A simulation study of a chemical distribution system

Bibliography: leaf 60.There has been a great deal of interest recently in using the simulation approach to analyse and optimize industrial systems. Applications of simulation techniques in the South African field are however limited and there is an urgent need for further work. This thesis provides industry an illustrative example of a simulation model of a chemical distribution system. It is concerned with the handling of raw materials and products at the African Explosives and Chemical Industries (AECI), situated in Somerset West. The model objectives were threefold; firstly, to establish the application of the simulation concept in the distribution field; secondly, to analyse the whole distribution system and to provide the factory with thorough details on its distribution performance; and finally, to identify any potential future strategies to minimize distribution cost

Prevalence of X-ray variability in the Chandra Deep Field South

We studied the X-ray variability of sources detected in the Chandra Deep Field South (Giacconi et al. 2002), nearly all of which are low to moderate z AGN (Tozzi et al. 2001). We find that 45% of the sources with >100 counts exhibit significant variability on timescales ranging from a day up to a year. The fraction of sources found to be variable increases with observed flux, suggesting that >90% of all AGNs possess intrinsic variability. We also find that the fraction of variable sources appears to decrease with increasing intrinsic absorption; a lack of variability in hard, absorbed AGNs could be due to an increased contribution of reflected X-rays to the total flux. We do not detect significant spectral variability in the majority (~70%) of our sources. In half of the remaining 30%, the hardness ratio is anti-correlated with flux, mimicking the high/soft-low/hard states of galactic sources. The X-ray variability appears anti-correlated with the luminosity of the sources, in agreement with previous studies. High redshift sources, however, have larger variability amplitudes than expected from extrapolations of their low-z counterparts, suggesting a possible evolution in the accretion rate and/or size of the X-ray emitting region. Finally, we discuss some effects that may produce the observed decrease in the fraction of variable sources from z=0.5 out to z=2.Comment: 24 pages, including 15 figures and 1 table. In press on Ap

Simulation of preheating effects in shock wave experiments

We have analyzed the shock wave propagation experiments performed at LULI and presented at ECLIM'94. The targets were aluminium foils with thickness from 5 to 25 μm. Simulations were performed with the SARA-1D multigroup radiation code. We have shown a small level of preheating caused by the absorption of X-rays with energies close to the K-edge of aluminum. Several sets of opacities were used in order to study this effect, including experimental values for cold aluminum. Simulations show a small level of visible emission induced by X-ray preheating before the arrival of the shock

Evolution of interdisciplinarity in biodiversity science

The study of biodiversity has grown exponentially in the last thirty years in response to demands for greater understanding of the function and importance of Earth's biodiversity and finding solutions to conserve it. Here, we test the hypothesis that biodiversity science has become more interdisciplinary over time. To do so, we analyze 97,945 peer‐reviewed articles over a twenty‐two‐year time period (1990–2012) with a continuous time dynamic model, which classifies articles into concepts (i.e., topics and ideas) based on word co‐occurrences. Using the model output, we then quantify different aspects of interdisciplinarity: concept diversity, that is, the diversity of topics and ideas across subdisciplines in biodiversity science, subdiscipline diversity, that is, the diversity of subdisciplines across concepts, and network structure, which captures interactions between concepts and subdisciplines. We found that, on average, concept and subdiscipline diversity in biodiversity science were either stable or declining, patterns which were driven by the persistence of rare concepts and subdisciplines and a decline in the diversity of common concepts and subdisciplines, respectively. Moreover, our results provide evidence that conceptual homogenization, that is, decreases in temporal β concept diversity, underlies the observed trends in interdisciplinarity. Together, our results reveal that biodiversity science is undergoing a dynamic phase as a scientific discipline that is consolidating around a core set of concepts. Our results suggest that progress toward addressing the biodiversity crisis via greater interdisciplinarity during the study period may have been slowed by extrinsic factors, such as the failure to invest in research spanning across concepts and disciplines. However, recent initiatives such as the Intergovernmental Science‐Policy Platform on Biodiversity and Ecosystem Services (IPBES) may attract broader support for biodiversity‐related issues and hence interdisciplinary approaches to address scientific, political, and societal challenges in the coming years

Origin of Middle-Infrared Peaks in Cerium Compounds

We have demonstrated that the middle-infrared (mid-IR) peaks in the optical conductivity spectra of Ce$X_3$ ($X$ = Pd, Sn, In) can be explained by first-principle band structure calculation with the spin-orbit interaction. The mid-IR peak shapes in these materials are not identical to one another: CePd$_3$, CeSn$_3$, and CeIn$_3$ have a triple-peak structure, double-peak structure and broad single-peak structure, respectively. These peaks can be theoretically explained by the optical transition from the occupied state to the spin-orbit splitted Ce $4f$ state. This result indicates that the mid-IR peaks originate from the simple band picture with the Ce $4f$ state near the Fermi level, not from the conventional cf hybridization gap based on the periodic Anderson model.Comment: 5 pages, 6 figures. To be published in J. Phys. Soc. Jpn. 78(1) (2009

Decaying shock studies of phase transitions in MgOSiO2 systems: implications for the Super-Earths interiors

We report an experimental study of the phase diagrams of periclase (MgO), enstatite (MgSiO3) and forsterite (Mg2SiO4) at high pressures. We investigated with laser driven decaying shocks the pressure/temperature curves of MgO, MgSiO3 and Mg2SiO4 between 0.2-1.2 TPa, 0.12-0.5 TPa and 0.2-0.85 TPa respectively. A melting signature has been observed in MgO at 0.47 TPa and 9860 K, while no phase changes were observed neither in MgSiO3 nor in Mg2SiO4. An increasing of reflectivity of MgO, MgSiO3 and Mg2SiO4 liquids have been detected at 0.55 TPa -12 760 K, 0.15 TPa - 7540 K, 0.2 TPa - 5800 K, respectively. In contrast to SiO2, melting and metallization of these compounds do not coincide implying the presence of poor electrically conducting liquids close to the melting lines. This has important implications for the generation of dynamos in Super-earths mantles