10 research outputs found

    Terrestrial bitumen analogue of orgueil organic material demonstrates high sensitivity to usual HF-HCl treatment

    Get PDF
    The relationship between the chemical composition and the interlayer spacing (d002) of organic materials (OM's) is known for various terrestrial OM's. We improved this general trend by correlation with corresponding trend of natural solid bitumens (asphaltite-kerite-anthraxolite) up to graphite. Using the improved trend we identified bitumen analogs of carbonaceous chondrite OM's residued after HF-HCl treatment. Our laboratory experiment revealed that these analogs and, hence, structure and chemical composition of carbonaceous chondrite OM's are very sensitive to the HF-HCl treatment. So, usual extraction of OM from carbonaceous chondrites may change significantly structural and chemical composition of extracted OM

    Sierra Gorda 009: A New Member of the Metal-Rich G Chondrites Grouplet

    Full text link
    We investigated the metal-rich chondrite Sierra Gorda (SG) 009, a member of the new G chondrite grouplet (also including NWA 5492, GRO 95551). G chondrites contain 23% metal, very reduced silicates, and rare oxidized mineral phases (Mg-chromite, FeO-rich pyroxene). G chondrites are not related to CH-CB chondrites, based on bulk O, C, and N isotopic compositions, mineralogy, and geochemistry. G chondrites have no fine-grained matrix or matrix lumps enclosing hydrated material typical for CH-CB chondrites. G chondrites’ average metal compositions are similar to H chondrites. Siderophile and lithophile geochemistry indicates sulfidization and fractionation of the SG 009 metal and silicates, unlike NWA 5492 and GRO 95551. The G chondrites have average O isotopic compositions Δ17O'0‰ ranging between bulk enstatite (E) and ordinary (O) chondrites. An Al-rich chondrule from SG 009 has Δ17O'0‰ indicating some heterogeneity in oxygen isotopic composition of G chondrite components. SG 009’s bulk carbon and nitrogen isotopic compositions correspond to E and O chondrites. Neon isotopic composition reflects a mixture of cosmogenic and solar components, and cosmic ray exposure age of SG 009 is typical for O, E, and R chondrites. G chondrites are closely related to O, E, and R chondrites and may represent a unique metal-rich parent asteroid containing primitive and fractionated material from the inner solar system. Oxidizing and reducing conditions during SG 009 formation may be connected with a chemical microenvironment and possibly could indicate that G chondrites may have formed by a planetesimal collision resulting in the lack of matrix. © The Meteoritical Society, 2020.We thank M. Weisberg, H. Downes, an anonymous reviewer, and Associate Editor C. Goodrich, for their thoughtful reviews which helped to improve this paper. The authors thank Sasha Krot for very fruitful discussions. This work was supported by the Russian Fond of Basic Research no. 20-05-00117A, by Klaus Tschira Stiftung gGmbH, by the NASA Emerging Worlds program (80NSSC18K0595, MH), and we thank the National High Magnetic Field Laboratory, which is supported by National Science Foundation Cooperative Agreement No. DMR-1644779* and the State of Florida. This work was also supported?by the Project No. FEUZ-2020-0059 of the Ministry of Science and Higher Education of the Russian Federation. This study was a partial contribution to research theme no. 0137-2019-0002

    Sierra Gorda 009: A new member of the metal‐rich G chondrites grouplet

    No full text
    We investigated the metal‐rich chondrite Sierra Gorda (SG) 009, a member of the new G chondrite grouplet (also including NWA 5492, GRO 95551). G chondrites contain 23% metal, very reduced silicates, and rare oxidized mineral phases (Mg‐chromite, FeO‐rich pyroxene). G chondrites are not related to CH‐CB chondrites, based on bulk O, C, and N isotopic compositions, mineralogy, and geochemistry. G chondrites have no fine‐grained matrix or matrix lumps enclosing hydrated material typical for CH‐CB chondrites. G chondrites’ average metal compositions are similar to H chondrites. Siderophile and lithophile geochemistry indicates sulfidization and fractionation of the SG 009 metal and silicates, unlike NWA 5492 and GRO 95551. The G chondrites have average O isotopic compositions Δ17O>0‰ ranging between bulk enstatite (E) and ordinary (O) chondrites. An Al‐rich chondrule from SG 009 has Δ17O>0‰ indicating some heterogeneity in oxygen isotopic composition of G chondrite components. SG 009’s bulk carbon and nitrogen isotopic compositions correspond to E and O chondrites. Neon isotopic composition reflects a mixture of cosmogenic and solar components, and cosmic ray exposure age of SG 009 is typical for O, E, and R chondrites. G chondrites are closely related to O, E, and R chondrites and may represent a unique metal‐rich parent asteroid containing primitive and fractionated material from the inner solar system. Oxidizing and reducing conditions during SG 009 formation may be connected with a chemical microenvironment and possibly could indicate that G chondrites may have formed by a planetesimal collision resulting in the lack of matrix

    Noble Gases, Nitrogen and Carbon Isotopic Compositions of the Ghubara Meteorite, Revealed by Stepwise Combustion and Crushing Methods

    No full text
    The Ghubara meteorite contains abundant trapped gases in voids of highly retentive phases that can be released by stepwise crushing and thermal degassing. Their composition is dominated by the solar wind component and by radiogenic argon. We favor a scenario in which a large impact event on L-chondrite asteroid 470 Ma ago caused release, mobilization, fractionation and redistribution of accumulated gases on the Ghubara parent body. The Ghubara breccia was formed at that event and occluded trapped gases into the voids. The uncommonly high 20Ne/36Ar ratios of the analysed samples compared to the solar composition is considered to be due to trapping of gases released from surrounding rocks that lost light noble gases preferentially over the heavy ones. The 4He/20Ne and 4He/36Ar ratios, being as usually lower than in solar wind, gradually increase during stepped crushing, indicating non equilibrium distribution of the gases between the voids of different sizes that can be caused by the dynamics of the shock metamorphism process. The neon isotopic composition released by stepwise crushing and combustion is a mixture of two components: solar dominating trapped and cosmogenic Ne. The former component is mainly degassed in the initial crushing steps opening the large inclusions/voids, while the relative contribution of the latter, likely released from galactic cosmic ray produced tracks, increases with progressive crushing. During stepwise combustion the same trend in the release of the Ne components with increasing temperature is observed. The nitrogen and carbon abundances as well as their isotopic compositions in Ghubara are usual for ordinary chondrites. Most of nitrogen is chemically bounded and associated with carbon. The delivery time of Ghubara from the parent body asteroid to the Earth calculated from its exposure age is 9–28 Ma

    Chelyabinsk airburst, damage assessment, meteorite recovery, and characterization

    No full text
    The asteroid impact near the Russian city of Chelyabinsk on 15 February 2013 was the largest airburst on Earth since the 1908 Tunguska event, causing a natural disaster in an area with a population exceeding one million. Because it occurred in an era with modern consumer electronics, field sensors, and laboratory techniques, unprecedented measurements were made of the impact event and the meteoroid that caused it. Here, we document the account of what happened, as understood now, using comprehensive data obtained from astronomy, planetary science, geophysics, meteorology, meteoritics, and cosmochemistry and from social science surveys. A good understanding of the Chelyabinsk incident provides an opportunity to calibrate the event, with implications for the study of near-Earth objects and developing hazard mitigation strategies for planetary protectionGeoscience & EngineeringCivil Engineering and Geoscience

    Chelyabinsk airburst, damage assessment, meteorite recovery, and characterization

    No full text
    The asteroid impact near the Russian city of Chelyabinsk on 15 February 2013 was the largest airburst on Earth since the 1908 Tunguska event, causing a natural disaster in an area with a population exceeding one million. Because it occurred in an era with modern consumer electronics, field sensors, and laboratory techniques, unprecedented measurements were made of the impact event and the meteoroid that caused it. Here, we document the account of what happened, as understood now, using comprehensive data obtained from astronomy, planetary science, geophysics, meteorology, meteoritics, and cosmochemistry and from social science surveys. A good understanding of the Chelyabinsk incident provides an opportunity to calibrate the event, with implications for the study of near-Earth objects and developing hazard mitigation strategies for planetary protection
    corecore