Ecotoxicity and fungal deterioration of recycled polypropylene/wood composites: Effect of wood content and coupling

Polypropylene (PP)/wood composites were produced by homogenization in a twin-screw extruder and injection molding of tensile bars. Their mechanical properties were determined before and after exposure to biological treatment, and the effect of the treatment was assessed by various ways including visual inspection and the measurement of weight loss. The ecotoxicity of the materials was also evaluated by using the bioluminescent bacteria Vibrio fischeri. The results proved that wood facilitates biodeterioration (colonization) under the conditions used. The coupling agents do not have inhibitory effect, but seems to stimulate fungal growth (biodeterioration) at large loads of wood flour. PP/wood composites can be considered quite durable, but the influence of wood content on environmental resistance must be taken into account for materials intended for applications requiring long-term outdoor exposure as the time of exposure to microbial colonization increases. Direct ecotoxic effect on aquatic ecosystems cannot be expected from PP/wood composites

Effect of particle size, coupling agent and DDGS additions on Paulownia wood polypropylene composites

Studies aimed at improving the tensile, flexural, impact, thermal, and physical characteristics of wood–plastic composites composed of Paulownia wood flour derived from 36-month-old trees blended with polypropylene were conducted. Composites of 25% and 40% w/w of Paulownia wood were produced by twin-screw compounding and injection molding. Composites containing 0–10% by weight of maleated polypropylene were evaluated and an optimum maleated polypropylene concentration determined, i.e., 5%. The particle size distribution of Paulownia wood filler is shown to have an effect on the tensile and flexural properties of the composites. Novel combination composites of dried distiller’s grain with solubles mixed with Paulownia wood (up to 40% w/w) were produced and their properties evaluated. Depending on the composite tested, soaking composites for 872 h alters mechanical properties and causes weight gain

Tensile and impact properties of three-component PP/wood/elastomer composites

Polypropylene (PP) was reinforced with wood flour and impact modified with elastomers to increase stiffness and impact resistance simultaneously. Elastomer content changed in four (0, 5, 10 and 20 wt%), while that of wood content in seven steps, the latter from 0 to 60 wt% in 10 wt% steps. Structure and adhesion were controlled by the addition of functionalized (maleated) polymers. Composites were homogenized in a twin-screw extruder and then injection molded to tensile bars. Fracture resistance was characterized by standard and instrumented impact tests. The results showed that the components are dispersed independently of each other even when a functionalized elastomer is used for impact modification, at least under the conditions of this study. Impact resistance does not change much as a function of wood content in PP/wood composites, but decreases drastically from the very high level of the PP/elastomer blend to almost the same value obtained without impact modifier in the three-component materials. Increasing stiffness and fiber related local deformation processes led to small fracture toughness at large wood content. Micromechanical deformation processes depend mainly on the strength of PP/wood interaction; debonding and pull-out take place at poor adhesion, while fiber fracture dominates when adhesion is strong. Composites with sufficiently large impact resistance cannot be prepared in the usual range of wood contents (50–60 wt%)