199 research outputs found
Spectroscopic signatures of spin-charge separation in the quasi-one-dimensional organic conductor TTF-TCNQ
The electronic structure of the quasi-one-dimensional organic conductor
TTF-TCNQ is studied by angle-resolved photoelectron spectroscopy (ARPES). The
experimental spectra reveal significant discrepancies to band theory. We
demonstrate that the measured dispersions can be consistently mapped onto the
one-dimensional Hubbard model at finite doping. This interpretation is further
supported by a remarkable transfer of spectral weight as function of
temperature. The ARPES data thus show spectroscopic signatures of spin-charge
separation on an energy scale of the conduction band width.Comment: 4 pages, 4 figures; to appear in PR
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Effect of carrier gas on the surface of morphology and mosaic dispersion for GaN films by low-pressure MOCVD
Low-pressure metal-organic chemical vapor deposition (MOCVD) has been used to deposit unnucleated and self-nucleated GaN thin films on (00.1) sapphire substrates. For the self-nucleated films, initial layers were grown at 540{degrees}C using trimethylgallium and ammonia as elemental sources and either nitrogen or hydrogen as the carrier gas. Using these same gas phase conditions, overlayers on native (00.1) sapphire substrates or the GaN-nucleated (00.1) sapphire substrates were deposited at 1025{degrees}C. The surface morphology and mosaic dispersion of these unnucleated and self-nucleated GaN thin films have been surveyed by a combination of real space images from atomic force microscopy and reciprocal space intensity data from X-ray scattering measurements. As expected, the unnucleated GaN films show a large-grained hexagonal relief, typical of three-dimensional island growth. However, the self-nucleated films are shown to be dense mosaics of highly oriented islands, emblematic of a more two-dimensional growth
Surface characterization and surface electronic structure of organic quasi-one-dimensional charge transfer salts
We have thoroughly characterized the surfaces of the organic charge-transfer
salts TTF-TCNQ and (TMTSF)2PF6 which are generally acknowledged as prototypical
examples of one-dimensional conductors. In particular x-ray induced
photoemission spectroscopy turns out to be a valuable non-destructive
diagnostic tool. We show that the observation of generic one-dimensional
signatures in photoemission spectra of the valence band close to the Fermi
level can be strongly affected by surface effects. Especially, great care must
be exercised taking evidence for an unusual one-dimensional many-body state
exclusively from the observation of a pseudogap.Comment: 11 pages, 12 figures, v2: minor changes in text and figure labellin
Effect of nearest neighbor repulsion on the low frequency phase diagram of a quarter-filled Hubbard-Holstein chain
We have studied the influence of nearest-neighbor (NN) repulsion on the low
frequency phase diagram of a quarter-filled Hubbard-Holstein chain. The NN
repulsion term induces the apparition of two new long range ordered phases (one
CDW for positive and one CDW for
negative ) that did not exist in the V=0 phase diagram. These results
are put into perspective with the newly observed charge ordered phases in
organic conductors and an interpretation of their origin in terms of
electron-molecular vibration coupling is suggested.Comment: 10 pages, 10 figure
Electronic structure of the quasi-one-dimensional organic conductor TTF-TCNQ
We study the electronic structure of the quasi-one-dimensional organic
conductor TTF-TCNQ by means of density-functional band theory, Hubbard model
calculations, and angle-resolved photoelectron spectroscopy (ARPES). The
experimental spectra reveal significant quantitative and qualitative
discrepancies to band theory. We demonstrate that the dispersive behavior as
well as the temperature-dependence of the spectra can be consistently explained
by the finite-energy physics of the one-dimensional Hubbard model at metallic
doping. The model description can even be made quantitative, if one accounts
for an enhanced hopping integral at the surface, most likely caused by a
relaxation of the topmost molecular layer. Within this interpretation the ARPES
data provide spectroscopic evidence for the existence of spin-charge separation
on an energy scale of the conduction band width. The failure of the
one-dimensional Hubbard model for the {\it low-energy} spectral behavior is
attributed to interchain coupling and the additional effect of electron-phonon
interaction.Comment: 18 pages, 9 figure
Scanning Tunneling Microscopy in TTF-TCNQ :direct proof of phase and amplitude modulated charge density waves
Charge density waves (CDW) have been studied at the surface of a cleaved
TTF-TCNQ single crystal using a low temperature scanning tunneling microscope
(STM) under ultra high vacuum (UHV) conditions. All CDW phase transitions of
TTF-TCNQ have been identified. The measurement of the modulation wave vector
along the a direction provides the first evidence for the existence of domains
comprising single plane wave modulated structures in the temperature regime
where the transverse wave vector of the CDW is temperature dependent, as hinted
by the theory more than 20 years ago.Comment: To appear in Phys.Rev.Rapid. Com
Mechanisms of ring chromosome formation, ring instability and clinical consequences
<p>Abstract</p> <p>Background</p> <p>The breakpoints and mechanisms of ring chromosome formation were studied and mapped in 14 patients.</p> <p>Methods</p> <p>Several techniques were performed such as genome-wide array, MLPA (Multiplex Ligation-Dependent Probe Amplification) and FISH (Fluorescent <it>in situ </it>Hybridization).</p> <p>Results</p> <p>The ring chromosomes of patients I to XIV were determined to be, respectively: r(3)(p26.1q29), r(4)(p16.3q35.2), r(10)(p15.3q26.2), r(10)(p15.3q26.13), r(13)(p13q31.1), r(13)(p13q34), r(14)(p13q32.33), r(15)(p13q26.2), r(18)(p11.32q22.2), r(18)(p11.32q21.33), r(18)(p11.21q23), r(22)(p13q13.33), r(22)(p13q13.2), and r(22)(p13q13.2). These rings were found to have been formed by different mechanisms, such as: breaks in both chromosome arms followed by end-to-end reunion (patients IV, VIII, IX, XI, XIII and XIV); a break in one chromosome arm followed by fusion with the subtelomeric region of the other (patients I and II); a break in one chromosome arm followed by fusion with the opposite telomeric region (patients III and X); fusion of two subtelomeric regions (patient VII); and telomere-telomere fusion (patient XII). Thus, the r(14) and one r(22) can be considered complete rings, since there was no loss of relevant genetic material. Two patients (V and VI) with r(13) showed duplication along with terminal deletion of 13q, one of them proved to be inverted, a mechanism known as inv-dup-del. Ring instability was detected by ring loss and secondary aberrations in all but three patients, who presented stable ring chromosomes (II, XIII and XIV).</p> <p>Conclusions</p> <p>We concluded that the clinical phenotype of patients with ring chromosomes may be related with different factors, including gene haploinsufficiency, gene duplications and ring instability. Epigenetic factors due to the circular architecture of ring chromosomes must also be considered, since even complete ring chromosomes can result in phenotypic alterations, as observed in our patients with complete r(14) and r(22).</p
Transport Properties of some Deprivatives of Tetrathiafulvalenetetracyano-p-quinodimethane (TTF-TCNQ)
Optical and infrared properties of tetramethyltetraselenafulvalene [(TMTSF)2X] and tetramethyltetrathiafulvalene [(TMTTF)2X] compounds
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