Carbon isotopes in bulk carbonaceous chondrites

The chemical and physical processes involved in the formation of the solar system are examined. Primitive matter has been found on a microscopic scale in a variety of meteorites: fragments of small solar system bodies that were never part of a large planet. This primitive matter has, in most cases, been identified by the presence of anomalous abundances of some isotopes of the chemical elements. Of particular interest for carbon isotope studies are the primitive meteorites known as carbonaceous chondrites. Using a selective oxidation technique to sort out the carbon contained in different chemical forms (graphite, carbonates, and organic matter), four carbonaceous chondrites are analyzed. The presence of the (13) C-rich component was confirmed and additional carbon components with different, but characteristic, isotopic signatures were resolved

Oxygen isotope fractionation in Apollo 12 rocks and soils

Oxygen isotopic compositions and fractionations between coexisting minerals found in lunar samples from Apollo 11 and Apollo 12 flight

Heterogeneities in the solar nebula

Oxygen isotopic compositions of the high-temperatue phases in carbonaceous chondrites define a mixing line with an O-16 rich component and show little superimposed chemical isotope fractionation. Within a single inclusion in Allende, variations of delta O-18 and delta O-17 of 39% are found. The ordinary chondrites are slightly displaced from the terrestrial fractionation trend, implying that at least 0.2% of the oxygen in terrestrial rocks was derived from the O-16 rich component

Energy radiation from intermediate to large magnitude earthquakes: implications for dynamic fault weakening

The amount of energy radiated from an earthquake can be measured using recent methods based on earthquake coda signals and spectral ratios. Such methods are not altered by either site or directivity effects, with the advantage of a greatly improved accuracy. Several studies of earthquake sequences based on the above measurements showed evidence of a breakdown in self-similarity in the moment to energy relation. Radiated energy can be also used as a gauge to estimate the average dynamic stress drop on the fault. Here we compute the dynamic stress drop, infer the co-seismic friction and estimate the co-seismic heating resulting from the frictional work during events from different main shock-aftershock earthquake sequences. We relate the dynamic friction to the maximum temperature rise estimated on the faults for each earthquake. Our results are strongly indicative that a thermally triggered dynamic frictional weakening is present, responsible for the breakdown in self-similarity. These observations from seismic data are compatible with recent laboratory evidence of thermal weakening in rock friction under seismic slip-rates, associated to various physical processes such as melting, decarbonation or dehydration

A regional ground motion excitation/attenuation model for the San Francisco region

By using small-to-moderate-sized earthquakes located within ~200 km of San Francisco, we characterize the scaling of the ground motions for frequencies ranging between 0.25 and 20 Hz, obtaining results for geometric spreading, Q(f), and site parameters using the methods of Mayeda et al. (2005) and Malagnini et al. (2004). The results of the analysis show that, throughout the Bay Area, the average regional attenuation of the ground motion can be modeled with a bilinear geometric spreading function with a 30 km crossover distance, coupled to an anelastic function exp(-pi*f*r/V*Q(f)) , where: Q(f)=180f^0.42. A body-wave geometric spreading, g(r)= r^-1.0, is used at short hypocentral distances (r < 30 km), whereas g(r)= r^-0.6 fits the attenuation of the spectral amplitudes at hypocentral distances beyond the crossover. The frequency-dependent site effects at 12 of the Berkeley Digital Seismic Network (BDSN) stations were evaluated in an absolute sense using coda-derived source spectra. Our results show: i) the absolute site response for frequencies ranging between 0.3 Hz and 2.0 Hz correlate with independent estimates of the local magnitude residuals (dML) for each of the stations; ii) moment-magnitudes (MW) derived from our path and site-corrected spectra are in excellent agreement with those independently derived using full-waveform modeling as well as coda-derived source spectra; iii) we use our weak-motion-based relationships to predict motions region wide for the Loma Prieta earthquake, well above the maximum magnitude spanned by our data set, on a completely different set of stations. Results compare well with measurements taken at specific NEHRP site classes; iv) an empirical, magnitude-dependent scaling was necessary for the Brune stress parameter in order to match the large magnitude spectral accelerations and peak ground velocities with our weak-motion-based model

Classificational parameters for acapulcoites and lodranites: The cases of FRO 90011, EET 84302 and ALH A81187/84190

Acapulcoites and lodranites probably sample a common parent body, which has experienced a range of partial melting. We present classificational parameters which allow acapulcoites-lodranites to be distinguished from other groups of meteorites, as well as from each other. Petrography can complement oxygen isotopic compositions in separating these meteorites from other groups of stony-irons and primitive achondrites, while petrographic properties alone distinguish acapulcoites from lodranites. Acapulcoites differ from lodranites in having smaller grain sizes, abundant Fe, Ni-FeS as micron-sized veins and plagioclase which escaped melting. We have applied these criteria to three new members of the group. FRO 90011 is a typical lodranite; EET 84302 is intermediate in many properties between acapulcoites and lodranites; and ALH A81187/84190 are paired meteorites and are first low-FeO acapulcoites. These meteorites provide a wider spectrum of samples from the acapulcoite-lodranite parent body and suggests that this body may have had a complex structure

A Regional Ground Motion Excitation attenuation Model for the San Francisco Region

By using small-to-moderate-sized earthquakes located within ~200 km of San Francisco, we characterize the scaling of the ground motions for frequencies ranging between 0.25 and 20 Hz, obtaining results for geometric spreading, Q(f), and site parameters using the methods of Mayeda et al. (2005) and Malagnini et al. (2004). The results of the analysis show that, throughout the Bay Area, the average regional attenuation of the ground motion can be modeled with a bilinear geometric spreading function with a 30 km crossover distance, coupled to an anelastic function ! exp " #fr $Q( f ) % & ' ( ) * , where: Q(f)=180 f 0.42. A body-wave geometric spreading, g(r)= r -1.0, is used at short hypocentral distances (r < 30 km), whereas g(r)= r -0.6 fits the attenuation of the spectral amplitudes at hypocentral distances beyond the crossover. The frequency-dependent site effects at 12 of the Berkeley Digital Seismic Network (BDSN) stations were evaluated in an absolute sense using coda-derived source spectra. Our results show: i) the absolute site response for frequencies ranging between 0.3 Hz and 2.0 Hz correlate with independent estimates of the local magnitude residuals (dML) for each of the stations; ii) moment-magnitudes (MW) derived from our path and sitecorrected spectra are in excellent agreement with those independently derived using fullwaveform modeling as well as coda-derived source spectra; iii) we use our weak-motionbased relationships to predict motions region wide for the Loma Prieta earthquake, well above the maximum magnitude spanned by our data set, on a completely different set of stations. Results compare well with measurements taken at specific NEHRP site classes; iv) an empirical, magnitude-dependent scaling was necessary for the Brune stress parameter in order to match the large magnitude spectral accelerations and peak ground velocities with our weak-motion-based model

General splicing factor SF2/ASF promotes alternative splicing by binding to an exonic splicing enhancer

The general splicing factor SF2/ASF binds in a sequence-specific manner to a purine-rich exonic splicing enhancer (ESE) in the last exon of bovine growth hormone (bGH) pre-mRNA. More importantly, SF2/ASF stimulates in vitro splicing of bGH intron D through specific interaction with the ESE sequences. However, another general splicing factor, SC35, does not bind the ESE sequences and has no effect on bGH intron D splicing. Thus, one possible function of SF2/ASF in alternative and, perhaps, constitutive pre-mRNA splicing is to recognize ESE sequences. The stimulation of bGH intron D splicing by SF2/ASF is counteracted by the addition of hnRNP A1. The relative levels of SF2/ASF and hnRNP A1 influence the efficiency of bGH intron D splicing in vitro and may be the underlying mechanism of this alternative pre-mRNA processing event in vivo

RNA splicing at human immunodeficiency virus type 1 3 ' splice site A2 is regulated by binding of hnRNP A/B proteins to an exonic splicing silencer element

The synthesis of human immunodeficiency virus type 1 (HIV-1) mRNAs is a complex process by which more than 30 different mRNA species are produced by alternative splicing of a single primary RNA transcript. HIV-1 splice sites are used with significantly different efficiencies, resulting in different levels of mRNA species in infected cells. Splicing of Tat mRNA, which is present at relatively low levels in infected cells, is repressed by the presence of exonic splicing silencers (ESS) within the two tat coding exons (ESS2 and ESS3). These ESS elements contain the consensus sequence PyUAG. Here we show that the efficiency of splicing at 3 ' splice site A2, which is used to generate Vpr mRNA, is also regulated by the presence of an ESS (ESSV), which has sequence homology to ESS2 and ESS3. Mutagenesis of the three PyUAG motifs within ESSV increases splicing at splice site A2, resulting in increased Vpr mRNA levels and reduced skipping of the noncoding exon flanked by A2 and D3. The increase in Vpr mRNA levels and the reduced skipping also occur when splice site D3 is mutated toward the consensus sequence. By in vitro splicing assays, we show that ESSV represses splicing when placed downstream of a heterologous splice site. A1, A1(B), A2, and B1 hnRNPs preferentially bind to ESSV RNA compared to ESSV mutant RNA. Each of these proteins, when added back to HeLa cell nuclear extracts depleted of ESSV-binding factors, is able to restore splicing repression. The results suggest that coordinate repression of HIV-1 RNA splicing is mediated by members of the hnRNP A/B protein family

The CR chondrite clan

The (1) CR chondrites, (2) LEW 85332,(3) Acfer 182,(4) ALH 85085-like chondrites, and (5) Bencubbin-like chondritic breccias are five kinds of chondritic groups which have dramatically different petrographic characteristics, but have mineralogical, bulk chemical, and oxygen and nitrogen isotopic similarities that indicate they are closely related. They are all considered to be members of what we term the CR chondrite clan. Distinguishing characteristics of CR clan chondrites include : (a) reduced, Mg-rich mafic silicates, (b) hydrous matrix and/or dark inclusions (except for Bencubbin-like chondrites), (c) high modal abundances of FeNi metal, (d) FeNi metal having a solar Ni : Co ratio, (e) solar (CI) abundances of refractory and moderately volatile lithophiles, and highly depleted abundances of volatile lithophiles, (f) similar oxygen isotopic compositions of whole rocks, chondrules and matrices, which are on or near the CR mixing line, and (g) anomalously high ^N abundances. CR clan chondrites must have formed in the same local region of the nebula, from closely related reservoirs of materials. The coexistence of anhydrous chondrules with hydrous matrix (and dark inclusions) in the LEW 85332,Acfer 182,and ALH 85085-like chondrites, as well as the widely differing degrees of hydration within and between chondritic samples, implies that hydration of the components was not variable in a single locality, but took place at a variety of locales prior to final lithification of the CR clan chondrites