Hypoxia in the Lower Rappahannock Estuary

There are several objectives to this study. The immediate objective is to collect a comprehensive and consistent set of field observations to better describe the hypoxic condition in the Rappahannock River. Other objectives can be classified as short and long term goals. Long term: (1) Identify and quantify the processes contributing to the dissolved oxygen budget in deep waters, and explain the variabilities among the three Virginia major tributary estuaries. (2) Provide information for resource management so that the James River can be protected from hypoxic problems and, perhaps, the problems in the York and Rappahannock Rivers can be alleviated. Short term: (1) Is the hypoxic condition in the Rappahannock River just an extension of that in Chesapeake Bay, or does it originate locally within the river

Coupled valence and spin state transition in (Pr0.7Sm0.3)0.7Ca0.3CoO3

The coupled valence and spin state transition (VSST) taking place in (Pr0.7Sm0.3)0.7Ca0.3CoO3 was investigated by soft x-ray absorption spectroscopy (XAS) experiments carried out at the Pr-M4,5, Co-L2,3, and O-1s edges. This VSST is found to be composed of a sharp Pr/Co valence and Co spin state transition centered at T*=89.3 K, followed by a smoother Co spin-state evolution at higher temperatures. At T < T*, we found that the praseodymium displays a mixed valence Pr3+/Pr4+ with about 0.13 Pr4+/f.u., while all the Co3+ is in the low-spin (LS) state. At T around T*, the sharp valence transition converts all the Pr4+ to Pr3+ with a corresponding Co3+ to Co4+ compensation. This is accompanied by an equally sharp spin state transition of the Co3+ from the low to an incoherent mixture of low and high spin (HS) states. An involvement of the intermediate spin (IS) state can be discarded for the Co3+. While above T* and at high temperatures the system shares rather similar properties as Sr-doped LaCoO3, at low temperatures it behaves much more like EuCoO3 with its highly stable LS configuration for the Co3+. Apparently, the mechanism responsible for the formation of Pr4+ at low temperatures also helps to stabilize the Co3+ in the LS configuration despite the presence of Co4+ ions. We also found out that that the Co4+ is in an IS state over the entire temperature range investigated in this study (10-290 K). The presence of Co3+ HS and Co4+ IS at elevated temperatures facilitates the conductivity of the material.Comment: 19 pages, 7 figures, Accepted in PR

Incommensurate spin correlations in highly oxidized cobaltates La2−x_{2-x}Srx_{x}CoO4_{4}

We observe quasi-static incommensurate magnetic peaks in neutron scattering experiments on layered cobalt oxides La2-xSrxCoO4 with high Co oxidation states that have been reported to be paramagnetic. This enables us to measure the magnetic excitations in this highly hole-doped incommensurate regime and compare our results with those found in the low-doped incommensurate regime that exhibit hourglass magnetic spectra. The hourglass shape of magnetic excitations completely disappears given a high Sr doping. Moreover, broad low-energy excitations are found, which are not centered at the incommensurate magnetic peak positions but around the quarter-integer values that are typically exhibited by excitations in the checkerboard charge ordered phase. Our findings suggest that the strong inter-site exchange interactions in the undoped islands are critical for the emergence of hourglass spectra in the incommensurate magnetic phases of La2-xSrxCoO4.Comment: http://www.nature.com/articles/srep25117

Can the Lepton Flavor Mixing Matrix Be Symmetric?

Current neutrino oscillation data indicate that the 3x3 lepton flavor mixing matrix V is likely to be symmetric about its V_{e3}-V_{\mu 2}-V_{\tau 1} axis. This off-diagonal symmetry corresponds to three pairs of {\it congruent} unitarity triangles in the complex plane. Terrestrial matter effects can substantially modify the genuine CP-violating parameter and off-diagonal asymmetries of V in realistic long-baseline experiments of neutrino oscillations.Comment: RexTex 14 pages (4 PS figures). More discussions adde

Intricacies of the Co3+^{3+} spin state in Sr2_2Co0.5_{0.5}Ir0.5_{0.5}O4_4: an x-ray absorption and magnetic circular dichroism study

We report on a combined soft x-ray absorption and magnetic circular dichroism (XMCD) study at the Co-$L_{3,2}$ on the hybrid 3$d$/5$d$ solid state oxide Sr$_2$Co$_{0.5}$Ir$_{0.5}$O$_4$ with the K$_2$NiF$_4$ structure. Our data indicate unambiguously a pure high spin state $(S=2)$ for the Co$^{3+}$ (3$d^6$) ions with a significant unquenched orbital moment $L_z/2S_z=0.25$ despite the sizeable elongation of the CoO$_6$ octahedra. Using quantitative model calculations based on parameters consistent with our spectra, we have investigated the stability of this high spin state with respect to the competing low spin and intermediate spin states.Comment: 7 pages, 4 figure

Electronically highly cubic conditions for Ru in alpha-RuCl3

We studied the local Ru 4d electronic structure of alpha-RuCl3 by means of polarization dependent x-ray absorption spectroscopy at the Ru-L2,3 edges. We observed a vanishingly small linear dichroism indicating that electronically the Ru 4d local symmetry is highly cubic. Using full multiplet cluster calculations we were able to reproduce the spectra excellently and to extract that the trigonal splitting of the t2g orbitals is -12 $\pm10$ meV, i.e. negligible as compared to the Ru 4d spin-orbit coupling constant. Consistent with our magnetic circular dichroism measurements, we found that the ratio of the orbital and spin moments is 2.0, the value expected for a Jeff = 1/2 ground state. We have thus shown that as far as the Ru 4d local properties are concerned, alpha-RuCl3 is an ideal candidate for the realization of Kitaev physics

Resonant Enhancement of Charge Density Wave Diffraction in the Rare-Earth Tritellurides

We performed resonant soft X-ray diffraction on known charge density wave (CDW) compounds, rare earth tri-tellurides. Near the $M_5$ (3d - 4f) absorption edge of rare earth ions, an intense diffraction peak is detected at a wavevector identical to that of CDW state hosted on Te$_2$ planes, indicating a CDW-induced modulation on the rare earth ions. Surprisingly, the temperature dependence of the diffraction peak intensity demonstrates an exponential increase at low temperatures, vastly different than that of the CDW order parameter. Assuming 4f multiplet splitting due to the CDW states,we present a model to calculate X-ray absorption spectrum and resonant profile of the diffraction peak, agreeing well with experimental observations. Our results demonstrate a situation where the temperature dependence of resonant X-ray diffraction peak intensity is not directly related to the intrinsic behavior of the order parameter associated with the electronic order, but is dominated by the thermal occupancy of the valence states.Comment: 7 pages, 5 figure

The MSW Effect in Quantum Field Theory

We show in detail the general relationship between the Schr\"{o}dinger equation approach to calculating the MSW effect and the quantum field theoretical S-matrix approach. We show the precise form a generic neutrino propagator must have to allow a physically meaningful ``oscillation probability'' to be decoupled from neutrino production fluxes and detection cross-sections, and explicitly list the conditions---not realized in cases of current experimental interest---in which the field theory approach would be useful.Comment: 20 page REVTeX file, submitted to Phys. Rev.

Classical Nambu-Goldstone fields

It is shown that a Nambu-Goldstone (NG) field may be coherently produced by a large number of particles in spite of the fact that the NG bosons do not couple to flavor conserving scalar densities like $\bar{\psi}\psi$. If a flavor oscillation process takes place the phases of the pseudo-scalar or flavor violating densities of different particles do not necessarily cancel each other. The NG boson gets a macroscopic source whenever the total (spontaneously broken) quantum number carried by the source particles suffers a net increase or decrease in time. If the lepton numbers are spontaneously broken such classical NG (majoron) fields may significantly change the neutrino oscillation processes in stars pushing the observational capabilities of neutrino-majoron couplings down to $m_{\nu}/300$ GeV.Comment: 11 pages, updated, to appear in PR

Quantum interference with photon pairs created in spatially separated sources

We report on a quantum interference experiment to probe the coherence between two photons coming from non degenerate photon pairs at telecom wavelength created in spatially separated sources. The two photons are mixed on a beam splitter and we observe a reduction of up to 84% in the coincidence count rate when the photons are made indistinguishable. This experiment constitutes an important step towards the realization of quantum teleportation and entanglement swapping with independent sources.Comment: 5 pages, 2 figures, changes according to referee's comments, discussions partly rewritte