Enhancement of electrostrictive polymer efficiency for energy harvesting with cellular polypropylene electrets

The purpose of this paper is to propose new means for harvesting energy using electrostrictive polymers. The recent development of electrostrictive polymers has generated new opportunities for high-strain actuators. At the current time, the investigation of using electrostrictive polymer for energy harvesting, or mechanical-to-electrical energy conversion, is beginning to show its potential for this application. The objective of this work was to study the effect of cellular polypropylene electrets after high-voltage corona poling on an electrostrictive polyurethane composite filled with 1 vol.% carbon black at a low applied voltage in order to increase the efficiency of the electromechanical conversion with electrostrictive polymers. Theoretical analysis supported by experimental investigations showed that an energy harvesting with this structure rendered it possible to obtain harvested power up to 13.93 nW using a low electric field of 0.4 V/mu m and a transverse strain of 3% at a mechanical frequency of 15 Hz. This represents an efficiency of 78.14% at low frequency. This percentage is very significant compared to other structures. Finally, it was found that the use of polypropylene electrets with electrostrictive polymers was the best way to decrease the power of polarization in order to obtain a good efficiency of the electromechanical conversion for energy harvesting

Spiral cracks in drying precipitates

We investigate the formation of spiral crack patterns during the desiccation of thin layers of precipitates in contact with a substrate. This symmetry-breaking fracturing mode is found to arise naturally not from torsion forces, but from a propagating stress front induced by the fold-up of the fragments. We model their formation mechanism using a coarse-grain model for fragmentation and successfully reproduce the spiral cracks. Fittings of experimental and simulation data show that the spirals are logarithmic, corresponding to constant deviation from a circular crack path. Theoretical aspects of the logarithmic spirals are discussed. In particular we show that this occurs generally when the crack speed is proportional to the propagating speed of stress front.Comment: 4 pages, 5 figures, RevTe

Development and geometry of isotropic and directional shrinkage crack patterns

We have studied shrinkage crack patterns which form when a thin layer of an alumina/water slurry dries. Both isotropic and directional drying were studied. The dynamics of the pattern formation process and the geometric properties of the isotropic crack patterns are similar to what is expected from recent models, assuming weak disorder. There is some evidence for a gradual increase in disorder as the drying layer become thinner, but no sudden transition, in contrast to what has been seen in previous experiments. The morphology of the crack patterns is influenced by drying gradients and front propagation effects, with sharp gradients having a strong orienting and ordering effect.Comment: 8 pages, 11 figures, 8 in jpg format, 3 in postscript. See also http://mobydick.physics.utoronto.ca/mud.htm

Theory of dynamic crack branching in brittle materials

The problem of dynamic symmetric branching of an initial single brittle crack propagating at a given speed under plane loading conditions is studied within a continuum mechanics approach. Griffith's energy criterion and the principle of local symmetry are used to determine the cracks paths. The bifurcation is predicted at a given critical speed and at a specific branching angle: both correlated very well with experiments. The curvature of the subsequent branches is also studied: the sign of $T$, with $T$ being the non singular stress at the initial crack tip, separates branches paths that diverge from or converge to the initial path, a feature that may be tested in future experiments. The model rests on a scenario of crack branching with some reasonable assumptions based on general considerations and in exact dynamic results for anti-plane branching. It is argued that it is possible to use a static analysis of the crack bifurcation for plane loading as a good approximation to the dynamical case. The results are interesting since they explain within a continuum mechanics approach the main features of the branching instabilities of fast cracks in brittle materials, i.e. critical speeds, branching angle and the geometry of subsequent branches paths.Comment: 41 pages, 15 figures. Accepted to International Journal of Fractur

Fracture Patterns Induced by Desiccation in a Thin Layer

We study a theoretical model of mud cracks, that is, the fracture patterns resulting from the contraction with drying in a thin layer of a mixture of granules and water. In this model, we consider the slip on the bottom of this layer and the relaxation of the elastic field that represents deformation of the layer. Analysis of the one-dimensional model gives results for the crack size that are consistent with experiments. We propose an analytical method of estimation for the growth velocity of a simple straight crack to explain the very slow propagation observed in actual experiments. Numerical simulations reveal the dependence of qualitative nature of the formation of crack patterns on material properties.Comment: 37 pages,18 figures,REVTEX,submitted to Rhys.Rev.

Thermal fracture as a framework for quasi-static crack propagation

We address analytically and numerically the problem of crack path prediction in the model system of a crack propagating under thermal loading. We show that one can explain the instability from a straight to a wavy crack propagation by using only the principle of local symmetry and the Griffith criterion. We then argue that the calculations of the stress intensity factors can be combined with the standard crack propagation criteria to obtain the evolution equation for the crack tip within any loading configuration. The theoretical results of the thermal crack problem agree with the numerical simulations we performed using a phase field model. Moreover, it turns out that the phase-field model allows to clarify the nature of the transition between straight and oscillatory cracks which is shown to be supercritical.Comment: 19 pages, 8 figure

Effect of Interaction on the Formation of Memories in Paste

A densely packed colloidal suspension with plasticity, called paste, is known to remember directions of vibration and flow. These memories in paste can be visualized by the morphology of desiccation crack patterns. Here, we find that paste made of charged colloidal particles cannot remember flow direction. If we add sodium chloride into such paste to screen the Coulombic repulsive interaction between particles, the paste comes to remember flow direction. That is, one drop of salt water changes memory effect in the paste and thereby we can tune the morphology of desiccation crack patterns more precisely.Comment: 10 pages, 11 figures, Title change

Drying colloidal systems: laboratory models for a wide range of applications

The drying of complex fluids provides a powerful insight into phenomena that take place on time and length scales not normally accessible. An important feature of complex fluids, colloidal dispersions and polymer solutions is their high sensitivity to weak external actions. Thus, the drying of complex fluids involves a large number of physical and chemical processes. The scope of this review is the capacity to tune such systems to reproduce and explore specific properties in a physics laboratory. A wide variety of systems are presented, ranging from functional coatings, food science, cosmetology, medical diagnostics and forensics to geophysics and art

Controllable electrostriction of polyurethane film

cited By 1; Conference of 8th International Conference on Processing and Manufacturing of Advanced Materials, THERMEC 2013 ; Conference Date: 2 December 2013 Through 6 December 2013; Conference Code:105675International audienceAlthough their experimental errors can be observed, pure polyurethane (PU) elastomers are one of the most important class of polymers due to some remarkable electromechanical characteristics such as large electric field induced strain, high specific energy and fast speed of response. In order to obtain the large strain at low electric field, a dependence of the solidification condition on strain was investigated for pure polyurethane films. Optimum solidification condition to get thin film with 19 μm thickness remarkably enhanced the strain at high electric field at high electric filed, although they show the low strain at low electric field at low electric filed. The starting point of the convergence occurred at a lower electric field for the solidification condition to get thick film with 150 μm thickness as opposed to for the optimum condition to obtain the thin film with 19 μm thickness. Based on results of crystalline volume fraction and crystalline periodicity, strongly attributed to not only polarization, but also electrostriction, the strain was controlled by the solidification condition. The optimum solidified samples do not have convergence until 20 MV/m. Based on the prediction and experimental results, the electrostriction of PU films depended on its solidification condition. © (2014) Trans Tech Publications, Switzerland

Elastocaloric effect in poly(vinylidene fluoride-trifluoroethylene-chlorotrifluoroethylene) terpolymer

cited By 4International audienceThe elastocaloric properties of poly (vinylidene fluoride-trifluoroethylene-chlorotrifluoroethylene) [P(VDF-TrFE-CTFE)] terpolymer were directly characterized using an infrared imaging camera. At a strain of 12%, a reversible adiabatic temperature variation of 2.15 �C was measured, corresponding to an isothermal entropy variation of 21.5 kJ m-3 K-1 or 11 J kg-1 K-1. In comparison with other elastocaloric materials, P(VDF-TrFE-CTFE) appears to represent a trade-off between the large required stresses in shape memory alloys and the large required strains in natural rubber. The internal energy of the P(VDF-TrFE-CTFE) polymer was found to be independent of the strain, resulting in complete conversion of the mechanical work into heat, as for pure elastomeric materials. The elastocaloric effect therefore originates from a pure entropic elasticity, which is likely to be related to the amorphous phase of the polymer only. � 2016 Author(s)