Soil Salinity Study in Northern Great Plains Sodium Affected Soil

Climate and land-use changes when combined with the marine sediments that underlay portions of the Northern Great Plains have increased the salinization and sodification risks. The objectives of this dissertation were to compare three chemical amendments (calcium chloride, sulfuric acid and gypsum) remediation strategies on water permeability and sodium (Na) transport in undisturbed soil columns and to develop a remote sensing technique to characterize salinization in South Dakota soils. Fortyeight undisturbed soil columns (30 cm x 15 cm) collected from White Lake, Redfield, and Pierpont were used to assess the chemical remediation strategies. In this study the experimental design was a completely randomized design and each treatment was replicated four times. Following the application of chemical remediation strategies, 45.2 cm of water was leached through these columns. The leachate was separated into 120- ml increments and analyzed for Na and electrical conductivity (EC). Sulfuric acid increased Na leaching, whereas gypsum and CaCl2 increased water permeability. Our results further indicate that to maintain effective water permeability, ratio between soil EC and sodium absorption ratio (SAR) should be considered. In the second study, soil samples from 0-15 cm depth in 62 x 62 m grid spacing were taken from the South Dakota Pierpont (65 ha) and Redfield (17 ha) sites. Saturated paste EC was measured on each soil sample. At each sampling points reflectance and derived indices (Landsat 5, 7, 8 images), elevation, slope and aspect (LiDAR) were extracted. Regression models based on multiple linear regression, classification and regression tree, cubist, and random forest techniques were developed and their ability to predict soil EC were compared. Results showed that: 1) Random forest method was found to be the most effective method because of its ability to capture spatially correlated variation, 2) the short wave infrared (1.5 -2.29 μm) and near infrared (0.75-0.90 μm) were very sensitive to soil salinity; 3) EC prediction model using all 3 season (spring, summer and fall) images was better on state wide validation dataset compared to individual season model. Finally, in eastern South Dakota, the model predicted that from 2008 to 2012, EC increased in 569,165 ha or 13.4% of the land seeded to corn (Zea mays L.) or soybeans (Glycine max L)

Structural and magnetic properties of Pr-alloyed MnBi nanostructures

The structural and magnetic properties of Pr-alloyed MnBi (short MnBi-Pr) nanostructures with a range of Pr concentrations have been investigated. The nanostructures include thin films having Pr concentrations 0, 2, 3, 5 and 9 atomic percent and melt-spun ribbons having Pr concentrations 0, 2, 4 and 6 percent respectively. Addition of Pr into the MnBi lattice has produced a significant change in the magnetic properties of these nanostructures including an increase in coercivity and structural phase transition temperature, and a decrease in saturation magnetization and anisotropy energy. The highest value of coercivity measured in the films is 23 kOe and in the ribbons is 5.6 kOe. The observed magnetic properties are explained as the consequences of competing ferromagnetic and antiferromagnetic interactions

Non-linear Microwave Surface Impedance of Epitaxial HTS Thin Films in Low DC Magnetic Fields

We have carried out non-linear microwave (8 GHz) surface impedance measurements of three YBaCuO thin films in dc magnetic fields $H_{dc}$ (parallel to c axis) up to 12 mT using a coplanar resonator technique. In zero dc field the three films, deposited by the same method, show a spread of low-power residual surface resistance, $R_{res}$ and penetration depth, $\lambda$ (T=15 K) within a factor of 1.9. However, they exhibit dramatically different microwave field, $H_{rf}$ dependences of the surface resistance, $R_s$, but universal $X_s(H_{rf})$ dependence. Application of a dc field was found to affect not only absolute values of $R_s$ and $X_s$, but the functional dependences $R_s(H_{rf})$ and $X_s(H_{rf})$ as well. For some of the samples the dc field was found to decrease $R_s$ below its zero-field low-power value.Comment: 4 pages, 4 figures. To be published in IEEE Trans. Appl. Supercond., June 199

Renal Transplantation and Pregnancy

Introduction: Although pregnancy after kidney transplantation is feasible, complications are relatively common and this needs to be considered in patient counseling and clinical decision making.Review: Fertility generally returns after renal transplantation. Approximately 74% of pregnancies in kidney transplant recipients end successfully in life births. Published reports suggest that pregnancy has no adverse affects on graft survival although patients with higher pre-pregnancy serum creatinine have a trend toward increased post-pregnancy serum creatinine. There is, however, a significantly increased risk of preeclampsia, gestational diabetes, cesarean section and preterm delivery compared to the general population. Almost half life births are preterm, and low birth weight is very common. Immunosuppressive medications are required to be continued during pregnancy in transplant recipients to prevent graft rejection, except for  sirolimus and mycophenolate mofetil (MMF) which are contraindicated during pregnancy. The incidence of birth defects in the live born is similar to the general population, except for pregnancies exposed to MMF which have a high incidence of birth defects. Every female in the reproductive age group should be counseled regarding pregnancy including the potential risks to the graft, to the mother and to the child. Timing pregnancy should be based upon whether graft function is optimal, but the general recommendation is to wait one year post transplantation before conception.Conclusion: Pregnancy in renal transplant patients should be planned with combined care from surgeons, nephrologists, obstetricians, pediatricians and dietitians which offers the best chance of a favorable outcome in the mother and the fetus

Effect of disorder on the resistivity of CoFeCrAl films

Structural and electron-transport properties of thin films of the ferrimagnetic Heusler compound CoFeCrAl have been investigated to elucidate structure-property relationships. The alloy is, ideally, a spin-gapless semiconductor, but structural disorder destroys the spin-gapless character and drastically alters the transport behavior. Two types of CoFeCrAl films were grown by magnetron sputtering deposition at 973 K, namely polycrystalline films on Si substrates and epitaxial films on MgO (001) substrates. The resistivity decreases with increasing temperature, with relatively small temperature coefficients of –0.19 cm=K for the polycrystalline films and –0.12 cm=K for the epitaxial films. The residual resistivity of the polycrystalline films deposited on Si is higher than that of the epitaxial film deposited on MgO, indicating that the polycrystalline films behave as socalled dirty metals

Ferromagnetism at 300 K in spin-coated films of Co doped anatase and rutile TiO2

Thin films of Ti1-xCoxO2 (x=0 and 0.03) have been prepared on sapphire substrates by spin-on technique starting from metalorganic precursors. When heat treated in air at 550 and 700 C respectively, these films present pure anatase and rutile structures as shown both by X-ray diffraction and Raman spectroscopy. Optical absorption indicate a high degree of transparency in the visible region. Such films show a very small magnetic moment at 300 K. However, when the anatase and the rutile films are annealed in a vacuum of 1x10-5 Torr at 500 oC and 600 oC respectively, the magnetic moment, at 300 K, is strongly enhanced reaching 0.36 B/Co for the anatase sample and 0.68 B/Co for the rutile one. The ferromagnetic Curie temperature of these samples is above 350 K.Comment: 31 july 200