590 research outputs found
Oxidation behavior of Co-25Cr and Co-35Cr alloys Topical report, 1 Nov. 1967 - 31 Mar. 1968
Oxidation characteristics of cobalt-chromium base alloy
Effect of Water Vapor on the Oxidation Behavior of the Eutectic High‐Temperature Alloy Mo‐20Si‐52.8Ti
Herein, the effect of water vapor on the oxidation resistance of the alloy Mo-20Si-52.8Ti (at%) is investigated. The alloy is oxidized in dry, wet, as well as in in situ changing atmospheres at 1100 C. The oxidation kinetics changes from nearly parabolic to linear if water vapor is present in oxidizing atmosphere. Under all conditions, the oxide scales consist of an outer TiO and a TiO─SiO duplex layer underneath. In wet atmosphere, the thicknesses of the two regions substantially increase indicating a severe ingress of water vapor. The inferior oxidation resistance in wet environment is primarily rationalized by the fast diffusion of HO through SiO
Laser clad and HVOF sprayed Stellite 6 coating in chlorine rich environment with KCI at 700 °C
Laser clads and HVOF coatings from a stellite 6 alloy (Co–Cr–W–C alloy) on 304 stainless steel substrates were exposed both bare and with KCl deposits in 500 ppm HCl with 5% O2 for 250 h at 700 C. SEM/EDX and PXRD analyses with Rietveld refinement were used for assessment of the attack and for analysis of the scales. The bare samples suffered from scale spallation and the scale was mostly composed of Cr2O3, CoCr2O4 and CoO, although due to dilution haematite (Fe2O3) was detected in the scale formed on the laser clad sample. A small amount of hydrated HCl was detected in bare samples. While the corrosion of the bare surfaces was limited to comparatively shallow depths and manifested by g and M7C3 carbide formation, the presence of KCl on the surface led to severe Cr depletion from the HVOF coating (to 1 wt%). Both inward and outward diffusion of elements occurred in the HVOF coating resulting in Kirdendall voids at the coating–steel interface. The laser clad sample performed significantly better in conditions of the KCl deposit-induced corrosion. In addition to the oxides, CoCl2 was detected in the HVOF sample and K3CrO4 was detected in the laser clad sample. Thermodynamic calculations and kinetic simulations were carried out to interpret the oxidation and diffusion behaviours of coatings
Thermal Diffusion and Quench Propagation in YBCO Pancake Coils Wound with ZnO-and Mylar Insulations
The thermal diffusion properties of several different kinds of YBCO
insulations and the quench properties of pancake coils made using these
insulations were studied. Insulations investigated include Nomex, Kapton, and
Mylar, as well as insulations based on ZnO, Zn2GeO4, and ZnO-Cu. Initially,
short stacks of YBCO conductors with interlayer insulation, epoxy, and a
central heater strip were made and later measured for thermal conductivity in
liquid nitrogen. Subsequently, three different pancake coils were made. The
first two were smaller, each using one meter total of YBCO tape present as four
turns around a G-10 former. One of these smaller coils used Mylar insulation
co-wound with the YBCO tape, the other used YBCO tape onto which ZnO based
insulation had been deposited. One larger coil was made which used 12 total
meters of ZnO-insulated tape and had 45 turns. The results for all short sample
and coil thermal conductivities were ~1-3 Wm-1K-1. Finally, quench propagation
velocity measurements were performed on the coils (77 K, self field) by
applying a DC current and then using a heater pulse to initiate a quench.
Normal zone propagation velocity (NZP) values were obtained for the coils both
in the radial direction and in the azimuthal direction. Radial NZP values
(0.05-0.7 mm/s) were two orders of magnitude lower than axial values (~14-17
mm/s). Nevertheless, the quenches were generally seen to propagate radially
within the coils, in the sense that any given layer in the coil is driven
normal by the layer underneath it.Comment: 58 pages, 5 tables, 16 fig
A family of oxide ion conductors based on the ferroelectric perovskite Na0.5Bi0.5TiO3
Oxide ion conductors find important technical applications in electrochemical devices such as solid-oxide fuel cells (SOFCs), oxygen separation membranes and sensors1, 2, 3, 4, 5, 6, 7, 8, 9. Na0.5Bi0.5TiO3 (NBT) is a well-known lead-free piezoelectric material; however, it is often reported to possess high leakage conductivity that is problematic for its piezo- and ferroelectric applications10, 11, 12, 13, 14, 15. Here we report this high leakage to be oxide ion conduction due to Bi-deficiency and oxygen vacancies induced during materials processing. Mg-doping on the Ti-site increases the ionic conductivity to ~0.01 S cm−1 at 600 °C, improves the electrolyte stability in reducing atmospheres and lowers the sintering temperature. This study not only demonstrates how to adjust the nominal NBT composition for dielectric-based applications, but also, more importantly, gives NBT-based materials an unexpected role as a completely new family of oxide ion conductors with potential applications in intermediate-temperature SOFCs and opens up a new direction to design oxide ion conductors in perovskite oxides
Effect of defects on reaction of NiO surface with Pb-contained solution
In order to understand the role of defects in chemical reactions, we used two types of samples, which are molecular beam epitaxy (MBE) grown NiO(001) film on Mg(001) substrate as the defect free NiO prototype and NiO grown on Ni(110) single crystal as the one with defects. In-situ observations for oxide-liquid interfacial structure and surface morphology were performed for both samples in water and Pb-contained solution using high-resolution X-ray reflectivity and atomic force microscopy. For the MBE grown NiO, no significant changes were detected in the high-resolution X-ray reflectivity data with monotonic increase in roughness. Meanwhile, in the case of native grown NiO on Ni(110), significant changes in both the morphology and atomistic structure at the interface were observed when immersed in water and Pb-contained solution. Our results provide simple and direct experimental evidence of the role of the defects in chemical reaction of oxide surfaces with both water and Pb-contained solution.ope
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