88 research outputs found
Testing the validity of THz reflection spectra by dispersion relations
Complex response function obtained in reflection spectroscopy at terahertz
range is examined with algorithms based on dispersion relations for integer
powers of complex reflection coefficient, which emerge as a powerful and yet
uncommon tools in examining the consistency of the spectroscopic data. It is
shown that these algorithms can be used in particular for checking the success
of correction of the spectra by the methods of Vartiainen et al [1] and
Lucarini et al [2] to remove the negative misplacement error in the terahertz
time-domain spectroscopy.Comment: 17 pages, 4 figure
Detection and correction of the misplacement error in THz Spectroscopy by application of singly subtractive Kramers-Kronig relations
In THz reflection spectroscopy the complex permittivity of an opaque medium
is determined on the basis of the amplitude and of the phase of the reflected
wave. There is usually a problem of phase error due to misplacement of the
reference sample. Such experimental error brings inconsistency between phase
and amplitude invoked by the causality principle. We propose a rigorous method
to solve this relevant experimental problem by using an optimization method
based upon singly subtractive Kramers-Kronig relations. The applicability of
the method is demonstrated for measured data on an n-type undoped (100) InAs
wafer in the spectral range from 0.5 up to 2.5 THz.Comment: 16 pages, 5 figure
Nonlinear Optical Response Functions of Mott Insulators Based on Dynamical Mean Field Approximation
We investigate the nonlinear optical susceptibilities of Mott insulators with
the dynamical mean field approximation. The two-photon absorption (TPA) and the
third-harmonic generation (THG) spectra are calculated, and the classification
by the types of coupling to external fields shows different behavior from
conventional semiconductors. The direct transition terms are predominant both
in the TPA and THG spectra, and the importance of taking all types of
interaction with the external field into account is illustrated in connection
with the THG spectrum and dcKerr effect. The dependence of the TPA and THG
spectra on the Coulomb interaction indicate a scaling relation. We apply this
relation to the quantitative evaluation and obtain results comparable to those
of experiments.Comment: 14 pages, 12 figure
Coherent detection of metal-metal terahertz quantum cascade lasers with improved emission characteristics
Coherent detection of emission from quantum cascade lasers with metal-metal waveguides is demonstrated through free-space coupling of a THz pulse to the sub-wavelength waveguide. We implement a simple, monolithic planar horn antenna design on the metal-metal waveguide that reduces the impedance mis-match to the waveguide. The resulting devices show up to 10 times more directed output power than conventional metal-metal waveguides. This enhanced coupling to free-space allows a more efficient injection of broad-band THz pulses into the waveguide. Through this, we are able to seed the laser emission and coherently detect the laser emission by electro-optic sampling
Analysis of Granular Packing Structure by Scattering of THz Radiation
Scattering methods are widespread used to characterize the structure and
constituents of matter on small length scales. This motivates this introductory
text on identifying prospective approaches to scattering-based methods for
granular media. A survey to light scattering by particles and particle
ensembles is given. It is elaborated why the established scattering methods
using X-rays and visible light cannot in general be transferred to granular
media. Spectroscopic measurements using Terahertz radiation are highlighted as
they to probe the scattering properties of granular media, which are sensitive
to the packing structure. Experimental details to optimize spectrometer for
measurements on granular media are discussed. We perform transmission
measurements on static and agitated granular media using Fourier-transform
spectroscopy at the THz beamline of the BessyII storage ring. The measurements
demonstrate the potential to evaluate degrees of order in the media and to
track transient structural states in agitated bulk granular media.Comment: 12 Pages, 9 Figures, 56 Reference
Instrumentation-related uncertainty of reflectance and transmittance measurements with a two-channel spectrophotometer
Spectrophotometers are operated in numerous fields of science and industry for a variety of applications. In order to provide confidence for the measured data, analyzing the associated uncertainty is valuable. However, the uncertainty of the measurement results is often unknown or reduced to sample-related contributions. In this paper, we describe our approach for the systematic determination of the measurement uncertainty of the commercially available two-channel spectrophotometer Agilent Cary 5000 in accordance with the Guide to the expression of uncertainty in measurements. We focus on the instrumentation-related uncertainty contributions rather than the specific application and thus outline a general procedure which can be adapted for other instruments. Moreover, we discover a systematic signal deviation due to the inertia of the measurement amplifier and develop and apply a correction procedure. Thereby we increase the usable dynamic range of the instrument by more than one order of magnitude. We present methods for the quantification of the uncertainty contributions and combine them into an uncertainty budget for the device. © 2017 Author(s)
Optics-based compressibility parameter for pharmaceutical tablets obtained with the aid of the terahertz refractive index
The objective of this study is to propose a novel optical compressibility parameter for porous pharmaceutical tablets. This parameter is defined with the aid of the effective refractive index of a tablet that is obtained from non-destructive and contactless terahertz (THz) time-delay transmission measurement. The optical compressibility parameter of two training sets of pharmaceutical tablets with known porosity and mass fraction of a drug was investigated. Both pharmaceutical sets were compressed with one of the most commonly used excipients, namely microcrystalline cellulose (MCC) and drug Indomethacin. The optical compressibility clearly correlates with the skeletal bulk modulus determined by mercury porosimetry and the recently proposed terahertz lumped structural parameter calculated from terahertz measurements. This lumped structural parameter can be used to analyse the pattern of arrangement of excipient and drug particles in porous pharmaceutical tablets. Therefore, we propose that the optical compressibility can serve as a quality parameter of a pharmaceutical tablet corresponding with the skeletal bulk modulus of the porous tablet, which is related to structural arrangement of the powder particles in the tablet
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