Defect healing at room temperature in pentacene thin films and improved transistor performance

We report on a healing of defects at room temperature in the organic semiconductor pentacene. This peculiar effect is a direct consequence of the weak intermolecular interaction which is characteristic of organic semiconductors. Pentacene thin-film transistors were fabricated and characterized by in situ gated four-terminal measurements. Under high vacuum conditions (base pressure of order 10E-8 mbar), the device performance is found to improve with time. The effective field-effect mobility increases by as much as a factor of two and mobilities up to 0.45 cm2/Vs were achieved. In addition, the contact resistance decreases by more than an order of magnitude and there is a significant reduction in current hysteresis. Oxygen/nitrogen exposure and annealing experiments show the improvement of the electronic parameters to be driven by a thermally promoted process and not by chemical doping. In order to extract the spectral density of trap states from the transistor characteristics, we have implemented a powerful scheme which allows for a calculation of the trap densities with high accuracy in a straightforward fashion. We show the performance improvement to be due to a reduction in the density of shallow traps <0.15 eV from the valence band edge, while the energetically deeper traps are essentially unaffected. This work contributes to an understanding of the shallow traps in organic semiconductors and identifies structural point defects within the grains of the polycrystalline thin films as a major cause.Comment: 13 pages, 13 figures, to be published in Phys. Rev.

Direct numerical simulation of homogeneous nucleation and growth in a phase-field model using cell dynamics method

Homogeneous nucleation and growth in a simplest two-dimensional phase field model is numerically studied using the cell dynamics method. Whole process from nucleation to growth is simulated and is shown to follow closely the Kolmogorov-Johnson-Mehl-Avrami (KJMA) scenario of phase transformation. Specifically the time evolution of the volume fraction of new stable phase is found to follow closely the KJMA formula. By fitting the KJMA formula directly to the simulation data, not only the Avrami exponent but the magnitude of nucleation rate and, in particular, of incubation time are quantitatively studied. The modified Avrami plot is also used to verify the derived KJMA parameters. It is found that the Avrami exponent is close to the ideal theoretical value m=3. The temperature dependence of nucleation rate follows the activation-type behavior expected from the classical nucleation theory. On the other hand, the temperature dependence of incubation time does not follow the exponential activation-type behavior. Rather the incubation time is inversely proportional to the temperature predicted from the theory of Shneidman and Weinberg [J. Non-Cryst. Solids {\bf 160}, 89 (1993)]. A need to restrict thermal noise in simulation to deduce correct Avrami exponent is also discussed.Comment: 9 pages, 8 figures, Journal of Chemical Physics to be publishe

Oxygen-related traps in pentacene thin films: Energetic position and implications for transistor performance

We studied the influence of oxygen on the electronic trap states in a pentacene thin film. This was done by carrying out gated four-terminal measurements on thin-film transistors as a function of temperature and without ever exposing the samples to ambient air. Photooxidation of pentacene is shown to lead to a peak of trap states centered at 0.28 eV from the mobility edge, with trap densities of the order of 10(18) cm(-3). These trap states need to be occupied at first and cause a reduction in the number of free carriers, i.e. a consistent shift of the density of free holes as a function of gate voltage. Moreover, the exposure to oxygen reduces the mobility of the charge carriers above the mobility edge. We correlate the change of these transport parameters with the change of the essential device parameters, i.e. subthreshold performance and effective field-effect mobility. This study supports the assumption of a mobility edge for charge transport, and contributes to a detailed understanding of an important degradation mechanism of organic field-effect transistors. Deep traps in an organic field-effect transistor reduce the effective field-effect mobility by reducing the number of free carriers and their mobility above the mobility edge.Comment: 13 pages, 14 figures, to be published in Phys. Rev.

Ensemble of Vortex Loops in the Abelian-Projected SU(3)-Gluodynamics

Grand canonical ensemble of small vortex loops emerging in the London limit of the effective Abelian-projected theory of the SU(3)-gluodynamics is investigated in the dilute gas approximation. An essential difference of this system from the SU(2)-case is the presence of two interacting gases of vortex loops. Two alternative representations for the partition function of such a grand canonical ensemble are derived, and one of them, which is a representation in terms of the integrals over vortex loops, is employed for the evaluation of the correlators of both kinds of loops in the low-energy limit.Comment: 10 pages, LaTeX2e, no figures, minor corrections, to appear in Mod. Phys. Lett.

The Abelian Higgs Model as an Ensemble of Vortex Loops

In the London limit of the Ginzburg-Landau theory (Abelian Higgs model), vortex dipoles (small vortex loops) are treated as a grand canonical ensemble in the dilute gas approximation. The summation over these objects with the most general rotation- and translation invariant measure of integration over their shapes leads to effective sine-Gordon theories of the dual fields. The representations of the partition functions of both grand canonical ensembles are derived in the form of the integrals over the vortex dipoles and the small vortex loops, respectively. By virtue of these representations, the bilocal correlator of the vortex dipoles (loops) is calculated in the low-energy limit. It is further demonstrated that once the vortex dipoles (loops) are considered as such an ensemble rather than individual ones, the London limit of the Ginzburg-Landau theory (Abelian Higgs model) with external monopoles is equivalent up to the leading order in the inverse UV cutoff to the compact QED in the corresponding dimension with the charge of Cooper pairs changed due to the Debye screening.Comment: 17 pages, LaTeX2e, no figures, dedicated to Prof. Yu.A. Simonov on the occasion of his 65-th birthday, final published version (minor corrections, references added

One-second coherence for a single electron spin coupled to a multi-qubit nuclear-spin environment

Single electron spins coupled to multiple nuclear spins provide promising multi-qubit registers for quantum sensing and quantum networks. The obtainable level of control is determined by how well the electron spin can be selectively coupled to, and decoupled from, the surrounding nuclear spins. Here we realize a coherence time exceeding a second for a single electron spin through decoupling sequences tailored to its microscopic nuclear-spin environment. We first use the electron spin to probe the environment, which is accurately described by seven individual and six pairs of coupled carbon-13 spins. We develop initialization, control and readout of the carbon-13 pairs in order to directly reveal their atomic structure. We then exploit this knowledge to store quantum states for over a second by carefully avoiding unwanted interactions. These results provide a proof-of-principle for quantum sensing of complex multi-spin systems and an opportunity for multi-qubit quantum registers with long coherence times

Do you need a job to find a job?

This paper investigates whether job offers arrive more frequently for those in employment than for those in unemployment. To this end, we take advantage of a unique Australian data set which contains information on both accepted and rejected job offers. Our estimation strategy takes account of the selectivity associated with the initial employment state and we allow for individual heterogeneity in the probability of obtaining jobs. Our results reveal that, across the wage range, individuals are about equally likely to obtain a job offer in employment as in unemployment. This implies that encouraging unemployed (rather than employed) search through the provision of unemployment benefits does not improve the speed of a job match

String Fields and the Standard Model

The Cremmer-Scherk mechanism is generalised in a non-Abelian context. In the presence of the Higgs scalars of the standard model it is argued that fields arising from the low energy effective string action may contribute to the mass generation of the observed vector bosons that mediate the electroweak interactions and that future analyses of experimental data should consider the possibility of string induced radiative corrections to the Weinberg angle coming from physics beyond the standard model.Comment: 4 pages, LATEX, no figure

Superconductors with Topological Order

We propose a mechanism of superconductivity in which the order of the ground state does not arise from the usual Landau mechanism of spontaneous symmetry breaking but is rather of topological origin. The low-energy effective theory is formulated in terms of emerging gauge fields rather than a local order parameter and the ground state is degenerate on topologically non-trivial manifolds. The simplest example of this mechanism of superconductivty is concretely realized as global superconductivty in Josephson junction arrays.Comment: 4 pages, no figure