The Origin of Nitrogen on Jupiter and Saturn from the 15^{15}N/14^{14}N Ratio

The Texas Echelon cross Echelle Spectrograph (TEXES), mounted on NASA's Infrared Telescope Facility (IRTF), was used to map mid-infrared ammonia absorption features on both Jupiter and Saturn in February 2013. Ammonia is the principle reservoir of nitrogen on the giant planets, and the ratio of isotopologues ($^{15}$N/$^{14}$N) can reveal insights into the molecular carrier (e.g., as N$_2$ or NH$_3$) of nitrogen to the forming protoplanets, and hence the source reservoirs from which these worlds accreted. We targeted two spectral intervals (900 and 960 cm$^{-1}$) that were relatively clear of terrestrial atmospheric contamination and contained close features of $^{14}$NH$_3$ and $^{15}$NH$_3$, allowing us to derive the ratio from a single spectrum without ambiguity due to radiometric calibration (the primary source of uncertainty in this study). We present the first ground-based determination of Jupiter's $^{15}$N/$^{14}$N ratio (in the range from $1.4\times10^{-3}$ to $2.5\times10^{-3}$), which is consistent with both previous space-based studies and with the primordial value of the protosolar nebula. On Saturn, we present the first upper limit on the $^{15}$N/$^{14}$N ratio of no larger than $2.0\times10^{-3}$ for the 900-cm$^{-1}$ channel and a less stringent requirement that the ratio be no larger than $2.8\times10^{-3}$ for the 960-cm$^{-1}$ channel ($1\sigma$ confidence). Specifically, the data rule out strong $^{15}$N-enrichments such as those observed in Titan's atmosphere and in cometary nitrogen compounds. To the extent possible with ground-based radiometric uncertainties, the saturnian and jovian $^{15}$N/$^{14}$N ratios appear indistinguishable, implying that $^{15}$N-enriched ammonia ices could not have been a substantial contributor to the bulk nitrogen inventory of either planet, favouring the accretion of primordial N$_2$ from the gas phase or as low-temperature ices.Comment: 33 pages, 19 figures, manuscript accepted for publication in Icaru

V838 Monocerotis: the central star and its environment a decade after outburst

Aims. V838 Monocerotis erupted in 2002, brightened in a series of outbursts, and eventually developed a spectacular light echo. A very red star emerged a few months after the outburst. The whole event has been interpreted as the result of a merger. Methods. We obtained near-IR and mid-IR interferometric observations of V838 Mon with the AMBER and MIDI recombiners located at the Very Large Telescope Interferometer (VLTI) array. The MIDI two-beam observations were obtained with the 8m Unit Telescopes between October 2011 and February 2012. The AMBER three-beam observations were obtained with the compact array (B$\leq$m) in April 2013 and the long array (B$\leq$140m) in May 2014, using the 1.8m Auxiliary Telescopes. Results. A significant new result is the detection of a compact structure around V838 Mon, as seen from MIDI data. The extension of the structure increases from a FWHM of 25 mas at 8 {\mu}m to 70 mas at 13 {\mu}m. At the adopted distance of D = 6.1 $\pm$ 0.6 kpc, the dust is distributed from about 150 to 400 AU around V838 Mon. The MIDI visibilities reveal a flattened structure whose aspect ratio increases with wavelength. The major axis is roughly oriented around a position angle of -10 degrees, which aligns with previous polarimetric studies reported in the literature. This flattening can be interpreted as a relic of the 2002 eruption or by the influence of the currently embedded B3V companion. The AMBER data provide a new diameter for the pseudo-photosphere, which shows that its diameter has decreased by about 40% in 10yrs, reaching a radius R$_*$ = 750 $\pm$ 200 R$_{\odot}$ (3.5 $\pm$ 1.0 AU). Conclusions. After the 2002 eruption, interpreted as the merging of two stars, it seems that the resulting source is relaxing to a normal state. The nearby environment exhibits an equatorial over-density of dust up to several hundreds of AU.Comment: Astronomy and Astrophysics (2014) Will be set by the publishe

Spiral inflow feeding the nuclear starburst in M83, observed in H-alpha emission with the GHAFAS Fabry-Perot interferometer

We present observations of the nearby barred starburst galaxy, M83 (NGC5236), with the new Fabry-Perot interferometer GHAFAS mounted on the 4.2 meter William Herschel Telescope on La Palma. The unprecedented high resolution observations, of 16 pc/FWHM, of the H-alpha-emitting gas cover the central two kpc of the galaxy. The velocity field displays the dominant disk rotation with signatures of gas inflow from kpc scales down to the nuclear regions. At the inner Inner Lindblad Resonance radius of the main bar and centerd at the dynamical center of the main galaxy disk, a nuclear $5.5 (\pm 0.9) \times 10^8 M_\odot$ rapidly rotating disk with scale length of $60 \pm 20$ pc has formed. The nuclear starburst is found in the vicinity as well as inside this nuclear disk, and our observations confirm that gas spirals in from the outer parts to feed the nuclear starburst, giving rise to several star formation events at different epochs, within the central 100 pc radius of M83.Comment: Accepted for publication in ApJ Letters. High-resolution version can be found at http://www.astro.su.se/~kambiz/DOC/paper-M83.pd

The Erpenbeck high frequency instability theorem for ZND detonations

The rigorous study of spectral stability for strong detonations was begun by J.J. Erpenbeck in [Er1]. Working with the Zeldovitch-von Neumann-D\"oring (ZND) model, which assumes a finite reaction rate but ignores effects like viscosity corresponding to second order derivatives, he used a normal mode analysis to define a stability function V(\tau,\eps) whose zeros in $\Re \tau>0$ correspond to multidimensional perturbations of a steady detonation profile that grow exponentially in time. Later in a remarkable paper [Er3] he provided strong evidence, by a combination of formal and rigorous arguments, that for certain classes of steady ZND profiles, unstable zeros of $V$ exist for perturbations of sufficiently large transverse wavenumber \eps, even when the von Neumann shock, regarded as a gas dynamical shock, is uniformly stable in the sense defined (nearly twenty years later) by Majda. In spite of a great deal of later numerical work devoted to computing the zeros of V(\tau,\eps), the paper \cite{Er3} remains the only work we know of that presents a detailed and convincing theoretical argument for detecting them. The analysis in [Er3] points the way toward, but does not constitute, a mathematical proof that such unstable zeros exist. In this paper we identify the mathematical issues left unresolved in [Er3] and provide proofs, together with certain simplifications and extensions, of the main conclusions about stability and instability of detonations contained in that paper. The main mathematical problem, and our principal focus here, is to determine the precise asymptotic behavior as \eps\to \infty of solutions to a linear system of ODEs in $x$, depending on \eps and a complex frequency $\tau$ as parameters, with turning points $x_*$ on the half-line $[0,\infty)$

Unveiling the central parsec region of an AGN: the Circinus nucleus in the near infrared with the VLT

VLT J- to M\p-band adaptive optics observations of the Circinus Galaxy on parsec scales resolve a central bright Ks-band source with a FWHM size of 1.9 $\pm$ 0.6 pc. This source is only visible at wavelengths longward of 1.6 $\mu$m and coincides in position with the peak of the [Si VII]~2.48 $\mu$m coronal line emission. With respect to the peak of the central optical emission, the source is shifted by $\sim$ 0.15\arcsec (2.8 pc) to the south-east. Indeed, it defines the vertex of a fairly collimated beam which extends for $\sim$ 10 pc, and which is seen in both continuum light shortward of 1.6 $\mu$m and in H$\alpha$ line emission. The source also lies at the center of a $\sim$ 19 pc size [Si VII] ionization {\it bicone}. Identifying this source as the nucleus of Circinus, its size is compatible with a putative parsec-scale torus. Its spectral energy distribution, characterized by a prominent narrow peak, is compatible with a dust temperature of 300 K. Hotter dust within a 1 pc radius of the center is not detected. The AGN luminosity required to heat this dust is in the range of X-ray luminosities that have been measured toward the central source. This in turn supports the existence of highly obscuring material, with column densities of $10^{24}$ cm$^{-2}$, that must be located within 1 pc of the core.Comment: 15 pages, 4 figures; To appear in The Astrophysical Journa

Synthesis and characterization of tantalum(V) boronate clusters : multifunctional Lewis acid cages for binding guests

Open and shut cases: Tantalum(V) boronate clusters [(Cp*Ta)3(μ2‐η2‐RBO2)3(μ2‐O)2(μ2‐OH)(μ3‐OH)] (Cp*=η5‐C5Me5; 1: R=Ph, 2: R=iBu) with Lewis acidic cavities were prepared. Whereas the cavity of 2 is blocked by the iBu groups, that of 1 is open and can bind Lewis basic guests such as ketones (see picture) by interaction with one boronate and one μ3‐OH ligand

Enhancement of the Nernst effect by stripe order in a high-Tc superconductor

The Nernst effect in metals is highly sensitive to two kinds of phase transition: superconductivity and density-wave order. The large positive Nernst signal observed in hole-doped high-Tc superconductors above their transition temperature Tc has so far been attributed to fluctuating superconductivity. Here we show that in some of these materials the large Nernst signal is in fact caused by stripe order, a form of spin / charge modulation which causes a reconstruction of the Fermi surface. In LSCO doped with Nd or Eu, the onset of stripe order causes the Nernst signal to go from small and negative to large and positive, as revealed either by lowering the hole concentration across the quantum critical point in Nd-LSCO, or lowering the temperature across the ordering temperature in Eu-LSCO. In the latter case, two separate peaks are resolved, respectively associated with the onset of stripe order at high temperature and superconductivity near Tc. This sensitivity to Fermi-surface reconstruction makes the Nernst effect a promising probe of broken symmetry in high-Tc superconductors

Beyond the Damping Tail: Cross-Correlating the Kinetic Sunyaev-Zel'dovich Effect with Cosmic Shear

Secondary anisotropies of the CMB have the potential to reveal intricate details about the history of our universe between the present and recombination epochs. However, because the CMB we observe is the projected sum of a multitude of effects, the interpretation of small scale anisotropies by future high resolution experiments will be marred by uncertainty and speculation without the handles provided by other observations. In this paper we show that cross correlating the CMB with an overlapping weak lensing survey will isolate the elusive kinetic Sunyaev-Zel'dovich Effect from secondary anisotropies generated at higher redshifts. We show that if upcoming high angular resolution CMB experiments, like PLANCK/ACT/SPT, cover the same area of sky as current and future weak lensing surveys, like CFTHLS/SNAP/LSST, the cross correlation of cosmic shear with the kSZ effect will be detected with high signal to noise ratio, increasing the potential science accessible to both sets of surveys. For example, if ACT and a CFHTLS like survey were to overlap this cross-correlation would be detected with a total signal to noise ratio greater than 220, reaching 1.8 per individual multipole around l \sim 5000. Furthermore, this cross-correlation probes the three point coupling between the underlying dark matter and the "momentum" of the ionized baryons in the densest regions of the universe at intermediate redshifts. Similar to the tSZ power spectrum, its strength is extremely sensitive to the power spectrum normalization parameter, \sigma_8, scaling roughly as \sigma_8^7. It provides an effective mechanism to isolate any component of anisotropy due to patchy reionization and rule out primordial small scale anisotropy.Comment: 13 pages, 10 figures, ApJ submitted. Units of one plot correcte

Contributions of the Environmental Non Governmental Organisations and international law on climate change

This study aims at finding out how Non Governmental Organisations (NGOs) perceive this issue and what roles they play in the fight against this phenomenon and in its formation in order to contribute to this domain and analyse contributions of Non Governmental Organisations to the International law on climate change. Results show that consequences of climate changeare visible and real. Thus, NGOs such as Friends of the Earth, Greenpeace, World Wild Funds (WWF), World Watch Institute (WWI) and Sierra Club emerged in the mode of the International law, bringing an effective participation in International negotiations by cooperating with States and by sensitizing citizens and political decision-makers. For this purpose, the United Nations Framework Convention on Climate Change (UNFCCC) was adopted in 1992 and the Kyoto Protocol in 1997 as well as several other multilateral treaties during different Conventions of Parties (COP). However, this struggle is opposed by industrialists and other States that protect their short-term interests and support the idea that climate change mightnot exist or climatic change is not due to men, but rather to natural phenomena. That is why NGOs have to actively play their role of pressure to call out to decision makers and populations on consequences of the climate change so that we can attenuate this phenomenon because the more we are doing nothing today, the more difficult it will be to avoid the consequences tomorrow