Cycloadditionsreaktionen von Allenyl-Kationen mit Cyclopentadien

Propargylhalogenide R1 C C CR2R3X (14) und Cyclopentadien reagieren in Gegenwart von Zinkhalogeniden in Ether/Dichlormethan unter Bildung von 3-Halogenbicyclo[3.2.1]octa-2,6-dienen 13 (R1 = Alkyl) oder 5-(-Halogenbenzyliden)norbornenen 15 (R1 = Aryl). Die Reaktionen werden durch stufenweise [3 + 4]- bzw. [2 + 4]-Cycloadditionen intermediärer Allenyl-Kationen 1 erklärt, wobei die Propargylcyclopentenyl-Kationen 5 sowie die bicyclischen Vinyl-Kationen 9 oder 12 als Zwischenstufen durchlaufen werden. Initiiert man diese Reaktionen durch äquimolare Mengen Silbertrifluoracetat, lassen sich Abfangprodukte aller postulierten Zwischenstufen isolieren. Die relativen Energieinhalte der intermediären Carbenium-Ionen werden mit Hilfe von Kraftfeldrechnungen unter Verwendung von Gasphasenstabilitäten einfacher Carbokationen ermittelt. Stereochemische Untersuchungen zeigen, daß die Additionsreaktionen den kompakten Übergangszustand 42 gegenüber 41 bevorzugen. Bei der Umsetzung des Propargylchlorids 14e mit Cyclopentadien erhält man unter Zinkchloridkatalyse außer dem 1:1-Produkt 15e noch ein pentacyclisches 2:1-Produkt 17, das durch Röntgenstrukturanalyse aufgeklärt wurde. Seine Bildung läßt sich durch [2 + 2]-Cycloaddition eines Allenyl-Kations mit Cyclopentadien erklären

W-algebras with set of primary fields of dimensions (3, 4, 5) and (3,4,5,6)

We show that that the Jacobi-identities for a W-algebra with primary fields of dimensions 3, 4 and 5 allow two different solutions. The first solution can be identified with WA_4. The second is special in the sense that, even though associative for general value of the central charge, null-fields appear that violate some of the Jacobi-identities, a fact that is usually linked to exceptional W-algebras. In contrast we find for the algebra that has an additional spin 6 field only the solution WA_5.Comment: 17 pages, LaTeX, KCL-TH-92-9, DFFT-70/9

Classification of Structure Constants for W-algebras from Highest Weights

We show that the structure constants of W-algebras can be grouped according to the lowest (bosonic) spin(s) of the algebra. The structure constants in each group are described by a unique formula, depending on a functional parameter h(c) that is characteristic for each algebra. As examples we give the structure constants C_{33}^4 and C_{44}^4 for the algebras of type W(2,3,4,...) (that include the WA_{n-1}-algebras) and the structure constant C_{44}^4 for the algebras of type W(2,4,...), especially for all the algebras WD_n, WB(0,n), WB_n and WC_n. It also includes the bosonic projection of the super-Virasoro algebra and a yet unexplained algebra of type W(2,4,6) found previously.Comment: 18 pages (A4), LaTeX, DFTT-40/9

Unifying W-Algebras

We show that quantum Casimir W-algebras truncate at degenerate values of the central charge c to a smaller algebra if the rank is high enough: Choosing a suitable parametrization of the central charge in terms of the rank of the underlying simple Lie algebra, the field content does not change with the rank of the Casimir algebra any more. This leads to identifications between the Casimir algebras themselves but also gives rise to new, `unifying' W-algebras. For example, the kth unitary minimal model of WA_n has a unifying W-algebra of type W(2,3,...,k^2 + 3 k + 1). These unifying W-algebras are non-freely generated on the quantum level and belong to a recently discovered class of W-algebras with infinitely, non-freely generated classical counterparts. Some of the identifications are indicated by level-rank-duality leading to a coset realization of these unifying W-algebras. Other unifying W-algebras are new, including e.g. algebras of type WD_{-n}. We point out that all unifying quantum W-algebras are finitely, but non-freely generated.Comment: 13 pages (plain TeX); BONN-TH-94-01, DFTT-15/9

Optical Spectroscopy of IRAS 02091+6333

We present a detailed spectroscopic investigation, spanning four winters, of the asymptotic giant branch (AGB) star IRAS 02091+6333. Zijlstra & Weinberger (2002) found a giant wall of dust around this star and modelled this unique phenomenon. However their work suffered from the quality of the optical investigations of the central object. Our spectroscopic investigation allowed us to define the spectral type and the interstellar foreground extinction more precisely. Accurate multi band photometry was carried out. This provides us with the possibility to derive the physical parameters of the system. The measurements presented here suggest a weak irregular photometric variability of the target, while there is no evidence of a spectroscopic variability over the last four years.Comment: 5 pages, Latex, 3 tables, 4 figures, Astron. & Astrophys. - in pres

W-Algebras of Negative Rank

Recently it has been discovered that the W-algebras (orbifold of) WD_n can be defined even for negative integers n by an analytic continuation of their coupling constants. In this letter we shall argue that also the algebras WA_{-n-1} can be defined and are finitely generated. In addition, we show that a surprising connection exists between already known W-algebras, for example between the CP(k)-models and the U(1)-cosets of the generalized Polyakov-Bershadsky-algebras.Comment: 12 papes, Latex, preprint DFTT-40/9

Generalized twisted modules associated to general automorphisms of a vertex operator algebra

We introduce a notion of strongly C^{\times}-graded, or equivalently, C/Z-graded generalized g-twisted V-module associated to an automorphism g, not necessarily of finite order, of a vertex operator algebra. We also introduce a notion of strongly C-graded generalized g-twisted V-module if V admits an additional C-grading compatible with g. Let V=\coprod_{n\in \Z}V_{(n)} be a vertex operator algebra such that V_{(0)}=\C\one and V_{(n)}=0 for n<0 and let u be an element of V of weight 1 such that L(1)u=0. Then the exponential of 2\pi \sqrt{-1} Res_{x} Y(u, x) is an automorphism g_{u} of V. In this case, a strongly C-graded generalized g_{u}-twisted V-module is constructed from a strongly C-graded generalized V-module with a compatible action of g_{u} by modifying the vertex operator map for the generalized V-module using the exponential of the negative-power part of the vertex operator Y(u, x). In particular, we give examples of such generalized twisted modules associated to the exponentials of some screening operators on certain vertex operator algebras related to the triplet W-algebras. An important feature is that we have to work with generalized (twisted) V-modules which are doubly graded by the group C/Z or C and by generalized eigenspaces (not just eigenspaces) for L(0), and the twisted vertex operators in general involve the logarithm of the formal variable.Comment: Final version to appear in Comm. Math. Phys. 38 pages. References on triplet W-algebras added, misprints corrected, and expositions revise

A differential U-module algebra for U=U_q sl(2) at an even root of unity

We show that the full matrix algebra Mat_p(C) is a U-module algebra for U = U_q sl(2), a 2p^3-dimensional quantum sl(2) group at the 2p-th root of unity. Mat_p(C) decomposes into a direct sum of projective U-modules P^+_n with all odd n, 1<=n<=p. In terms of generators and relations, this U-module algebra is described as the algebra of q-differential operators "in one variable" with the relations D z = q - q^{-1} + q^{-2} z D and z^p = D^p = 0. These relations define a "parafermionic" statistics that generalizes the fermionic commutation relations. By the Kazhdan--Lusztig duality, it is to be realized in a manifestly quantum-group-symmetric description of (p,1) logarithmic conformal field models. We extend the Kazhdan--Lusztig duality between U and the (p,1) logarithmic models by constructing a quantum de Rham complex of the new U-module algebra.Comment: 29 pages, amsart++, xypics. V3: The differential U-module algebra was claimed quantum commutative erroneously. This is now corrected, the other results unaffecte