Using the object modeling system for hydrological model development and application

State of the art challenges in sustainable management of water resources have created demand for integrated, flexible and easy to use hydrological models which are able to simulate the quantitative and qualitative aspects of the hydrological cycle with a sufficient degree of certainty. Existing models which have been de-veloped to fit these needs are often constrained to specific scales or purposes and thus can not be easily adapted to meet different challenges. As a solution for flexible and modularised model development and application, the Object Modeling System (OMS) has been developed in a joint approach by the USDA-ARS, GPSRU (Fort Collins, CO, USA), USGS (Denver, CO, USA), and the FSU (Jena, Germany). The OMS provides a modern modelling framework which allows the implementation of single process components to be compiled and applied as custom tailored model assemblies. This paper describes basic principles of the OMS and its main components and explains in more detail how the problems during coupling of models or model components are solved inside the system. It highlights the integration of different spatial and temporal scales by their representation as spatial modelling entities embedded into time compound components. As an exam-ple the implementation of the hydrological model J2000 is discussed

The Financial Collapse Of The Milwaukee Public Museum

The 123-year old Milwaukee Public Museum, which had long been considered to be one of the top natural history museums in the country, found itself in dire financial straights in 2005. The museum had run large deficits for the past three years and had almost entirely eaten through its cash and long-term endowment. In June 2005 it was forced to lay off many of its experienced collections and research staff and had begun the process of preparing to sell off assets that were not a part of the “exhibit experience.”  Milwaukee County’s Chief Executive went so far as to suggest that the Museum’s celebrated 700-acre Tirimbina rain forest preserve in Costa Rica should be sold. How did this once renowned organization become a shell of its former self? What financial management and governance mistakes were made, if any, and how could this disaster have been prevented

The Diminishing Benefits Of Nae International Portfolio Diversification Following The 1997 Asian Financial Crisis

Nae international diversification has been fundamental to portfolio management over the past 30 years, but the benefits appear to be significantly diminished following the 1997 Asian financial crisis. Using monthly return data covering the period from 1970 through 2004, we found rising correlations between U.S. and international equity markets exceeding 0.85 since July 1997. Even the return correlation of emerging countries recently has reached almost 0.80. We also found a significant reduction in the variance of the international return correlation after the financial crisis. Portfolio managers should not expect to receive the same benefits from international portfolio diversification as that obtained prior to the Asian financial crisis

Advanced nickel-cadmium batteries for geosynchronous spacecraft

A nickel cadmium battery was developed that can be operated at 80 percent depth of discharge in excess of 10 years in a geosynchronous orbit application, and has about a 30 percent weight savings per spacecraft over present nickel cadmium batteries when used with a 1000 watts eclipse load. The approach used in the development was to replace nylon separators with inert polymer impregnated zirconia, use electrochemically deposited plates in place of conventional chemically precipitated ones, and use an additive to extend negative plate lifetime. The design has undergone extensive testing using both engineering and protoflight cell configurations

Multituberculates (Mammalia, Allotheria) From The Earliest Tiffanian (Late Paleocene) Douglass Quarry, Eastern Crazy Mountains Basin, Montana

http://deepblue.lib.umich.edu/bitstream/2027.42/49355/1/Vol 31 No10 final 11-15-06.pd

Synthetic, Spectroscopic and DFT Studies of Iron Complexes with Iminobenzo(semi)quinone Ligands: Implications for o-Aminophenol Dioxygenases

The oxidative CC bond cleavage of o-aminophenols by nonheme Fe dioxygenases is a critical step in both human metabolism (the kynurenine pathway) and the microbial degradation of nitroaromatic pollutants. The catalytic cycle of o-aminophenol dioxygenases (APDOs) has been proposed to involve formation of an FeII/O2/iminobenzosemiquinone complex, although the presence of a substrate radical has been called into question by studies of related ring-cleaving dioxygenases. Recently, we reported the first synthesis of an iron(II) complex coordinated to an iminobenzosemiquinone (ISQ) ligand, namely, [Fe(Tp)(tBuISQ)] (2 a; where Tp=hydrotris(3,5-diphenylpyrazol-1-yl)borate and tBuISQ is the radical anion derived from 2-amino-4,6-di-tert-butylphenol). In the current manuscript, density functional theory (DFT) calculations and a wide variety of spectroscopic methods (electronic absorption, Mössbauer, magnetic circular dichroism, and resonance Raman) were employed to obtain detailed electronic-structure descriptions of 2 a and its one-electron oxidized derivative [3 a]+. In addition, we describe the synthesis and characterization of a parallel series of complexes featuring the neutral supporting ligand tris(4,5-diphenyl-1-methylimidazol-2-yl)phosphine (TIP). The isomer shifts of about 0.97 mm s−1 obtained through Mössbauer experiments confirm that 2 a (and its TIP-based analogue [2 b]+) contain FeII centers, and the presence of an ISQ radical was verified by analysis of the absorption spectra in light of time-dependent DFT calculations. The collective spectroscopic data indicate that one-electron oxidation of the FeII–ISQ complexes yields complexes ([3 a]+ and [3 b]2+) with electronic configurations between the FeIII–ISQ and FeII–IBQ limits (IBQ=iminobenzoquinone), highlighting the ability of o-amidophenolates to access multiple oxidation states. The implications of these results for the mechanism of APDOs and other ring-cleaving dioxygenases are discussed

Reversible skew laurent polynomial rings and deformations of poisson automorphisms

A skew Laurent polynomial ring S = R[x(+/- 1); alpha] is reversible if it has a reversing automorphism, that is, an automorphism theta of period 2 that transposes x and x(-1) and restricts to an automorphism gamma of R with gamma = gamma(-1). We study invariants for reversing automorphisms and apply our methods to determine the rings of invariants of reversing automorphisms of the two most familiar examples of simple skew Laurent polynomial rings, namely a localization of the enveloping algebra of the two-dimensional non-abelian solvable Lie algebra and the coordinate ring of the quantum torus, both of which are deformations of Poisson algebras over the base field F. Their reversing automorphisms are deformations of Poisson automorphisms of those Poisson algebras. In each case, the ring of invariants of the Poisson automorphism is the coordinate ring B of a surface in F-3 and the ring of invariants S-theta of the reversing automorphism is a deformation of B and is a factor of a deformation of F[x(1), x(2), x(3)] for a Poisson bracket determined by the appropriate surface

Stormwater Best Management Practices Assessment for the City of Lincoln, Nebraska

The objective of this research was to assess BMP performance and implementation in Lincoln, Nebraska. In order to accomplish this objective, four tasks were established: sampling of stormwater runoff at eight sites located upstream of Holmes Lake, inspecting BMPs at construction sites in Lincoln, sampling and analysis of soil phosphorus levels in the Holmes Lake watershed, and conducting discussions with professionals involved with stormwater management in Lincoln. Based on the information collected during these tasks, several recommendations regarding the BMP assessment process are made including: recommendations for sampling site selection, an inexpensive flow monitoring method, and a rapid construction site BMP assessment protocol