6 research outputs found
Phase transformations in CdSe quantum dots induced by reaction time
This paper reports the synthesis of high-quality TOP/TOPO capped CdSe nanocrystals using a simple colloidal method. The effects of varying the reaction time on the size and crystallinity of the synthesized CdSe quantum dots were studied in detail. Powder X-ray diffraction (PXRD) analysis showed a dependence of the crystallite phases as a function of reaction time, from cubic zinc-blende to hexagonal wurtzite and back again to the cubic phase. PXRD data was found to be consistent with high resolution transmission electron microscopy (HRTEM) images of the particles, whilst optical spectroscopy demonstrated the quantum dot nature of the particles. The reaction time-dependent phase behavior is best accounted for by rapid growth along the {111} crystallite facets, after which the facial facets then 'catch-up', resulting once again in cubic symmetry.3 page(s
La<sub>2</sub>O<sub>3</sub> Promoted Pd/rGO Electro-catalysts for Formic Acid Oxidation
High activity, a low rate of CO poisoning,
and long-term stability of Pd electro-catalysts are necessary for
practical use as an anode material in direct formic acid fuel cells.
Achieving a high degree of Pd nanoparticle dispersion on a carbon
support, without agglomeration, while maintaining a facile electron
transfer through the catalyst surface are two challenging tasks to
be overcome in fulfilling this aim. Herein, we report the effect of
addition of La/La-oxides on the efficiency of Pd nanoparticles supported
on reduced graphene oxide (rGO) for formic acid electro-oxidation
reaction. A series of electro-catalysts with different Pd–La
molar ratios were successfully synthesized and characterized using
a range of techniques including PXRD, XPS, TEM, FTIR, and Raman spectroscopy
and then tested as anode materials for direct formic acid fuel cells.
We explore that the lanthanum species (La/La-oxide) significantly
promote the activity and stability of Pd catalyst toward electrocatalytic
oxidation of formic acid. The metallic ratio is found to be critical,
and the activity order of various catalysts is observed as follows;
Pd<sub>30</sub>La<sub>70</sub>/rGO > Pd<sub>80</sub>La<sub>20</sub>/rGO > Pd<sub>70</sub>La<sub>30</sub> rGO. The obtained mass specific
activity for Pd<sub>30</sub>La<sub>70</sub>/rGO (986.42 A/g) is 2.18
times higher than that for Pd/rGO (451 A/g) and 16 times higher than
that for Pd/C (61.5 A/g) at given onset peak potentials. The high
activity and stability of the electro-catalysts are attributed to
the uniform dispersion of Pd nanoparticles over the rGO support, as
evidenced from TEM images. It is believed that the role of La species
in promoting the catalyst activity is to disperse the catalyst particles
during synthesis and to facilitate the electron transfer via providing
a suitable pathway during electrochemical testing
Latent fingermark detection using functionalised silicon oxide nanoparticles: Optimisation and comparison with cyanoacrylate fuming
Synthesis and characterization of organic-inorganic hybrid materials prepared by sol-gel and containing ZnxCd1-xS nanoparticles prepared by a colloidal method
Nanocomposite materials based on a hybrid organic–inorganic ureasilicate matrix doped with ZnxCd1 xS
nanoparticles were prepared. ZnxCd1 xS nanoparticles with different compositions (Zn/Cd mole ratio)
were prepared through a colloidal method using reverse micelles. Previously to dispersion within the
matrix precursors used to prepare the hybrid gel composite, the nanoparticles surface was modified in
order to improve compatibility and stability with the matrix and to assure the preservation of the
original optical properties of the nanoparticles. The matrix was obtained by the reaction between a
silicon alkoxide modified by an isocyanate group and a di-amine functionalized oligopolyoxyethylene
(Jeffamine ED-600), which by subsequent hydrolysis and condensation reactions formed a mechanically
stable and highly transparent solid network containing the ZnxCd1 xS nanoparticles. The materials were
characterized by absorption, steady-state and time-resolved photoluminescence spectroscopy and by
HRTEM. The obtained nanocomposites show a high transparency in the visible range accounting for the
good dispersion of the nanoparticles within the matrix. The results obtained confirmed the preservation of
the original optical properties of the nanoparticles after their incorporation into the ureasilicate matrix,
showing that the developed method is suitable for the production of materials with potential applications
in which it is necessary to take advantage of the optical properties of the nanoparticles incorporated. The
HRTEM analysis confirmed that the dispersed nanoparticles show a high level of crystallinization.This work has been partially supported by the Fundacao para a Ciencia e a Tecnologia (FCT). L.F. Goncalves thanks the FCT for the PhD grant SFRH/BD/38262/2007. The authors gratefully acknowledge the financial support by Centro de Quimica [project F-COMP-01-0124-FEDER-022716 (ref. FCT Pest-C/Qui/UI0686/2011)-FEDER-COMPETE] and Centro de Fisica (Universidade do Minho). The authors would like to thank the Electron Microscope Unit of the Mark Wainwright Analytical Centre at The University of New South Wales, for scientific and technical suppor
Synthesis and characterization of organic-inorganic hybrid materials prepared by sol-gel and containing CdS nanoparticles prepared by a colloidal method using poly(N-vinyl-2-pyrrolidone)
This paper describes the synthesis and characterization
of CdS nanoparticles (NPs) stabilized with
poly(N-vinyl-2-pyrrolidone) and their further immobilization
on a hybrid organic–inorganic matrix produced by the
sol–gel process. The production of the hybrid matrix doped
with CdS NPs was carried out in two steps. In the first step
a precursor, designated diureasil precursor, was synthesized
from the reaction between the terminal amine groups
of a,x-diamine-poly(oxyethylene-co-oxypropylene) and
the isocyanate group of 3-isocyanatopropyltriethoxysilane.
The next step involved the hydrolysis and condensation
reactions of ethoxy groups attached to silicon, this step
resulting in the formation of a crosslinked siliceous network
linked through urea bonds to a poly(oxyethylene)/
poly(oxypropylene) chain. The NPs were added to the
diureasil precursor before the gelation process to allow a
homogeneous dispersion of the NPs within the matrix. The
developed method allowed the transfer of colloidal NPs to
a solid matrix without the need of exchange the capping
agents or the solvent. The materials were characterized by
absorption, steady-state photoluminescence spectroscopy
and by TEM. The results obtained showed the presence of
CdS NPs with quantum size effect dispersed within the diureasil matrix. The obtained nanocomposites show a high
transparency in the visible range accounting for the good
dispersion of the NPs within the matrix. The TEM analysis
confirmed that the NPs are uniformly dispersed within the
diureasil matrix.This work has been partially supported by the Fundação para a Ciência e a Tecnologia (FCT). L. F. Gonçalves
thanks the FCT for the PhD grant SFRH/BD/38262/2007. The authors gratefully acknowledge the financial support by Centro de QuĂmica [project F-COMP-01-0124-FEDER-022716 (ref. FCT Pest-C/Qui/UI0686/2011)-FEDER-COMPETE] and Centro de FĂsica (Universidade do Minho). The authors would like to thank the Electron Microscope Unit of the Mark Wainwright Analytical Centre at The University of New South Wales, for scientific and technical support