critical water content values, which define different drying zones where extragranular, intragranular or mixed limitations prevail. When drying is externally controlled. the decrease of the drying rate observed during experiments can be related to the reduction of the external area of the sample, i.e., to shrinkage. When drying is internally controlled, resistances inside the solid govern the process. Between these two extreme situations, the drying rate reduction is the result of both the external area decrease and the development of internal resistances limiting drying. A multizone model is proposed to describe quantitatively these observations. The analysis of the internal texture of the Sludge extrudates reveal, crack formation at the end of the drying process. The onset of crack formation is clearly related to the appearance of internal transfer limitations. i.e., humidity and temperature gradients inside the material

Rigid urea and self-healing thiourea ethanolamine monolayers

A series of long-tail alkyl ethanolamine analogs containing amide-, urea-, and thiourea moieties was synthesized and the behavior of the corresponding monolayers was assessed on the Langmuir–Pockels trough combined with grazing incidence X-ray diffraction experiments and complemented by computer simulations. All compounds form stable monolayers at the soft air/water interface. The phase behavior is dominated by strong intermolecular headgroup hydrogen bond networks. While the amide analog forms well-defined monolayer structures, the stronger hydrogen bonds in the urea analogs lead to the formation of small three-dimensional crystallites already during spreading due to concentration fluctuations. The hydrogen bonds in the thiourea case form a two-dimensional network, which ruptures temporarily during compression and is recovered in a self-healing process, while in the urea clusters the hydrogen bonds form a more planar framework with gliding planes keeping the structure intact during compression. Because the thiourea analogs are able to self-heal after rupture, such compounds could have interesting properties as tight, ordered, and self-healing monolayers

Preparing a solar take-off: solar energy demonstration and exhibitions in Japan, 1945–1993

When the first oil crisis hit Japan in 1973, the country was highly dependent on imported oil as the source of electric power. The dire prospect of an oil cut-off gave sufficient and immediate impetus for Japan to begin searching frantically for alternative energy sources. Starting in 1974, the state-sponsored Sunshine Project, which originated from concern about the country’s excessive oil dependency – rather than being a direct response to the oil crisis – mobilised the technological and financial resources for finding viable energy alternatives and implemented a number of state-funded projects. One of the most successful enterprises was the development of solar photovoltaic (PV) power generation, and, as a consequence, the household solar PV panel penetrated into the consumer market in the 1990s, comparatively earlier than most of the developed nations. The existing literature tends to focus on the economic incentive provided by state subsidy. However, the diffusion of the solar panel in Japan calls for a more nuanced explanation. A certain degree of social acceptance was needed before a large number of consumers embraced a new energy technology to the extent that they were willing to pay for the initial cost. The social acceptance for using a new technology was, in turn, based on pre-existing knowledge about the technology. This paper aims at shedding light on the pathways through which the knowledge about solar energy proliferated in the Japanese society, by focusing on solar energy demonstration and exhibitions – these forms of knowledge circulation had their roots in the penetration of the solar water heater in rural areas of Japan in the immediate post-WWII period

Hubbert's Oil Peak Revisited by a Simulation Model

CERNA WORKING PAPER SERIES 2010-17As conventional oil reserves are declining, the debate on the oil production peak has become a burning issue. An increasing number of papers refer to Hubbert's peak oil theory to forecast the date of the production peak, both at regional and world levels. However, in our views, this theory lacks microeconomic foundations. Notably, it does not assume that exploration and production decisions in the oil industry depend on market prices. In an attempt to overcome these shortcomings, we have built an adaptative model, accounting for the behavior of one agent, standing for the competitive exploration-production industry, subjected to incomplete but improving information on the remaining reserves. Our work yields challenging results on the reasons for an Hubbert type peak oil, lying mainly "above the ground", both at regional and world levels, and on the shape of the production and marginal cost trajectories

Against the rules: pressure induced transition from high to reduced order

Envisioning the next generation of drug delivery nanocontainers requires more in- depth information on the fundamental physical forces at play in bilayer membranes. In order to achieve this, we combine chemical synthesis with physical–chemical analytical methods and probe the relationship between a molecular structure and its biophysical properties. With the aim of increasing the number of hydrogen bond donors compared to natural phospholipids, a phospholipid compound bearing urea moieties has been synthesized. The new molecules form interdigitated bilayers in aqueous dispersions and self-assemble at soft interfaces in thin layers with distinctive structural order. At lower temperatures, endothermic and exothermic transitions are observed during compression. The LC1 phase is dominated by an intermolecular hydrogen bond network of the urea moieties leading to a very high chain tilt of 52°. During compression and at higher temperatures, presumably this hydrogen bond network is broken allowing a much lower chain tilt of 35°. The extremely different monolayer thicknesses violate the two-dimensional Clausius–Clapeyron equation

Hubbert's Oil Peak Revisited by a Simulation Model

As conventional oil reserves are declining, the debate on the oil production peak has become a burning issue. An increasing number of papers refer to Hubbert's peak oil theory to forecast the date of the production peak, both at regional and world levels. However, in our views, this theory lacks microeconomic foundations. Notably, it does not assume that exploration and production decisions in the oil industry depend on market prices. In an attempt to overcome these shortcomings, we have built an adaptative model, accounting for the behavior of one agent, standing for the competitive exploration-production industry, subjected to incomplete but improving information on the remaining reserves. Our work yields challenging results on the reasons for an Hubbert type peak oil, lying mainly "above the ground", both at regional and world levels, and on the shape of the production and marginal cost trajectories.